An efficient approach for mitigation of efflorescence in fly ash-based geopolymer mortars under high-low humidity cycles

Article


Wu, Bo, Ma, Xue, Deng, Hao, Li, Yuxiang, Xiang, Yi and Zhu, Yingcan. 2022. "An efficient approach for mitigation of efflorescence in fly ash-based geopolymer mortars under high-low humidity cycles ." Construction and Building Materials. 317, pp. 1-10. https://doi.org/10.1016/j.conbuildmat.2021.126159
Article Title

An efficient approach for mitigation of efflorescence in fly ash-based geopolymer mortars under high-low humidity cycles

ERA Journal ID3470
Article CategoryArticle
AuthorsWu, Bo, Ma, Xue, Deng, Hao, Li, Yuxiang, Xiang, Yi and Zhu, Yingcan
Journal TitleConstruction and Building Materials
Journal Citation317, pp. 1-10
Article Number126159
Number of Pages10
Year2022
PublisherElsevier
Place of PublicationNetherlands
ISSN0950-0618
Digital Object Identifier (DOI)https://doi.org/10.1016/j.conbuildmat.2021.126159
Web Address (URL)https://www.sciencedirect.com/science/article/abs/pii/S0950061821038915
Abstract

The efflorescence of fly ash-based geopolymer (FG) is a significant factor of durability, which has been widely concerned in the application of civil engineering. Fly ash based-geopolymer mortars (FGMs) were fabricated by optimizing their water/cement (w/c) ratio from 0.6 to 0.4 as well as the addition of caltite solution (CS) in this paper. The characteristics and mechanism of efflorescence under the high-low humidity cycles were identified. These free cations in FGMs migrated in the direction of surface to form carbonate (Na2Ca(CO3)2·5H2O), resulting in efflorescence. The most effective way for FGMs to mitigate efflorescence from the obtained results was adding 1 wt% CS into the FGMs with the w/c ratio of 0.4. The filter membrane of alkaline stearate was formed by the reaction between CS and alkaline activator, and it adhered to the capillary to suppress migrating and leaching behavior of Na(H2O)n+. Efflorescence fraction was thus decreased from 92.16% to 2.82%, and the mechanical properties were simultaneously decreased by 23.17%. Adding 3 wt% CS into FGMs with the w/c ratio of 0.5 also mitigated efflorescence, the efflorescence fraction was decreased by 18.13%. With the dosage of CS increasing to 4 wt%, the efflorescence of FGMs with the w/c ratio of 0.6 could be accelerated. The results further confirmed that the trace addition of CS could obtain the optimal result for mitigating the efflorescence of the FGMs.

KeywordsCaltite; Efflorescence; Fly ash; Geopolymer; High-low humidity cycle; Mechanism
ANZSRC Field of Research 20204016. Materials engineering
Public Notes

Files associated with this item cannot be displayed due to copyright restrictions.

FunderSouthwest University of Science and Technology
Byline AffiliationsSouthwest University of Science and Technology, China
Institute for Life Sciences and the Environment
Hunan University, China
Library Services
Permalink -

https://research.usq.edu.au/item/yy35q/an-efficient-approach-for-mitigation-of-efflorescence-in-fly-ash-based-geopolymer-mortars-under-high-low-humidity-cycles

  • 54
    total views
  • 1
    total downloads
  • 1
    views this month
  • 0
    downloads this month

