Unlocking the role of Ni-Fe species in CO2 methanation

Article

Yan, Penghui, Peng, Hong, Zhang, Xi, Rabiee, Hesamoddin, Ahmed, Mohamed, Weng, Yilun, Rozhkovskaya, Alexandra, Vogrin, John, Konarova, Muxina and Zhu, Zhonghua. 2024. "Unlocking the role of Ni-Fe species in CO2 methanation." Fuel: the science and technology of fuel and energy. 374. https://doi.org/10.1016/j.fuel.2024.132373
Article Title

Unlocking the role of Ni-Fe species in CO2 methanation

ERA Journal ID3883
Article CategoryArticle
AuthorsYan, Penghui, Peng, Hong, Zhang, Xi, Rabiee, Hesamoddin, Ahmed, Mohamed, Weng, Yilun, Rozhkovskaya, Alexandra, Vogrin, John, Konarova, Muxina and Zhu, Zhonghua
Journal TitleFuel: the science and technology of fuel and energy
Journal Citation374
Article Number132373
Number of Pages11
Year2024
PublisherElsevier
Place of PublicationUnited Kingdom
ISSN0016-2361
1873-7153
Digital Object Identifier (DOI)https://doi.org/10.1016/j.fuel.2024.132373
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S0016236124015217
AbstractThe conversion of CO2 to methane has garnered immense interest, owing to its pivotal roles in reducing carbon emissions and producing environmentally friendly natural gas. This study explores the application of 13X zeolite-supported Ni-Fe catalysts with varying Ni/Fe ratios in CO2 methanation. Structural analyses reveal the formation of Ni-Fe alloy species. Specifically, the Ni-Fe species induce a high binding energy shift for Fe and a low energy shift for Ni species. Additionally, the presence of Ni-Fe species results in a slight increase in the reduction temperature for Ni species, while significantly lowering the reduction temperature of Fe species. Comparative assessments demonstrate that Ni-Fe species exhibit diminished hydrogenation activity in comparison to monometallic Ni species, resulting in reduced CO2 conversion and CH4 selectivity with increased Fe/Ni ratios. Notably, 5Ni-5Fe-13X and 2Ni-8Fe-13X catalysts display heightened activity in the conversion of CO2 to CO and ethane. Furthermore, this study finds that the blockage of micropores does not significantly affect the catalyst’s methanation activity, suggesting the small metal species in the micropores did not promote the CO2 methanation activity. In situ DRIFTS reveals that the formate intermediate is promoted by the presence of Ni species, whereas the formation of CO intermediate is facilitated by Ni-Fe species. These insights deepen our grasp of the structural and catalytic attributes inherent to Ni-Fe species in the context of CO2 conversion, fostering a more comprehensive understanding of their functionality in this critical process.
KeywordsCO2 methanation; Zeolite X ; Nickel; Iron; Hydrogenation
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020401907. Petroleum and reservoir engineering
Byline AffiliationsUniversity of Queensland
Centre for Future Materials
Zeotech, Australia
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Metal organic frameworks based mixed matrix membrane: An overview on filler/polymer interface
Lin, Rijia, Villacorta Hernandez, Byron, Ge, Lei and Zhu, Zhonghua. 2018. "Metal organic frameworks based mixed matrix membrane: An overview on filler/polymer interface." Journal of Materials Chemistry A. 6 (2), pp. 293-312. https://doi.org/10.1039/C7TA07294E
Enabling process intensification by 3D printing of catalytic structures
Konarova, Muxina, Aslam, Waqas, Ge, Lei, Ma, Qing, Tang, Fengqiu, Rudolph, Victor and Beltramini, Jorge Norberto. 2017. "Enabling process intensification by 3D printing of catalytic structures." ChemCatChem. 9 (21), pp. 4132-4138. https://doi.org/10.1002/cctc.201700829
Activated carbon derived from bio-waste hemp hurd and retted hemp hurd for CO2 adsorption
Liu, Shan, Ge, Lei, Gao, Shuai, Zhuang, Linzhou, Zhu, Zhonghua and Wang, Hao. 2017. "Activated carbon derived from bio-waste hemp hurd and retted hemp hurd for CO2 adsorption." Composites Communications. 5, pp. 27-30. https://doi.org/10.1016/j.coco.2017.06.002
Effect of sonication and hydrogen peroxide oxidation of carbon nanotube modifiers on the microstructure of pitch-derived activated carbon foam discs
Gao, Shuai, Villacorta, Byron S., Ge, Lei, Rufford, Thomas E. and Zhu, Zhonghua. 2017. "Effect of sonication and hydrogen peroxide oxidation of carbon nanotube modifiers on the microstructure of pitch-derived activated carbon foam discs." Carbon. 124, pp. 142-151. https://doi.org/10.1016/j.carbon.2017.08.036
Effect of hydrogen peroxide oxidation of carbon nanotube additives on the microstructure of pitch-derived activated carbon foam
Villacorta, Byron, Gao, Shuai, Ge, Lei and Zhu, Zhonghua. 2016. "Effect of hydrogen peroxide oxidation of carbon nanotube additives on the microstructure of pitch-derived activated carbon foam." 23rd American Biennial Conference on Carbon (Carbon'97) 2016. Pennsylvania, United States 10 - 15 Jul 2016
Functionalization of carbon nanotubes for catalytic applications
Wang, Li, Ge, Lei, Rufford, Thomas and Zhu, Zhonghua. 2015. "Functionalization of carbon nanotubes for catalytic applications." Chen, Ying (Ian) (ed.) Nanotubes and nanosheets: functionalization and applications of boron nitride and Other nanomaterials. Boca Raton, FL, United States. CRC Press. pp. 409-440
The preparation of activated carbon discs from tar pitch and coal powder for adsorption of CO 2, CH 4 and N 2
