Impact of varied zeolite materials on nickel catalysts in CO2 methanation

Article

Yan, Penghui, Peng, Hong, Wu, Xuankun, Rabiee, Hesamoddin, Weng, Yilun, Konarova, Muxina, Vogrin, John, Rozhkovskaya, Alexandra and Zhu, Zhonghua. 2024. "Impact of varied zeolite materials on nickel catalysts in CO2 methanation." Journal of Catalysis. 432. https://doi.org/10.1016/j.jcat.2024.115439
Article Title

Impact of varied zeolite materials on nickel catalysts in CO2 methanation

ERA Journal ID1451
Article CategoryArticle
AuthorsYan, Penghui, Peng, Hong, Wu, Xuankun, Rabiee, Hesamoddin, Weng, Yilun, Konarova, Muxina, Vogrin, John, Rozhkovskaya, Alexandra and Zhu, Zhonghua
Journal TitleJournal of Catalysis
Journal Citation432
Article Number115439
Number of Pages11
Year2024
PublisherElsevier
Place of PublicationUnited States
ISSN0021-9517
1090-2694
Digital Object Identifier (DOI)https://doi.org/10.1016/j.jcat.2024.115439
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S0021951724001520
AbstractNi catalysts supported on 4A, 5A, 13X, ZSM-5, and BEA zeolites were prepared using the vacuum-heating method for CO2 methanation. These support materials play a pivotal role in shaping the catalysts' properties and their catalytic performance. High-resolution high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectroscopy (EDS) mappings suggest a significant concentration of Ni nanoparticles situated on the external surfaces of catalysts with low Si/Al ratios zeolites (Ni-4A, Ni-5A, and Ni-13X). These Ni nanoparticles exhibit characteristics of weaker metal-support interaction, lower metal reduction temperatures, and moderate H2 adsorption activity. Moreover, these low Si/Al ratio zeolites demonstrate robust CO2 adsorption activity. These properties endow Ni-5A and Ni-13X catalysts with heightened CO2 conversion (70.4–70.9%) and methane selectivity (92.4–96.4%). In contrast, high Si/Al ratio zeolite-based catalysts (Ni-ZSM-5 and Ni-BEA) exhibit smaller Ni particles, strong metal-support interaction and weaker CO2 adsorption activity, resulting in reduced CO2 methanation activity and decreased methane selectivity (71.2–73.4%). The normalized CO2 conversion rate presents a correlation with the average Ni particle size.
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020340601. Catalysis and mechanisms of reactions
Byline AffiliationsUniversity of Queensland
Centre for Future Materials
Zeotech, Australia
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Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction
Zhuang, Linzhou, Ge, Lei, Yang, Yisu, Li, Mengran, Jia, Yi, Yao, Xiangdong and Zhu, Zhonghua. 2017. "Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction." Advanced Materials. 29 (17), p. 1606793. https://doi.org/10.1002/adma.201606793
A new cathode for solid oxide fuel cells capable of in situ electrochemical regeneration
Zhou, Wei, Shao, Zongping, Liang, Fengli, Chen, Zhi-Gang, Zhu, Zhonghua, Jin, Wanqin and Xu, Nanping. 2011. "A new cathode for solid oxide fuel cells capable of in situ electrochemical regeneration." Journal of Materials Chemistry. 21 (39), pp. 15343-15351. https://doi.org/10.1039/c1jm12660a
Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction
Zhou, Wei, Sunarso, Jaka, Chen, Zhi Gang, Ge, Lei, Motuzas, Julius, Zou, Jin, Wang, Guoxiong, Julbe, Anne and Zhu, Zhonghua. 2011. "Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction." Energy and Environmental Science. 4 (3), pp. 872-875. https://doi.org/10.1039/c0ee00451k
Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation
Sun, Hongqi, Wang, Yuxian, Liu, Shizhen, Ge, Lei, Wang, Li, Zhu, Zhonghua and Wang, Shaobin. 2013. "Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation." Chemical Communications. 49 (85), pp. 9914-9916. https://doi.org/10.1039/C3CC43401J
In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption
Yang, Ying, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2014. "In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption." Dalton Transactions: an international journal of inorganic chemistry. 43 (19), pp. 7028-7036. https://doi.org/10.1039/c3dt53191k
Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance
Lin, Rijia, Ge, Lei, Hou, Lei, Strounina, Ekaterina, Rudolph, Victor and Zhu, Zhonghua. 2014. "Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance." ACS Applied Materials and Interfaces. 6 (8), pp. 5609-5618. https://doi.org/10.1021/am500081e
Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells
Niu, Yingjie, Sunarso, Jaka, Zhou, Wei, Liang, Fengli, Ge, Lei, Zhu, Zhonghua and Shao, Zongping. 2011. "Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells." International Journal of Hydrogen Energy. 36 (4), pp. 3179-3186. https://doi.org/10.1016/j.ijhydene.2010.11.109
Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells
Zhou, Wei, Sunarso, Jaka, Motuzas, Julius, Liang, Fengli, Chen, Zhigang, Ge, Lei, Liu, Shaomin, Julbe, Anne and Zhu, Zhonghua. 2011. "Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells." Chemistry of Materials. 23 (6), pp. 1618-1624. https://doi.org/10.1021/cm103534x
Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays
Ge, Lei, Chen, Jiuling, Chen, Jun, Zhu, Zhonghua and Rudolph, Victor. 2012. "Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays." Journal of Nanoscience and Nanotechnology. 12 (3), pp. 2722-2732. https://doi.org/10.1166/jnn.2012.5726