Export as

Related outputs

Review of porous vegetation eco-concrete (PVEC) technology: From engineering requirements to material design
Zheng, Chaowei, Zhang, Zuhua, Chen, Ziye, Wang, Dongyu, Wang, Wenjing, Zhou, Zhengning, Zhu, Yingcan, Wang, Dongmin, Wang, Hao and Jiang, Zhengwu. 2024. "Review of porous vegetation eco-concrete (PVEC) technology: From engineering requirements to material design." Composites Part B: Engineering. 279. https://doi.org/10.1016/j.compositesb.2024.111442
Selection of a stress-based soil compaction test to determine potential impact of machine wheel loads
Ali, Aram, Bennett, John McLean, Roberton, Stirling, Krwanji, Diman, Zhu, YingCan and West, David. 2024. "Selection of a stress-based soil compaction test to determine potential impact of machine wheel loads." European Journal of Soil Science. 75 (3). https://doi.org/10.1111/ejss.13501
Insight to workability, compressive strength and microstructure of lithium slag-steel slag based cement under standard condition
Zhou, Mengya, Yan, Jiahao, Fan, Jinyuan, Xu, Yuan, Lu, Yuwei, Duan, Ping, Zhu, Yingcan, Zhang, Zuhua and Lu, Zheng. 2023. "Insight to workability, compressive strength and microstructure of lithium slag-steel slag based cement under standard condition." Journal of Building Engineering. 75. https://doi.org/10.1016/j.jobe.2023.107076
Hydration Characteristics and Mechanical Properties of Cement-Based Materials Modified by Calcined Zeolite and Montmorillonite
Qin, Lingling, Zhou, Mengya, Yan, Jiahao, Duan, Ping, Zhu, Yingcan, Chen, Wei, Zhang, Zuhua and Wang, Aiguo. 2023. "Hydration Characteristics and Mechanical Properties of Cement-Based Materials Modified by Calcined Zeolite and Montmorillonite." Journal of Renewable Materials. 11 (5), pp. 2191-2207. https://doi.org/10.32604/jrm.2023.025197
Synthesis of alkali-activated uncalcined Pisha sandstone cement composites
Dong, Jingliang, Zhang, Tingting, Zhu, Yingcan, Zhang, Liqing, Jiang, Yalong and Zhu, Junhua. 2021. "Synthesis of alkali-activated uncalcined Pisha sandstone cement composites." Composites Part B: Engineering. 225, pp. 1-12. https://doi.org/10.1016/j.compositesb.2021.109311
Valorization of calcined coal gangue as coarse aggregate in concrete
Zhu, Yuanyuan, Zhu, Yingcan, Wang, Aiguo, Sun, Daosheng, Liu, Kaiwei, Liu, Peng and Chu, Yingjie. 2021. "Valorization of calcined coal gangue as coarse aggregate in concrete." Cement and Concrete Composites. 121, pp. 1-15. https://doi.org/10.1016/j.cemconcomp.2021.104057
Microstructure and melting properties of Ag–Cu–In intermediate-temperature brazing alloys
Ma, Xue, Li, Liang-Feng, Zhang, Zu-Hua, Wang, Hao, Wang, En-Ze and Qiu, Tai. 2015. "Microstructure and melting properties of Ag–Cu–In intermediate-temperature brazing alloys." Rare Metals. 34 (5), pp. 324-328. https://doi.org/10.1007/s12598-015-0484-7
Enhancing the performance of basic magnesium sulfate cement-based coral aggregate concrete through gradient composite design technology
Chu, Yingjie, Wang, Aiguo, Zhu, Yingcan, Wang, Hao, Liu, Kaiwei, Ma, Rui, Guo, Liping and Sun, Daosheng. 2021. "Enhancing the performance of basic magnesium sulfate cement-based coral aggregate concrete through gradient composite design technology." Composites Part B: Engineering. 227, pp. 1-13. https://doi.org/10.1016/j.compositesb.2021.109382
The impact of clay dispersion and migration on soil hydraulic conductivity and pore networks
