Fast responsive and morphologically robust thermo-responsive hydrogel nanofibres from poly(N-isopropylacrylamide) and POSS crosslinker

Article

Wang, Jing, Sutti, Alessandra, Wang, Xungai and Lin, Tong. 2011. "Fast responsive and morphologically robust thermo-responsive hydrogel nanofibres from poly(N-isopropylacrylamide) and POSS crosslinker." Soft Matter. 7 (9), pp. 4364-4369. https://doi.org/10.1039/c1sm00010a
Article Title

Fast responsive and morphologically robust thermo-responsive hydrogel nanofibres from poly(N-isopropylacrylamide) and POSS crosslinker

ERA Journal ID30185
Article CategoryArticle
AuthorsWang, Jing (Author), Sutti, Alessandra (Author), Wang, Xungai (Author) and Lin, Tong (Author)
Journal TitleSoft Matter
Journal Citation7 (9), pp. 4364-4369
Number of Pages6
Year2011
Place of PublicationLondon, United Kingdom
ISSN1744-683X
1744-6848
Digital Object Identifier (DOI)https://doi.org/10.1039/c1sm00010a
Web Address (URL)http://dro.deakin.edu.au/eserv/DU:30034677/wang-fastresponsive-2011.pdf
Abstract

Stable thermo-responsive hydrogel nanofibres have been prepared by electrospinning of commercial poly(N-isopropylacrylamide) (PNIPAM) in the presence of a polyhedral oligomeric silsesquioxane (POSS) possessing eight epoxide groups and of an organic-base catalyst, followed by a heat curing treatment. The nanofibres showed excellent hydrogel characteristics with fast swelling and de-swelling responses triggered by temperature changes. They were also morphologically robust as their physical integrity was preserved upon repeated hydration/dehydration cycles and exposure to solvents.

Keywordsbase catalyst; crosslinker; epoxide groups; fast responsive; N-isopropylacrylamides; nanofibres; physical integrity; poly(N-isopropyl acrylamide) (pNIPAM); polyhedral oligomeric silsesquioxanes; temperature changes; thermo-responsive
ANZSRC Field of Research 2020401807. Nanomaterials
340601. Catalysis and mechanisms of reactions
340399. Macromolecular and materials chemistry not elsewhere classified
Public Notes

© 2011 The Royal Society of Chemistry. This publication is copyright. It may be reproduced in whole or in part for the purposes of study, research, or review, but is subject to the inclusion of an acknowledgment of the source.

Byline AffiliationsDeakin University
Institution of OriginUniversity of Southern Queensland
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