Application of infrared spectrum for rapid classification of dominant petroleum hydrocarbon fractions for contaminated site assessment

Article

Wang, Liang, Cheng, Ying, Lamb, Dane, Dharmarajan, Raja, Chadalavada, Sreenivasulu and Naidu, Ravi. 2019. "Application of infrared spectrum for rapid classification of dominant petroleum hydrocarbon fractions for contaminated site assessment." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 207, pp. 183-188. https://doi.org/10.1016/j.saa.2018.09.024
Article Title

Application of infrared spectrum for rapid classification of dominant petroleum hydrocarbon fractions for contaminated site assessment

ERA Journal ID34303
Article CategoryArticle
AuthorsWang, Liang (Author), Cheng, Ying (Author), Lamb, Dane (Author), Dharmarajan, Raja (Author), Chadalavada, Sreenivasulu (Author) and Naidu, Ravi (Author)
Journal TitleSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Journal Citation207, pp. 183-188
Number of Pages6
Year2019
Place of PublicationNetherlands
ISSN1386-1425
1873-3557
Digital Object Identifier (DOI)https://doi.org/10.1016/j.saa.2018.09.024
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S1386142518308709
Abstract

In this study, the infrared spectrum (4000–400 cm−1) was applied to identify and classify the different alkanes based on carbon chain length (Cn). It was found there were two bands coherent to the doublet at location 2954 and 2872 cm−1, respectively can be applied to identify the fraction of carbon chains. From C20 to C37, by the increase of the Cn, the intensities of the two bands were reduced as demonstrated. There were another two doublets existed at the region from 1480 to 1450 cm−1 and the region at 750 and 730 cm−1. It was observed the intensity of one coherent band at each of these regions was increased following the increase on the Cn. The bands center at 1462 and 730 cm−1 were increased from C20 to C37. The intensity ratio of the coherent bands can be applied to identify the Cn. Successfully identify four different petroleum products with different fractions of carbon chains in soil samples, is evidence the theory can be applied to investigate the fraction of carbon chains in soil. Coupling with handheld FTIR, it is possible to rapidly estimate the dominant fraction of Cn in soil in field.

KeywordsAlkanes; Carbon chain length (Cn); Handheld FTIR; Petroleum hydrocarbon; Rapid site assessment
ANZSRC Field of Research 2020401199. Environmental engineering not elsewhere classified
Byline AffiliationsUniversity of Newcastle
Institution of OriginUniversity of Southern Queensland
Permalink -

https://research.usq.edu.au/item/q7206/application-of-infrared-spectrum-for-rapid-classification-of-dominant-petroleum-hydrocarbon-fractions-for-contaminated-site-assessment

Log in to edit
  • 53
    total views
  • 3
    total downloads
  • 1
    views this month
  • 0
    downloads this month

