Polymer supported naphthalene-catalysed sodium reactions

Article


van den Ancker, Tania R. and Love, Cameron J.. 2007. "Polymer supported naphthalene-catalysed sodium reactions." Organic and Biomolecular Chemistry. 5 (21), pp. 3520-3523. https://doi.org/10.1039/b710308e
Article Title

Polymer supported naphthalene-catalysed sodium reactions

ERA Journal ID1592
Article CategoryArticle
Authorsvan den Ancker, Tania R. (Author) and Love, Cameron J. (Author)
Journal TitleOrganic and Biomolecular Chemistry
Journal Citation5 (21), pp. 3520-3523
Number of Pages4
Year2007
Place of PublicationLondon, United Kingdom
ISSN1477-0520
1477-0539
Digital Object Identifier (DOI)https://doi.org/10.1039/b710308e
Web Address (URL)http://pubs.rsc.org/en/Content/ArticlePDF/2007/OB/B710308E/2007-09-20?page=Search
Abstract

Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields >80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5-100%), was quenched with chlorotrimethylsilane, water or PriCHO respectively.

Keywordsorganosodium complexes; phenylsodium; chlorobenzene; chlorotrimethylsilane; organosodium complexes; sodium powder
ANZSRC Field of Research 2020340499. Medicinal and biomolecular chemistry not elsewhere classified
310699. Industrial biotechnology not elsewhere classified
340503. Organic chemical synthesis
Byline AffiliationsDepartment of Biological and Physical Sciences
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