Metal-organic framework-derived transition metal chalcogenides (S, Se, and Te): Challenges, recent progress, and future directions in electrochemical energy storage and conversion systems

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Lamiel, Charmaine, Hussain, Iftikhar, Rabiee, Hesamoddin, Ogunsakin, Olakunle Richard and Zhang, Kaili. 2023. "Metal-organic framework-derived transition metal chalcogenides (S, Se, and Te): Challenges, recent progress, and future directions in electrochemical energy storage and conversion systems." Coordination Chemistry Reviews. 480. https://doi.org/10.1016/j.ccr.2023.215030
Article Title

Metal-organic framework-derived transition metal chalcogenides (S, Se, and Te): Challenges, recent progress, and future directions in electrochemical energy storage and conversion systems

ERA Journal ID1522
Article CategoryArticle
AuthorsLamiel, Charmaine, Hussain, Iftikhar, Rabiee, Hesamoddin, Ogunsakin, Olakunle Richard and Zhang, Kaili
Journal TitleCoordination Chemistry Reviews
Journal Citation480
Article Number215030
Number of Pages30
Year2023
PublisherElsevier
Place of PublicationNetherlands
ISSN0010-8545
1873-3840
Digital Object Identifier (DOI)https://doi.org/10.1016/j.ccr.2023.215030
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S001085452300019X
AbstractMetal-organic framework (MOF) is one of the well-investigated nanomaterials with favorable properties exhibiting high surface area and tailorable porosity. In energy storage systems, MOFs have been highly anticipated as templates to obtain the desired properties of MOF-based nanomaterials. Such products of MOF-derived porous carbon, metal/metal oxide, and metal/metal oxide@C have shown exemplary performance in electrochemical energy storage devices. However, the growing studies of MOF-inspired derivation into the chalcogenide group of sulfide, selenide, and telluride have not fully been explored. This review reports the development of MOFs from their initial pristine state to their highly functionalized MOF-derived forms. Particularly, we report the current methodologies and challenges for obtaining MOF-derived transition metal chalcogenides (TMC representing S, Se, and Te). Such advantages of MOF-derived TMC are then explored in electrochemical applications including batteries (lithium-ion, sodium-ion, and potassium-ion), supercapacitors, and electrocatalysis (hydrogen evolution reaction and oxygen evolution reaction). The review concludes by addressing the challenges and future perspectives of MOF toward its commercialization in electrochemical energy storage and conversion systems. © 2023 Elsevier B.V.
KeywordsBattery; Metal-organic framework; MOF; Transition metal chalcogenide; Transition metal sulfide; Transition metal selenide; Transition metal telluride; Supercapacitor; Electrocatalysis
ANZSRC Field of Research 2020400404. Electrochemical energy storage and conversion
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Byline AffiliationsUniversity of Queensland
City University of Hong Kong, China
Centre for Future Materials
School of Engineering
University of Wyoming, United States
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