Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines
Article
Flynn, Matthew T., Liu, Xin, Dell'Acqua, A., Rabeah, Jabor, Brueckner, Angelika, Barath, Eszter, Tin, Sergey and de Vries, Johannes G.. 2022. "Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines." ChemSusChem: chemistry and sustainability, energy and materials. 15 (20), pp. 1-6. https://doi.org/10.1002/cssc.202201264
| Article Title | Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines |
|---|---|
| ERA Journal ID | 1615 |
| Article Category | Article |
| Authors | Flynn, Matthew T., Liu, Xin, Dell'Acqua, A., Rabeah, Jabor, Brueckner, Angelika, Barath, Eszter, Tin, Sergey and de Vries, Johannes G. |
| Journal Title | ChemSusChem: chemistry and sustainability, energy and materials |
| Journal Citation | 15 (20), pp. 1-6 |
| Article Number | e202201264 |
| Number of Pages | 6 |
| Year | 21 Oct 2022 |
| Publisher | John Wiley & Sons |
| Place of Publication | Germany |
| ISSN | 1864-5631 |
| 1864-564X | |
| Digital Object Identifier (DOI) | https://doi.org/10.1002/cssc.202201264 |
| Web Address (URL) | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202201264 |
| Abstract | Biomass derived glycolaldehyde was employed as C1 building block for the N-formylation of secondary amines using air as oxidant. The reaction is atom economic, highly selective and proceeds under catalyst free conditions. This strategy can be used for the synthesis of cyclic and acyclic formylamines, including DMF. Mechanistic studies suggest a radical oxidation pathway. |
| Keywords | amines; formylation; glycolaldehyde; oxidation; platform chemicals |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 340504. Organic green chemistry |
| Byline Affiliations | Leibniz Institute for Catalysis, Germany |
Permalink -
https://research.usq.edu.au/item/wz49y/glycolaldehyde-as-a-bio-based-c1-building-block-for-selective-n-formylation-of-secondary-amines
Download files
Published Version
| ChemSusChem - 2022 - Flynn - Glycolaldehyde as a Bio‐Based C1 Building Block for Selective N‐Formylation of Secondary.pdf | ||
| License: CC BY-NC-ND 4.0 | ||
| File access level: Anyone | ||
43
total views29
total downloads1
views this month1
downloads this month
Export as
Related outputs
Circular economy barriers in Australia: How to translate theory into practice?
Feldman, Jessica, Seligmann, Hannah, King, Sarah, Flynn, Matthew, Shelley, Tristan, Helwig, Andreas and Burey, Paulomi (Polly). 2024. "Circular economy barriers in Australia: How to translate theory into practice?" Sustainable Production and Consumption. 45, pp. 582-597. https://doi.org/10.1016/j.spc.2024.02.001Construction and Deconstruction: Materials and substances from 'waste'
Burey, Paulomi, Feldman, Jessica, Seligmann, Hannah, Song, Eric, Flynn, Matthew, Helwig, Andreas, Gharineiat, Zahra, Seneviratne, Dinuki, Whiteside, Eliza, Shelley, Tristan, Priesler, Nils, Manalo, Allan, Mirzaghorbanali, Ali, Nourizadeh, Hadi, Roberts, Michae, Nicol, Rose, Redmond, Petrea, Lynch, Mark, Dearnaley, John, ..., Germon, Geoff. 2023. "Construction and Deconstruction: Materials and substances from 'waste'." Chemistry in Australia. (June-August 2023), pp. 16-21.Atom-economic synthesis of an oligomeric P/N-containing fire retardant towards fire-retarding and mechanically robust polylactide biocomposites
Feng, Jiabing, Lu, Yixia, Xie, Hongyan, Zhang, Yan, Huo, Siqi, Liu, Xiaohuan, Flynn, Matt, Xu, Zhiguang, Burey, Paulomi, Lynch, Mark, Wang, Hao and Song, Pingan. 2023. "Atom-economic synthesis of an oligomeric P/N-containing fire retardant towards fire-retarding and mechanically robust polylactide biocomposites." Journal of Materials Science and Technology. 160, pp. 86-95. https://doi.org/10.1016/j.jmst.2023.04.003On the activation of PhICl2 with pyridine
Poynder, Tiffany B., Orue, Analia I. Chamorro, Tania, Sharp-Bucknall, Lachlan, Flynn, M., Wilson, David J. D., Arachchige, K., Clegg, J.K. and Dutton, Jason L.. 2021. "On the activation of PhICl2 with pyridine." Chemical Communications. 57 (40), pp. 4970-4973. https://doi.org/10.1039/d1cc01567bA pilot study to assess the effects of Tai Chi on health indicators in type 1 diabetes patients
Liu, Xin, Russell, Anthony, Kabir, Enamul and Brown, Wendy. 2019. "A pilot study to assess the effects of Tai Chi on health indicators in type 1 diabetes patients." Health. 11, pp. 341-350. https://doi.org/10.4236/health.2019.113030Characterization of superfine down powder
Xu, Weilin, Wang, Xin, Cui, Weigang, Peng, Xuqiang, Li, Wenbin and Liu, Xin. 2009. "Characterization of superfine down powder ." Journal of Applied Polymer Science. 111 (5), pp. 2204-2209. https://doi.org/10.1002/app.29205This item comprises data from the following sources: Web of Science