Awedat, Awedat Musbah, Zhu, Yingcan, Bennett, John McLean and Raine, Steven R.. 2021. "The impact of clay dispersion and migration on soil hydraulic conductivity and pore networks." Geoderma. 404, pp. 1-12. https://doi.org/10.1016/j.geoderma.2021.115297
Conventional tillage combined with residue removal reduces growing-season methane emissions in flooded paddy (Oryza sativa L. subsp. japonica Kato) fields
Deng, Jiayu, Wang, Gang, Zhu, Yingcan, Zhou, Deyi, Zhou, Lingling, Yuan, Hongfang, Huang, Dongyan and Jia, Honglei. 2022. "Conventional tillage combined with residue removal reduces growing-season methane emissions in flooded paddy (Oryza sativa L. subsp. japonica Kato) fields." European Journal of Agronomy. 140. https://doi.org/10.1016/j.eja.2022.126612
Alkali leaching features of 3-year-old alkali activated fly ash-slag-silica fume: For a better understanding of stability
Zhu, Yingcan, Longhi, Marlon A., Wang, Aiguo, Hou, Dongshuai, Wang, Hao and Zhang, Zuhua. 2022. "Alkali leaching features of 3-year-old alkali activated fly ash-slag-silica fume: For a better understanding of stability ." Composites Part B: Engineering. 230, pp. 1-12. https://doi.org/10.1016/j.compositesb.2021.109469
Targeting Subsoil Constraints in Southern Queensland: Concept Proof of Spraying Polyacrylamide for Subsoil Stabilisation during Tillage
Zhu, Yingcan, Ali, Aram, Bennett, John McLean, Guppy, Chris and McKenzie, David. 2022. "Targeting Subsoil Constraints in Southern Queensland: Concept Proof of Spraying Polyacrylamide for Subsoil Stabilisation during Tillage ." Sustainability. 14 (20), pp. 1-16. https://doi.org/10.3390/su142013147
Research Progress of Geopolymer-based Protective Coating and Its Performance Improvement Technology
Xu, Haiyan, Yang, Xuelei, Wang, Aiguo, Zhu, Yingcan, Liu, Kaiwei, Huang, Meng and Wang, Xingyao. 2022. "Research Progress of Geopolymer-based Protective Coating and Its Performance Improvement Technology ." Cailiao Daobao/Materials Reports. 36 (19), pp. 1-7.
An analytical approach to estimating electrostatic repulsion between soil particles
Li, Yiyang, Zhu, Yingcan, Ding, Wuquan, Liu, Xinmin and Li, Hang. 2022. "An analytical approach to estimating electrostatic repulsion between soil particles ." Soil and Tillage Research. 223, pp. 1-11. https://doi.org/10.1016/j.still.2022.105488
Optimization of mix proportion of basic magnesium sulfate cement-based high-strength coral concrete
Wang, Aiguo, Huang, Meng, Chu, Yingjie, Zhu, Yingcan, Liu, Kaiwei, Guo, Liping, Liu, Peng and Sun, Daosheng. 2022. "Optimization of mix proportion of basic magnesium sulfate cement-based high-strength coral concrete ." Construction and Building Materials. 341, pp. 1-16. https://doi.org/10.1016/j.conbuildmat.2022.127709
Effects of sodium adsorption ratio and electrolyte concentration on soil saturated hydraulic conductivity
Liu, Xinmin, Zhu, Yingcan, Bennett, John McLean, Wu, Laosheng and Li, Hang. 2022. "Effects of sodium adsorption ratio and electrolyte concentration on soil saturated hydraulic conductivity ." Geoderma. 414, pp. 1-8. https://doi.org/10.1016/j.geoderma.2022.115772
A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
Ren, Jie, Zhang, Lihai, Zhu, Yingcan, Li, Zhenming and San Nicolas, Rackel. 2022. "A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid ." Frontiers in Materials. 9, pp. 1-14. https://doi.org/10.3389/fmats.2022.845349
Finite Element Modeling for Thermal Conductivity of Cement-based Encapsulation Materials
