Effects of sodium adsorption ratio and electrolyte concentration on soil saturated hydraulic conductivity

Article


Liu, Xinmin, Zhu, Yingcan, Bennett, John McLean, Wu, Laosheng and Li, Hang. 2022. "Effects of sodium adsorption ratio and electrolyte concentration on soil saturated hydraulic conductivity ." Geoderma. 414, pp. 1-8. https://doi.org/10.1016/j.geoderma.2022.115772
Article Title

Effects of sodium adsorption ratio and electrolyte concentration on soil saturated hydraulic conductivity

ERA Journal ID5257
Article CategoryArticle
AuthorsLiu, Xinmin, Zhu, Yingcan, Bennett, John McLean, Wu, Laosheng and Li, Hang
Journal TitleGeoderma
Journal Citation414, pp. 1-8
Article Number115772
Number of Pages8
Year2022
PublisherElsevier
Place of PublicationNetherlands
ISSN0016-7061
1872-6259
Digital Object Identifier (DOI)https://doi.org/10.1016/j.geoderma.2022.115772
Web Address (URL)https://www.sciencedirect.com/science/article/abs/pii/S0016706122000799
Abstract

Sodium adsorption ratio (SAR) and electrolyte concentration (EC) can significantly affect water movement in soil. However, the theoretical mechanisms behind it are rarely studied. In the present study, an analytical function between electrostatic repulsive pressure (PEDL) and SAR/EC was derived in Na-Ca mixed electrolyte solutions or soil water. Soil water SAR and EC controls PEDL through surface potential and midpoint potential between two adjacent soil particles, which consequently influences the saturated soil hydraulic conductivity (Ks). Theoretical calculations show that the PEDL decreases with increasing EC and increases with increasing SAR, and the reduction in Ks is correlated with the repulsive PEDL. Five soils of different dominant clay minerals, specifically kaolinite (K), illite (I) and montmorillonite (M), were used to investigate the relationship between PEDL and change of Ks. The soils were packed in columns and leached with a serial of solutions (constant EC values of 0.5, 1, and 2 ds m−1, respectively) with increasing SAR from 0 to infinity. Our study showed that the Ks decreases with increasing PEDL. At the inflection point of the percent of Ks reduction (Kred) vs. PEDL curve, the critical PEDL values are 8.358 ∼ 8.569 atm and Kred > 92% for the Mungana soil (M), Yarrandoo soil (M, K) and Dunholm soil (M), while the average critical PEDL value is about 12.34 atm and Kred is only ∼51.75% for the Urrbrae soil (I) and Timberlea soil (K). For a given soil, the PEDL is the determinant factor, while other factors such as soil texture and clay type can also affect Ks.

KeywordsElectrical double layer; Electrostatic interaction; Soil water movement; Surface potential
ANZSRC Field of Research 20204106. Soil sciences
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FunderCotton Research and Development Corporation
Byline AffiliationsSouthwest University, China
Centre for Sustainable Agricultural Systems (Research)
Centre for Sustainable Agricultural Systems
University of California, United States
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