Export as

Related outputs

An Alternative Method for Estimating the Peak Flow for a Regional Catchment Considering the Uncertainty via Continuous Simulation
Brown, Ian, McDougall, Kevin, Chadalavada, Sreeni and Alam, Md Jahangir. 2023. "An Alternative Method for Estimating the Peak Flow for a Regional Catchment Considering the Uncertainty via Continuous Simulation ." Water. 15 (19). https://doi.org/https://doi.org/10.3390/w15193355
Prediction of Water Quality in Reservoirs: A Comparative Assessment of Machine Learning and Deep Learning Approaches in the Case of Toowoomba, Queensland, Australia
Farzana, Syeda Zehan, Paudyal, Dev Raj, Chadalavada, Sreeni and Alam, Md Jahangir. 2023. "Prediction of Water Quality in Reservoirs: A Comparative Assessment of Machine Learning and Deep Learning Approaches in the Case of Toowoomba, Queensland, Australia." Geosciences. 13 (293). https://doi.org/10.3390/geosciences13100293
A Multi-Framework of Google Earth Engine and GEV for Spatial Analysis of Extremes in Non-Stationary Condition in Southeast Queensland, Australia
Pakdel, Hadis, Paudyal, Dev Raj, Chadalavada, Sreeni, Alam, Md Jahangir and Vazifedoust, Majid. 2023. "A Multi-Framework of Google Earth Engine and GEV for Spatial Analysis of Extremes in Non-Stationary Condition in Southeast Queensland, Australia." ISPRS International Journal of Geo-Information. 12 (9). https://doi.org/10.3390/ijgi12090370
Evaluating the role of preferential pathways in exacerbating vapour intrusion risks
Unnithan, Aravind, Bekele, Dawit, Samarasinghe, Chamila, Chadalavada, Sreenivasulu and Naidu, Ravi. 2023. "Evaluating the role of preferential pathways in exacerbating vapour intrusion risks." Journal of Hazardous Materials Advances. 10. https://doi.org/10.1016/j.hazadv.2023.100310
Climate-influenced hydrobiogeochemistry and groundwater remedy design: A review
Warner, Scott D., Bekele, Dawit, Nathanail, Paul, Chadalavada, Sreeni and Naidu, Ravi. 2023. "Climate-influenced hydrobiogeochemistry and groundwater remedy design: A review ." Remediation: the journal of environmental cleanup costs, technologies and techniques. 33 (3), pp. 187-207. https://doi.org/10.1002/rem.21753
Two-dimensional chlorinated vapour intrusion model involving advective transport of vapours with a highly permeable granular layer in the vadose zone serving as the preferential pathway
Unnithan, Aravind, Bekele, Dawit Nega, Chadalavada, Sreenivasulu and Naidu, Ravi. 2023. "Two-dimensional chlorinated vapour intrusion model involving advective transport of vapours with a highly permeable granular layer in the vadose zone serving as the preferential pathway." Science of the Total Environment. 869. https://doi.org/10.1016/j.scitotenv.2023.161743
Enhanced Bio-P removal: Past, present, and future – A comprehensive review
Diaz, Ruby, Mackey, Brendan, Chadalavada, Sreeni, kainthola, Jyoti, Heck, Phil and Goel, Ramesh. 2022. "Enhanced Bio-P removal: Past, present, and future – A comprehensive review." Chemosphere. 309 (Part 2), pp. 1-20. https://doi.org/10.1016/j.chemosphere.2022.136518
Phytotoxicity of Class B aqueous firefighting formulations, Tridol S 3 and 6% to Lemna minor
Logeshwaran, Panneerselvan, Sivaram, Anithadevi Kenday, Yadav, Meena, Chadalavada, Sreenivasulu, Naidu, Ravi and Mallavarapu, Megharaj. 2020. "Phytotoxicity of Class B aqueous firefighting formulations, Tridol S 3 and 6% to Lemna minor." Environmental Technology and Innovation. 18, pp. 1-11. https://doi.org/10.1016/j.eti.2020.100688
Smartphone-based / Fluoro-SPE for selective detection of PFAS at ppb level
Al Amin, Md., Sobhani, Zahra, Chadalavada, Sreenivasulu, Naidu, Ravi and Fang, Cheng. 2020. "Smartphone-based / Fluoro-SPE for selective detection of PFAS at ppb level." Environmental Technology and Innovation. 18, pp. 1-8. https://doi.org/10.1016/j.eti.2020.100778
