Polymer supported naphthalene-catalysed sodium reactions
Article
van den Ancker, Tania R. and Love, Cameron J.. 2007. "Polymer supported naphthalene-catalysed sodium reactions." Organic and Biomolecular Chemistry. 5 (21), pp. 3520-3523. https://doi.org/10.1039/b710308e
Article Title | Polymer supported naphthalene-catalysed sodium reactions |
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ERA Journal ID | 1592 |
Article Category | Article |
Authors | van den Ancker, Tania R. (Author) and Love, Cameron J. (Author) |
Journal Title | Organic and Biomolecular Chemistry |
Journal Citation | 5 (21), pp. 3520-3523 |
Number of Pages | 4 |
Year | 2007 |
Place of Publication | London, United Kingdom |
ISSN | 1477-0520 |
1477-0539 | |
Digital Object Identifier (DOI) | https://doi.org/10.1039/b710308e |
Web Address (URL) | http://pubs.rsc.org/en/Content/ArticlePDF/2007/OB/B710308E/2007-09-20?page=Search |
Abstract | Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields >80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5-100%), was quenched with chlorotrimethylsilane, water or PriCHO respectively. |
Keywords | organosodium complexes; phenylsodium; chlorobenzene; chlorotrimethylsilane; organosodium complexes; sodium powder |
ANZSRC Field of Research 2020 | 340499. Medicinal and biomolecular chemistry not elsewhere classified |
310699. Industrial biotechnology not elsewhere classified | |
340503. Organic chemical synthesis | |
Byline Affiliations | Department of Biological and Physical Sciences |
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