Glyphosate in waters and soils from genetically modified canola cultivation in Parkes, NSW, Australia

Glyphosate in waters and soils from genetically modified canola cultivation in Parkes, NSW, Australia

Investigations were conducted of farmland from the Parkes region of New South Wales, Australia, cultivated with genetically modified canola, involving the determination of glyphosate (N-(phosphonomethyl)glycine) concentrations in water and soils, and its sorption. The soils are classified as loam under the USDA system (clay 13.8-15.8%, silt 39-43%, sand 41.2-47.2%). Firstly, a low-cost fluorometric method was developed for the analysis of glyphosate in waters and soils, calibrated against analytical standards and spectrophotometric and enzyme-linked immunosorbent assay (ELISA) methods. Soil and water samples were then collected using the NEPM sampling protocol into glass containers, chilled and analysed within two weeks. The samples were collected in multiple episodes, taking account of glyphosate and pesticide crop applications. The soil and water physical and chemical properties were characterised, and glyphosate levels were determined. Field concentrations of glyphosate ranged between 0.01 - 0.067 mg/L in water and 0.10 - 0.575 mg/kg in soil. The aqueous levels lie below Australian and international drinking water guidelines, but reach a Canadian freshwater guideline. Glyphosate levels varied with time of application and rainfall events. Glyphosate sorption isotherms were also constructed by batch tests on several soils, and were fitted with Freundlich and Langmuir isotherms. Desorption tests indicated 25% to 58% of soil glyphosate is extractable by 0.1M KH2PO4.

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