A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles
Wang, Li, Ge, Lei, Rufford, Thomas E., Chen, Jiuling, Zhou, Wei, Zhu, Zhonghua and Rudolph, Victor. 2011. "A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles." Carbon. 49 (6), pp. 2022-2032. https://doi.org/10.1016/j.carbon.2011.01.028
Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location
Ge, Lei, Zhu, Zhonghua, Li, Feng, Liu, Shaomin, Wang, Li, Tang, Xuegang and Rudolph, Victor. 2011. "Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 115 (14), pp. 6661-6670. https://doi.org/10.1021/jp1120965
Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane
Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane." Separation and Purification Technology. 78 (1), pp. 76-82. https://doi.org/10.1016/j.seppur.2011.01.024
Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen
Wang, Li, Chen, Jiuling, Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen." Energy and Fuels. 25 (8), pp. 3408-3416. https://doi.org/10.1021/ef200719v
Vertically-aligned carbon nanotube membranes for hydrogen separation
Ge, Lei, Wang, Li, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Vertically-aligned carbon nanotube membranes for hydrogen separation." RSC Advances: an international journal to further the chemical sciences. 2 (12), pp. 5329-5336. https://doi.org/10.1039/c2ra00031h
Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer
Ge, Lei, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer." RSC Advances: an international journal to further the chemical sciences. 2 (31), pp. 11793-11800. https://doi.org/10.1039/c2ra21460a
Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation
Ge, Lei, Zhou, Wei, Du, Aijun and Zhu, Zhonghua. 2012. "Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 116 (24), pp. 13264-13270. https://doi.org/10.1021/jp3035105
The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites
Tang, Xue‐Gang, Hou, Meng, Ge, Lei, Zou, Jin, Truss, Rowan, Yang, Wei, Yang, Ming‐Bo, Zhu, Zhong-Hua and Bao, Rui‐Ying. 2012. "The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites." Journal of Applied Polymer Science. 125 (S1), pp. E592-E600. https://doi.org/10.1002/app.36671
Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction
Zhou, Wei, Ge, Lei, Chen, Zhi-Gang, Liang, Fengli, Xu, Hong-Yi, Motuzas, Julius, Julbe, Anne and Zhu, Zhonghua. 2011. "Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction." Chemistry of Materials. 23 (18), pp. 4193-4198. https://doi.org/10.1021/cm201439d
Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation
Ge, Lei, Zhou, Wei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation." Journal of Materials Chemistry A. 1 (21), pp. 6350-6358. https://doi.org/10.1039/c3ta11131h
Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface." RSC Advances: an international journal to further the chemical sciences. 3 (31), pp. 12641-12647. https://doi.org/10.1039/c3ra41208c
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 117 (8), pp. 4141-4151. https://doi.org/10.1021/jp312491m
Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture
Ge, Lei, Wang, Li, Rudolph, Victor and Zhu, Zhonghua. 2013. "Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture." RSC Advances: an international journal to further the chemical sciences. 3 (47), pp. 25360-25366. https://doi.org/10.1039/c3ra44250k
High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction
Ge, Lei, Yang, Ying, Wang, Li, Zhou, Wei, De Marco, Roland, Chen, Zhigang, Zou, Jin and Zhu, Zhonghua. 2015. "High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction." Carbon. 82 (C), pp. 417-424. https://doi.org/10.1016/j.carbon.2014.10.085
An experimental and simulation study of binary adsorption in metal–organic frameworks
Yang, Ying, Sitprasert, Chatcharin, Rufford, Thomas E., Ge, Lei, Shukla, Pradeep, Wang, Shaobin, Rudolph, Victor and Zhu, Zhonghua. 2015. "An experimental and simulation study of binary adsorption in metal–organic frameworks." Separation and Purification Technology. 146, pp. 136-142. https://doi.org/10.1016/j.seppur.2015.03.041
Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation
Lin, Rijia, Ge, Lei, Liu, Shaomin, Rudolph, Victor and Zhu, Zhonghua. 2015. "Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation." ACS Applied Materials and Interfaces. 7 (27), pp. 14750-14757. https://doi.org/10.1021/acsami.5b02680
Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand
Yang, Ying, Lin, Rijia, Ge, Lei, Hou, Lei, Bernhardt, Paul, Rufford, Thomas E., Wang, Shaobin, Rudolph, Victor, Wang, Yaoyu and Zhu, Zhonghua. 2015. "Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand." Dalton Transactions: an international journal of inorganic chemistry. 44 (17), pp. 8190-8197. https://doi.org/10.1039/C4DT03927K
Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler." Journal of Materials Chemistry A. 4 (16), pp. 6084-6090. https://doi.org/10.1039/c5ta10553f
Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation." ACS Applied Materials and Interfaces. 8 (46), pp. 32041-32049. https://doi.org/10.1021/acsami.6b11074
Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation
Lu, Xuemei, Peng, Yuelian, Ge, Lei, Lin, Rijia, Zhu, Zhonghua and Liu, Shaomin. 2016. "Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation." Journal of Membrane Science. 505, pp. 61-69. https://doi.org/10.1016/j.memsci.2015.12.042