Calibration of a continuous hydrologic simulation model in the urban Gowrie Creek catchment in Toowoomba, Australia
Brown, I. W., McDougall, K., Alam, Md. Jahangir, Chowdhury, R. and Chadalavada, S.. 2022. "Calibration of a continuous hydrologic simulation model in the urban Gowrie Creek catchment in Toowoomba, Australia." Journal of Hydrology: Regional Studies. 40, pp. 1-16. https://doi.org/10.1016/j.ejrh.2022.101021
Per- and poly-fluoroalkyl substances (PFAS): Current status and research needs
Naidu, R., Nadebaum, P., Fang, C., Cousins, I., Pennell, K., Conder, J., Newell, C. J., Longpre, D., Warner, S., Crosbie, N. D., Surapaneni, A., Bekele, D., Spiese, R., Bradshaw, T., Slee, D., Liu, Y., Qi, F., Mallavarapu, M., Duan, L., ..., Nathanail, P.. 2020. "Per- and poly-fluoroalkyl substances (PFAS): Current status and research needs." Environmental Technology and Innovation. 19, pp. 1-18. https://doi.org/10.1016/j.eti.2020.100915
Actively facilitated permeable reactive barrier for remediation of TCE from a low permeability aquifer: Field application
Bekele, Dawit N., Du, Jianhua, de Freitas, Leandro Gomes, Mallavarapu, Megharaj, Chadalavada, Sreenivasulu and Naidu, Ravi. 2019. "Actively facilitated permeable reactive barrier for remediation of TCE from a low permeability aquifer: Field application." Journal of Hydrology. 572, pp. 592-602. https://doi.org/10.1016/j.jhydrol.2019.03.059
Effectiveness of gravity based particle separation and soil washing for reduction of Pb in a clay loam shooting range soil
Sanderson, Peter, Thangavadivel, Kandasamy, Ranganathan, Srinivasan, Chadalavada, Sreenivasulu, Naidu, Ravi and Bowman, Mark. 2019. "Effectiveness of gravity based particle separation and soil washing for reduction of Pb in a clay loam shooting range soil." Environmental Technology and Innovation. 16, pp. 1-7. https://doi.org/10.1016/j.eti.2019.100480
A review of electrokinetically enhanced bioremediation technologies for PHs
Saini, Anish, Bekele, Dawit Nega, Chadalavada, Sreenivasulu, Fang, Cheng and Naidu, Ravi. 2020. "A review of electrokinetically enhanced bioremediation technologies for PHs." Journal of Environmental Sciences. 88, pp. 31-45. https://doi.org/10.1016/j.jes.2019.08.010
Recent advances in the analysis of per- and polyfluoroalkyl substances (PFAS) - A review
Al-Amin, Md., Sobhani, Zahra, Liu, Yanju, Dharmaraja, Raja, Chadalavada, Sreenivasulu, Naidu, Ravi, Chalker, Justin M. and Fang, Cheng. 2020. "Recent advances in the analysis of per- and polyfluoroalkyl substances (PFAS) - A review." Environmental Technology and Innovation. 19, pp. 1-24. https://doi.org/10.1016/j.eti.2020.100879
Separation and Lithological Mapping of PFAS Mixtures in the Vadose Zone at a Contaminated Site
Bekele, Dawit N., Liu, Yanju, Donaghey, Mark, Umeh, Anthony, Arachchige, Chamila S. V., Chadalavada, Sreenivasulu and Naidu, Ravi. 2020. "Separation and Lithological Mapping of PFAS Mixtures in the Vadose Zone at a Contaminated Site." Frontiers in Water. 2, pp. 1-12. https://doi.org/10.3389/frwa.2020.597810
Application of portable gas chromatography–mass spectrometer for rapid field based determination of TCE in soil vapour and groundwater
Wang, Liang, Cheng, Ying, Naidu, Ravi, Chadalavada, Sreenivasulu, Bekele, Dawit, Gell, Peter, Donaghey, Mark and Bowman, Mark. 2021. "Application of portable gas chromatography–mass spectrometer for rapid field based determination of TCE in soil vapour and groundwater." Environmental Technology and Innovation. 21, pp. 1-11. https://doi.org/10.1016/j.eti.2020.101274