Gao, Hanyan, Zhang, Jing, Zhu, Yingcan, Guo, Ruiqian, Zhang, Wanlu, Zhang, Guoqi and Liu, Pan. 2022. "Finite Element Modeling for Thermal Conductivity of Cement-based Encapsulation Materials." 2022 23rd International Conference on Electronic Packaging Technology (ICEPT). Dalian, China 10 - 13 Aug 2022 China. IEEE (Institute of Electrical and Electronics Engineers). https://doi.org/10.1109/ICEPT56209.2022.9873392
Prediction of mechanical solutions for a laminated LCEs system fusing an analytical model and neural networks
Wang, Jue, Yuan, Weiyi, Li, Zichuan, Zhu, Yingcan, Santos, Thebano and Fan, Jiajie. 2022. "Prediction of mechanical solutions for a laminated LCEs system fusing an analytical model and neural networks ." Journal of The Mechanical Behavior of Biomedical Materials. 125, pp. 1-11. https://doi.org/10.1016/j.jmbbm.2021.104918
Advances in immobilization of radionuclide wastes by alkali activated cement and related materials
Zhu Yingcan, Zheng, Zhao, Deng, Yulin, Shi, Caijun and Zhang, Zuhua. 2022. "Advances in immobilization of radionuclide wastes by alkali activated cement and related materials ." Cement and Concrete Composites. 126, pp. 1-15. https://doi.org/10.1016/j.cemconcomp.2021.104377
Towards operational predictions of the near-term climate
Kushnir, Yochanan, Scaife, Adam A., Arritt, Raymond, Balsamo, Gianpaolo, Boer, George, Doblas-Reyes, Francisco, Hawkins, Ed, Kimoto, Masahide, Kolli, Rupa Kumar, Kumar, Arun, Matei, Daniela, Matthes, Katja, Muller, Wolfgang A., O’Kane, Terence, Perlwitz, Judith, Power, Scott, Raphael, Marilyn, Shimpo, Akihiko, Smith, Doug, ..., Wu, Bo. 2019. "Towards operational predictions of the near-term climate." Nature Climate Change. 9 (2), pp. 94-101. https://doi.org/10.1038/s41558-018-0359-7
Growing-season soil microbial respiration response to long-term no tillage and spring ridge tillage
Wang, Gang, Jia, Honglei, Zhuang, Jian, Glatzel, Stephan, Bennett, John McL. and Zhu, Yingcan. 2020. "Growing-season soil microbial respiration response to long-term no tillage and spring ridge tillage." International Journal of Agricultural and Biological Engineering. 13 (4), pp. 143-150. https://doi.org/10.25165/j.ijabe.20201304.5587
Ionicity of clay-cation bonds in relation to dispersive behavior of Mg and K soil clays as influenced by pH
Zhu, Yingcan, Marchuk, Alla and Bennett, John McLean. 2020. "Ionicity of clay-cation bonds in relation to dispersive behavior of Mg and K soil clays as influenced by pH." Clays and Clay Minerals. https://doi.org/10.1007/s42860-020-00100-x
Research Progress on Setting and Hardening of Geopolymers and Their Control
Wang, Aiguo, Wang, Xingyao, Sun, Daosheng, Zhu Yingcan, Liu, Kaiwei, Jing, Yan and Guan, Yanmei. 2021. "Research Progress on Setting and Hardening of Geopolymers and Their Control ." Cailiao Daobao/Materials Reports. 35 (13), pp. 13001-13010.
Overview of Finite-Element Analysis in Simulation of SiC Power Device Packaging
Li, Liangtao, Tang, Jiuyang, Zhang, Jon Qingchun, Zhang, Jing, Zhu, Yingcan, Zhang, Guoqi and Liu, Pan. 2021. "Overview of Finite-Element Analysis in Simulation of SiC Power Device Packaging." 2021 18th China International Forum on Solid State Lighting & 2021 7th International Forum on Wide Bandgap Semiconductors (SSLChina: IFWS). Shenzhen, China 06 - 08 Dec 2021 IEEE (Institute of Electrical and Electronics Engineers). pp. 53-57 https://doi.org/10.1109/SSLChinaIFWS54608.2021.9675174
