Adsorption performance of an amine-functionalized MCM–41 mesoporous silica nanoparticle system for ciprofloxacin removal

Article


Rumman, Ghaida Abu, Al-Musawi, Tariq J., Sillanpää, Mika and Balarak, Davoud. 2021. "Adsorption performance of an amine-functionalized MCM–41 mesoporous silica nanoparticle system for ciprofloxacin removal." Environmental Nanotechnology, Monitoring & Management. 16. https://doi.org/10.1016/j.enmm.2021.100536
Article Title

Adsorption performance of an amine-functionalized MCM–41 mesoporous silica nanoparticle system for ciprofloxacin removal

ERA Journal ID212399
Article CategoryArticle
AuthorsRumman, Ghaida Abu, Al-Musawi, Tariq J., Sillanpää, Mika and Balarak, Davoud
Journal TitleEnvironmental Nanotechnology, Monitoring & Management
Journal Citation16
Article Number100536
Number of Pages10
Year2021
PublisherElsevier BV
Place of PublicationNetherlands
ISSN2215-1532
Digital Object Identifier (DOI)https://doi.org/10.1016/j.enmm.2021.100536
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S2215153221001112
Abstract

Antibiotic pollutants discharged from pharmaceutical industries are often present in the aquatic environment due to ineffective treatment of pharmaceutical wastewater and are hazardous to human and aquatic life. Therefore, effective treatment of antibiotic-containing wastewater is of utmost importance in the field of environmental protection. This study aims to evaluate the adsorption performance of an amine-functionalized MCM–41 mesoporous silica nanoparticles system (MCM–41–NH2) as an adsorbent for the removal of ciprofloxacin (CIP) antibiotic from aqueous solution. Surface and structural characteristics of MCM–41–NH2 were examined using scanning electron microscopy, X-ray diffraction, N2 adsorption–desorption analysis, Fourier transform infrared spectroscopy, and point of zero charge analysis. In addition, thermal stability was investigated by thermogravimetric analysis. Via the proposed treatment, 99.25% CIP removal was achieved under the following conditions: pH = 7; MCM–41–NH2 dose = 0.8 g/L; CIP concentration = 10 mg/L; adsorption time = 120 min; and shaking speed = 200 rpm. Isotherm study showed that the experimental data fitted well with the Langmuir equation. Moreover, the maximum adsorption capacity of MCM–41–NH2 for CIP was 164.3 mg/g. Thermodynamic parameters showed that the adsorption process of CIP on MCM–41–NH2 was endothermic and spontaneous. Additionally, the increase in solution temperature had a positive impact on the removal of CIP. The kinetic data obtained at different CIP concentrations (10, 25, 50, and 100 mg/L) were consistent with the pseudo-second-order model. MCM–41–NH2 could be recycled eight times in the proposed adsorption process, with a slight loss in its adsorption capacity. Compared with other adsorbents, MCM–41–NH2 was more effective for CIP removal.

KeywordsMCM–41–NH2; Ciprofloxacin; Adsorption study; Modeling; Regeneration test
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020401104. Health and ecological risk assessment
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Byline AffiliationsIsra University, Jordan
School of Engineering
University of Johannesburg, South Africa
Zahedan University of Medical Sciences, Iran
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