Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines
Article
Flynn, Matthew T., Liu, Xin, Dell'Acqua, A., Rabeah, Jabor, Brueckner, Angelika, Barath, Eszter, Tin, Sergey and de Vries, Johannes G.. 2022. "Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines." ChemSusChem: chemistry and sustainability, energy and materials. 15 (20), pp. 1-6. https://doi.org/10.1002/cssc.202201264
| Article Title | Glycolaldehyde as a Bio-Based C1 Building Block for Selective N-Formylation of Secondary Amines |
|---|---|
| ERA Journal ID | 1615 |
| Article Category | Article |
| Authors | Flynn, Matthew T., Liu, Xin, Dell'Acqua, A., Rabeah, Jabor, Brueckner, Angelika, Barath, Eszter, Tin, Sergey and de Vries, Johannes G. |
| Journal Title | ChemSusChem: chemistry and sustainability, energy and materials |
| Journal Citation | 15 (20), pp. 1-6 |
| Article Number | e202201264 |
| Number of Pages | 6 |
| Year | 21 Oct 2022 |
| Publisher | John Wiley & Sons |
| Place of Publication | Germany |
| ISSN | 1864-5631 |
| 1864-564X | |
| Digital Object Identifier (DOI) | https://doi.org/10.1002/cssc.202201264 |
| Web Address (URL) | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202201264 |
| Abstract | Biomass derived glycolaldehyde was employed as C1 building block for the N-formylation of secondary amines using air as oxidant. The reaction is atom economic, highly selective and proceeds under catalyst free conditions. This strategy can be used for the synthesis of cyclic and acyclic formylamines, including DMF. Mechanistic studies suggest a radical oxidation pathway. |
| Keywords | amines; formylation; glycolaldehyde; oxidation; platform chemicals |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 340504. Organic green chemistry |
| Byline Affiliations | Leibniz Institute for Catalysis, Germany |
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