A gentle acid-wash and pre-coating treatment of coral aggregate to manufacture high-strength geopolymer concrete
Wang, Aiguo, Lyu, Bangcheng, Zhu, Yingcan, Liu, Kaiwei, Guo, Liping and Sun, Daosheng. 2021. "A gentle acid-wash and pre-coating treatment of coral aggregate to manufacture high-strength geopolymer concrete." Construction and Building Materials. 274, pp. 1-13. https://doi.org/10.1016/j.conbuildmat.2020.121780
Reduction of hydraulic conductivity and loss of organic carbon in non-dispersive soils of different clay mineralogy is related to magnesium induced disaggregation
Zhu, Yingcan, Bennett, John McLean and Marchuk, Alla. 2019. "Reduction of hydraulic conductivity and loss of organic carbon in non-dispersive soils of different clay mineralogy is related to magnesium induced disaggregation." Geoderma. 349, pp. 1-10. https://doi.org/10.1016/j.geoderma.2019.04.019
Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites
Ma, Xue, Li, Liang-feng, Zhang, Fan, Zhang, Zu-hua, Wang, Hao and Wang, En-ze. 2018. "Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites." China Foundry. 15 (3), pp. 167-172. https://doi.org/10.1007/s41230-018-7211-6
High strength inorganic-organic polymer composites (IOPC) manufactured by mold pressing of geopolymers
Wang, Shunfeng, Ma, Xue, He, Liu, Zhang, Zuhua, Li, Liangfeng and Li, Yuxiang. 2019. "High strength inorganic-organic polymer composites (IOPC) manufactured by mold pressing of geopolymers." Construction and Building Materials. 198, pp. 501-511. https://doi.org/10.1016/j.conbuildmat.2018.11.281
In-situ transition of amorphous gels to Na-P1 zeolite in geopolymer: Mechanical and adsorption properties
Zheng, Zhao, Ma, Xue, Zhang, Zuhua and Li, Yuxiang. 2019. "In-situ transition of amorphous gels to Na-P1 zeolite in geopolymer: Mechanical and adsorption properties." Construction and Building Materials. 202, pp. 851-860. https://doi.org/10.1016/j.conbuildmat.2019.01.067
Re-examining the flocculating power of sodium, potassium, magnesium and calcium for a broad range of soils
Zhu, Yingcan, Ali, Aram, Dang, Aaditi, Wandel, Andrew P. and Bennett, John McLean. 2019. "Re-examining the flocculating power of sodium, potassium, magnesium and calcium for a broad range of soils." Geoderma. 352, pp. 422-428. https://doi.org/10.1016/j.geoderma.2019.05.041
Magnesic soils: first principle soil management strategies for increased productivity
Zhu, Yingcan. 2019. Magnesic soils: first principle soil management strategies for increased productivity. PhD Thesis Doctor of Philosophy. University of Southern Queensland. https://doi.org/10.26192/fp4j-sj70
Effect of drying procedures on pore structure and phase evolution of alkali-activated cements
Zhang, Zuhua, Zhu, Yingcan, Zhu, Huajun, Zhang, Yu, Provis, John L. and Wang, Hao. 2019. "Effect of drying procedures on pore structure and phase evolution of alkali-activated cements." Cement and Concrete Composites. 96, pp. 194-203. https://doi.org/10.1016/j.cemconcomp.2018.12.003
The transition of fly ash-based geopolymer gels into ordered structures and the effect on the compressive strength
Ma, Xue, Zhang, Zuhua and Wang, Aiguo. 2016. "The transition of fly ash-based geopolymer gels into ordered structures and the effect on the compressive strength." Construction and Building Materials. 104, pp. 25-33. https://doi.org/10.1016/j.conbuildmat.2015.12.049
