Interfacial engineering of polymer-MOF composite by in situ vitrification
Article
Lin, Rijia, Hou, Jingwei, Li, Mengran, Wang, Zhanke, Ge, Lei, Li, Shichun, Smart, Simon, Zhu, Zhonghua, Bennett, Thomas D. and Chen, Vicki. 2020. "Interfacial engineering of polymer-MOF composite by in situ vitrification." Chemical Communications. 56 (25), pp. 3609-3612. https://doi.org/10.1039/d0cc00664e
Article Title | Interfacial engineering of polymer-MOF composite by in situ vitrification |
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ERA Journal ID | 1319 |
Article Category | Article |
Authors | Lin, Rijia (Author), Hou, Jingwei (Author), Li, Mengran (Author), Wang, Zhanke (Author), Ge, Lei (Author), Li, Shichun (Author), Smart, Simon (Author), Zhu, Zhonghua (Author), Bennett, Thomas D. (Author) and Chen, Vicki (Author) |
Journal Title | Chemical Communications |
Journal Citation | 56 (25), pp. 3609-3612 |
Number of Pages | 5 |
Year | 2020 |
Publisher | The Royal Society of Chemistry |
Place of Publication | United Kingdom |
ISSN | 1359-7345 |
1364-548X | |
Digital Object Identifier (DOI) | https://doi.org/10.1039/d0cc00664e |
Web Address (URL) | https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc00664e#!divAbstract |
Abstract | Non-stoichoimetric crystalline ZIF-62 was used as the filler for a 6FDA-DAM polyimide-based composite membrane. In situ melting and vitrification of ZIF-62 was then performed, to yield the ZIF-62 glass phase (agZIF-62), within the polymer matrix. Focus ion beam scanning electron microscopy (FIB-SEM), thermal characterisation and membrane separation tests demonstrate the filling of voids at the MOF/polymer interface from the liquid phase of ZIF-62. |
Keywords | Mixed-matrix membranes; metal-organic framework; gas separation; performance; liquid; films |
ANZSRC Field of Research 2020 | 340399. Macromolecular and materials chemistry not elsewhere classified |
400409. Separation technologies | |
Byline Affiliations | University of Queensland |
Centre for Future Materials | |
China Academy of Engineering Physics, China | |
University of Cambridge, United Kingdom | |
Institution of Origin | University of Southern Queensland |
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