The behavior of natural rubber–epoxidized natural rubber–silica composites based on wet masterbatch technique

Article


Wang, Yueqiong, Liao, Lusheng, Zhong, Jieping, He, Dongning, Xu, Kui, Yang, Changjin, Luo, Yongyue and Peng, Zheng. 2016. "The behavior of natural rubber–epoxidized natural rubber–silica composites based on wet masterbatch technique." Journal of Applied Polymer Science. 133 (26), pp. 43571-43579. https://doi.org/10.1002/app.43571
Article Title

The behavior of natural rubber–epoxidized natural rubber–silica composites based on wet masterbatch technique

ERA Journal ID1671
Article CategoryArticle
AuthorsWang, Yueqiong (Author), Liao, Lusheng (Author), Zhong, Jieping (Author), He, Dongning (Author), Xu, Kui (Author), Yang, Changjin (Author), Luo, Yongyue (Author) and Peng, Zheng (Author)
Journal TitleJournal of Applied Polymer Science
Journal Citation133 (26), pp. 43571-43579
Number of Pages9
Year2016
PublisherJohn Wiley & Sons
Place of PublicationUnited States
ISSN0021-8995
1097-4628
Digital Object Identifier (DOI)https://doi.org/10.1002/app.43571
Web Address (URL)http://onlinelibrary.wiley.com/doi/10.1002/app.43571/full
Abstract

Natural rubber–epoxidized natural rubber–silica composites were prepared by the wet masterbatch technique and the traditional dry mixing method. Performances of the composites based on different preparation methods were investigated with a moving die rheometer, an electronic universal testing machine, a dynamic mechanical analyzer, a nuclear magnetic resonance crosslink density analyzer, a rubber processing analyzer (RPA), a scanning electron microscope (SEM), and a transmission electron microscope (TEM). The RPA, SEM, and TEM analyses indicated that silica has better dispersion, lower filler–filler interaction, and better filler–rubber interaction in compounds based on the wet masterbatch technique, leading to improvements in mechanical strength and the dynamic mechanical and compression properties of the composites. It also indicates that composites prepared by the wet masterbatch technique have shorter scorch time, faster curing velocity, and higher crosslink density. The composites prepared by the wet materbatch technique also have lower rolling resistance, which is an important property for their use as a green material for the tire industry.

Keywordscomposites; mechanical properties; rubber
ANZSRC Field of Research 2020401408. Manufacturing processes and technologies (excl. textiles)
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Byline AffiliationsChinese Academy of Tropical Agricultural Sciences, China
Guangdong Ocean University, China
Institution of OriginUniversity of Southern Queensland
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