Combining environmental isotopes with Contaminants of Emerging Concern (CECs) to characterise wastewater derived impacts on groundwater quality
McCance, W., Jones, O. A. H., Cendon, D. I., Edwards, M., Surapaneni, A., Chadalavada, S., Wang, S. and Currell, M.. 2020. "Combining environmental isotopes with Contaminants of Emerging Concern (CECs) to characterise wastewater derived impacts on groundwater quality." Water Research. 182, pp. 1-15. https://doi.org/10.1016/j.watres.2020.116036
Sorption of PFOS in 114 Well-Characterized Tropical and Temperate Soils: Application of Multivariate and Artificial Neural Network Analyses
Umeh, Anthony C., Naidu, Ravi, Shilpi, Sonia, Boateng, Emmanuel B., Rahman, Aminur, Cousins, Ian T., Chadalavada, Sreenivasulu, Lamb, Dane and Bowman, Mark. 2021. "Sorption of PFOS in 114 Well-Characterized Tropical and Temperate Soils: Application of Multivariate and Artificial Neural Network Analyses." Environmental Science and Technology. 55 (3), pp. 1779-1789. https://doi.org/10.1021/acs.est.0c07202
Decoupling wastewater impacts from hydrogeochemical trends in impacted groundwater resources
McCance, W., Jones, O. A. H., Cendon, D. I., Edwards, M., Surapaneni, A., Chadalavada, S. and Currell, M.. 2021. "Decoupling wastewater impacts from hydrogeochemical trends in impacted groundwater resources." Science of the Total Environment. 774, pp. 1-16. https://doi.org/10.1016/j.scitotenv.2021.145781
Electrokinetic remediation of petroleum hydrocarbon contaminated soil (I)
Saini, Anish, Bekele, Dawit Nega, Chadalavada, Sreenivasulu, Fang, Cheng and Naidu, Ravi. 2021. "Electrokinetic remediation of petroleum hydrocarbon contaminated soil (I)." Environmental Technology and Innovation. 23, pp. 1-9. https://doi.org/10.1016/j.eti.2021.101585
Insights into vapour intrusion phenomena: Current outlook and preferential pathway scenario
Unnithan, Aravind, Bekele, Dawit Nega, Chadalavada, Sreenivasulu and Naidu, Ravi. 2021. "Insights into vapour intrusion phenomena: Current outlook and preferential pathway scenario." Science of the Total Environment. 796, pp. 1-16. https://doi.org/10.1016/j.scitotenv.2021.148885
Green roof substrates—A literature review
Kader, Shuraik, Chadalavada, Sreenivasulu, Jaufer, Lizny, Spalevic, Velibor and Dudic, Branislav. 2022. "Green roof substrates—A literature review." Frontiers in Built Environment. 8, pp. 265-272. https://doi.org/https://doi.org/10.3389/fbuil.2022.1019362
Google Earth Engine as Multi-Sensor Open-Source Tool for Monitoring Stream Flow in the Transboundary River Basin: Doosti River Dam
Pakdel-Khasmakhi, Hadis, Vazifedoust, Majid, Paudyal, Dev Raj, Chadalavada, Sreeni and Alam, Md Jahangir. 2022. "Google Earth Engine as Multi-Sensor Open-Source Tool for Monitoring Stream Flow in the Transboundary River Basin: Doosti River Dam." ISPRS International Journal of Geo-Information. 11 (11), pp. 1-28. https://doi.org/10.3390/ijgi11110535
Arsenic ecotoxicology: the interface between geosphere, hydrosphere and biosphere
Bundschuh, Jochen, Bhattacharya, Prosun, Nath, Bibhash, Naidu, Ravi, Ng, Jack, Guilherme, Luiz R. G., Ma, Lena Q., Kim, Kyoung-Woong and Jean, Jiin-Shuh. 2013. "Arsenic ecotoxicology: the interface between geosphere, hydrosphere and biosphere." Journal of Hazardous Materials. 262, pp. 883-886. https://doi.org/10.1016/j.jhazmat.2013.08.019
Arsenic in hydrological processes: sources, speciation, bioavailability and management
Bhattacharya, Prosun, Naidu, Ravi, Polya, David A., Mukherjee, Abhijit, Bundschuh, Jochen and Charlet, Laurent. 2014. "Arsenic in hydrological processes: sources, speciation, bioavailability and management ." Journal of Hydrology. 518 (Part C), pp. 279-283. https://doi.org/10.1016/j.jhydrol.2014.09.017