Thermo-responsive Hercosett/Poly(N-isopropylacrylamide) films: a new, fast, optically responsive coating

Article


Wang, Jing, Sutti, Alessandra, Wang, Xungai and Lin, Tong. 2012. "Thermo-responsive Hercosett/Poly(N-isopropylacrylamide) films: a new, fast, optically responsive coating." Journal of Colloid and Interface Science. 369 (1), pp. 231-237. https://doi.org/10.1016/j.jcis.2011.11.035
Article Title

Thermo-responsive Hercosett/Poly(N-isopropylacrylamide) films: a new, fast, optically responsive coating

ERA Journal ID1454
Article CategoryArticle
AuthorsWang, Jing (Author), Sutti, Alessandra (Author), Wang, Xungai (Author) and Lin, Tong (Author)
Journal TitleJournal of Colloid and Interface Science
Journal Citation369 (1), pp. 231-237
Number of Pages7
Year2012
PublisherElsevier
Place of PublicationMaryland Heights, MO. United States
ISSN0021-9797
1095-7103
Digital Object Identifier (DOI)https://doi.org/10.1016/j.jcis.2011.11.035
Web Address (URL)http://www.sciencedirect.com/science/article/pii/S0021979711014111#
Abstract

Poly(N-isopropylacrylamide) (PNIPAM) is a common thermo-responsive, water-soluble polymer, while Hercosett is a cationic resin commonly employed in the paper industry. In this paper, Hercosettâ„¢ and poly(N-isopropylacrylamide) (PNIPAM) nanoparticles were used to prepare composite films that show thermo-responsive behavior and swelling-shrinking properties in water. First, size-controlled PNIPAM hydrogel nanoparticles were synthesized. These were then embedded within a matrix of the cationic resin Kymene 577H by film casting. The distribution of nanoparticles in the resin film was investigated. The thermo-responsive properties of the as-synthesized PNIPAM hydrogel nanoparticles and of the composite films were characterized together with the repeatability of the swelling-shrinking cycles. The presence of nanoparticles endowed the film with highly enhanced water retention (in comparison with resin-only films) and, most importantly, thermo-responsiveness. A very fast optical and morphological response was in fact observed. Due to the dual (optical and morphological) response, this new system is suitable for applications in optical or morphological actuation and gating.

Keywordsfilm; Hercosett; hydrogel; optical actuator; poly(N-isopropylacrylamide); thermo-responsive
ANZSRC Field of Research 2020340306. Polymerisation mechanisms
340601. Catalysis and mechanisms of reactions
340399. Macromolecular and materials chemistry not elsewhere classified
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Byline AffiliationsDeakin University
Institution of OriginUniversity of Southern Queensland
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