Properties of natural microlayers on Australian freshwater storages and their potential to interact with artificial monolayers

Article

Pittaway, Pam and van den Ancker, Tania. 2010. "Properties of natural microlayers on Australian freshwater storages and their potential to interact with artificial monolayers." Marine and Freshwater Research. 61 (10), pp. 1083-1091. https://doi.org/10.1071/MF09159
Article Title

Properties of natural microlayers on Australian freshwater storages and their potential to interact with artificial monolayers

ERA Journal ID3285
Article CategoryArticle
AuthorsPittaway, Pam (Author) and van den Ancker, Tania (Author)
Journal TitleMarine and Freshwater Research
Journal Citation61 (10), pp. 1083-1091
Number of Pages9
Year2010
Place of PublicationMelbourne, Australia
ISSN0067-1940
1323-1650
1448-6059
Digital Object Identifier (DOI)https://doi.org/10.1071/MF09159
Web Address (URL)http://www.publish.csiro.au/?act=view_file&file_id=MF09159.pdf
Abstract

Microlayers are natural surface films derived from hydrophobic organic compounds that form on most lakes and streams. Holoarctic brown water lakes have been most commonly studied, with Australian research limited to marine microlayers. Artificial monolayers based on long-chain fatty alcohols have been applied to freshwater storages to reduce evaporative loss. As a water conservation strategy, monolayer technology was not widely adopted due to variable field performance. However, the role of natural microlayers in reducing monolayer performance has not previously been investigated.

In this study, microlayer and subsurface samples from six water storages in Queensland were characterized for water quality indices including biochemical oxygen demand, permanganate index and ultraviolet light absorbance. Microlayer enrichment in southeast Queensland is comparable to or higher than holoarctic lakes. Results indicate that microlayer compounds have the potential to disrupt monolayers in at least three ways: As substrates for microbes capable of degrading monolayer compounds, as chromophores accelerating photodegradation, and as impurities disrupting the molecular packing required to reduce evaporative loss. The knowledge gained from studying natural microlayers can also be used to benchmark novel monolayer compounds, to minimize their environmental impact on freshwater ecosystems.

KeywordsBOD; UV absorbance; permanganate index
ANZSRC Field of Research 2020300201. Agricultural hydrology
400513. Water resources engineering
410404. Environmental management
Public Notes

File reproduced in accordance with the copyright policy of the publisher/author.

Byline AffiliationsNational Centre for Engineering in Agriculture
St Saviour's College, Toowoomba, Australia
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