Novel self-supporting zeolitic block with tunable porosity and crystallinity for water treatment
Zhang, Zuhua, Li, Liangfeng, He, Dongning, Ma, Xue, Yan, Chunjie and Wang, Hao. 2016. "Novel self-supporting zeolitic block with tunable porosity and crystallinity for water treatment." Materials Letters. 178, pp. 151-154. https://doi.org/10.1016/j.matlet.2016.04.214
Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement
Zhang, Zuhua, Li, Liangfeng, Ma, Xue and Wang, Hao. 2016. "Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement." Construction and Building Materials. 113, pp. 237-245. https://doi.org/10.1016/j.conbuildmat.2016.03.043
Conversion of local industrial wastes into greener cement through geopolymer technology: a case study of high-magnesium nickel slag
Zhang, Zuhua, Zhu, Yingcan, Yang, Tao, Li, Liangfeng, Zhu, Huajun and Wang, Hao. 2017. "Conversion of local industrial wastes into greener cement through geopolymer technology: a case study of high-magnesium nickel slag." Journal of Cleaner Production. 141, pp. 463-471. https://doi.org/10.1016/j.jclepro.2016.09.147
Rapid method for assessment of soil structural stability by turbidimeter
Zhu, Yingcan, Marchuk, Alla and Bennett, John McLean. 2016. "Rapid method for assessment of soil structural stability by turbidimeter." Soil Science Society of America Journal. 80 (6), pp. 1629-1637. https://doi.org/10.2136/sssaj2016.07.0222
Effects of rare earth La on microstructure and properties of Ag-21Cu-25Sn alloy ribbon prepared by melt spinning
Ma, Xue, Li, Liangfeng, Zhang, Zuhua, Wang, Hao, Wang, Enze and Qiu, Tai. 2015. "Effects of rare earth La on microstructure and properties of Ag-21Cu-25Sn alloy ribbon prepared by melt spinning ." Materials and Design. 83, pp. 1-5. https://doi.org/10.1016/j.matdes.2015.05.083
The importance of fly ash property in the manufacture of geopolymers
Zhang, Zuhua, Zhu, Yingcan, Reid, Andrew and Wang, Hao. 2014. "The importance of fly ash property in the manufacture of geopolymers." Shi, Caijun and Shen, Xiaodong (ed.) 2nd International Conference on Advances in Chemically Activated Materials (CAM 2014). Changsha, China 01 - 03 Jun 2014 Bagneux, France.
Durability of alkali-activated fly ash concrete: chloride penetration in pastes and mortars
Zhu, Huajun, Zhang, Zuhua, Zhu, Yingcan and Tian, Liang. 2014. "Durability of alkali-activated fly ash concrete: chloride penetration in pastes and mortars." Construction and Building Materials. 65, pp. 51-59. https://doi.org/10.1016/j.conbuildmat.2014.04.110
Using fly ash to partially substitute metakaolin in geopolymer synthesis
Zhang, Zuhua, Wang, Hao, Zhu, Yingcan, Reid, Andrew, Provis, John L. and Bullen, Frank. 2014. "Using fly ash to partially substitute metakaolin in geopolymer synthesis." Applied Clay Science. 88-89, pp. 194-201. https://doi.org/10.1016/j.clay.2013.12.025
Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide
Zhang, Zuhua, Wang, Hao, Provis, John L., Bullen, Frank, Reid, Andrew and Zhu, Yingcan. 2012. "Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide." Thermochimica Acta. 539, pp. 23-33. https://doi.org/10.1016/j.tca.2012.03.021
Effects of halloysite in kaolin on the formation and properties of geopolymers
Zhang, Z., Wang, H., Yao, X. and Zhu, Y.. 2012. "Effects of halloysite in kaolin on the formation and properties of geopolymers." Cement and Concrete Composites. 34 (5), pp. 709-715. https://doi.org/10.1016/j.cemconcomp.2012.02.003