Gao, Shuai, Ge, Lei, Rufford, Thomas E. and Zhu, Zhonghua. 2017. "The preparation of activated carbon discs from tar pitch and coal powder for adsorption of CO 2, CH 4 and N 2." Microporous and Mesoporous Materials. 238, pp. 19-26. https://doi.org/10.1016/j.micromeso.2016.08.004
Surface-etched halloysite nanotubes in mixed matrix membranes for efficient gas separation
Ge, Lei, Lin, Rijia, Wang, Li, Rufford, Thomas E., Villacorta, Byron, Liu, Shaomin, Liu, Lian X. and Zhu, Zhonghua. 2017. "Surface-etched halloysite nanotubes in mixed matrix membranes for efficient gas separation." Separation and Purification Technology. 173, pp. 63-71. https://doi.org/10.1016/j.seppur.2016.09.015
Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction
Zhuang, Linzhou, Ge, Lei, Yang, Yisu, Li, Mengran, Jia, Yi, Yao, Xiangdong and Zhu, Zhonghua. 2017. "Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction." Advanced Materials. 29 (17), p. 1606793. https://doi.org/10.1002/adma.201606793
A new cathode for solid oxide fuel cells capable of in situ electrochemical regeneration
Zhou, Wei, Shao, Zongping, Liang, Fengli, Chen, Zhi-Gang, Zhu, Zhonghua, Jin, Wanqin and Xu, Nanping. 2011. "A new cathode for solid oxide fuel cells capable of in situ electrochemical regeneration." Journal of Materials Chemistry. 21 (39), pp. 15343-15351. https://doi.org/10.1039/c1jm12660a
Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction
Zhou, Wei, Sunarso, Jaka, Chen, Zhi Gang, Ge, Lei, Motuzas, Julius, Zou, Jin, Wang, Guoxiong, Julbe, Anne and Zhu, Zhonghua. 2011. "Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction." Energy and Environmental Science. 4 (3), pp. 872-875. https://doi.org/10.1039/c0ee00451k
Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation
Sun, Hongqi, Wang, Yuxian, Liu, Shizhen, Ge, Lei, Wang, Li, Zhu, Zhonghua and Wang, Shaobin. 2013. "Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation." Chemical Communications. 49 (85), pp. 9914-9916. https://doi.org/10.1039/C3CC43401J
In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption
Yang, Ying, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2014. "In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption." Dalton Transactions: an international journal of inorganic chemistry. 43 (19), pp. 7028-7036. https://doi.org/10.1039/c3dt53191k
Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance
Lin, Rijia, Ge, Lei, Hou, Lei, Strounina, Ekaterina, Rudolph, Victor and Zhu, Zhonghua. 2014. "Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance." ACS Applied Materials and Interfaces. 6 (8), pp. 5609-5618. https://doi.org/10.1021/am500081e
Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells
Niu, Yingjie, Sunarso, Jaka, Zhou, Wei, Liang, Fengli, Ge, Lei, Zhu, Zhonghua and Shao, Zongping. 2011. "Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells." International Journal of Hydrogen Energy. 36 (4), pp. 3179-3186. https://doi.org/10.1016/j.ijhydene.2010.11.109
Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells
Zhou, Wei, Sunarso, Jaka, Motuzas, Julius, Liang, Fengli, Chen, Zhigang, Ge, Lei, Liu, Shaomin, Julbe, Anne and Zhu, Zhonghua. 2011. "Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells." Chemistry of Materials. 23 (6), pp. 1618-1624. https://doi.org/10.1021/cm103534x
Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays
Ge, Lei, Chen, Jiuling, Chen, Jun, Zhu, Zhonghua and Rudolph, Victor. 2012. "Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays." Journal of Nanoscience and Nanotechnology. 12 (3), pp. 2722-2732. https://doi.org/10.1166/jnn.2012.5726
A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles
Wang, Li, Ge, Lei, Rufford, Thomas E., Chen, Jiuling, Zhou, Wei, Zhu, Zhonghua and Rudolph, Victor. 2011. "A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles." Carbon. 49 (6), pp. 2022-2032. https://doi.org/10.1016/j.carbon.2011.01.028
Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location
Ge, Lei, Zhu, Zhonghua, Li, Feng, Liu, Shaomin, Wang, Li, Tang, Xuegang and Rudolph, Victor. 2011. "Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 115 (14), pp. 6661-6670. https://doi.org/10.1021/jp1120965
Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane
Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane." Separation and Purification Technology. 78 (1), pp. 76-82. https://doi.org/10.1016/j.seppur.2011.01.024
Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen
Wang, Li, Chen, Jiuling, Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen." Energy and Fuels. 25 (8), pp. 3408-3416. https://doi.org/10.1021/ef200719v
Vertically-aligned carbon nanotube membranes for hydrogen separation
Ge, Lei, Wang, Li, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Vertically-aligned carbon nanotube membranes for hydrogen separation." RSC Advances: an international journal to further the chemical sciences. 2 (12), pp. 5329-5336. https://doi.org/10.1039/c2ra00031h
Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer
Ge, Lei, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer." RSC Advances: an international journal to further the chemical sciences. 2 (31), pp. 11793-11800. https://doi.org/10.1039/c2ra21460a
Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation
Ge, Lei, Zhou, Wei, Du, Aijun and Zhu, Zhonghua. 2012. "Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 116 (24), pp. 13264-13270. https://doi.org/10.1021/jp3035105
The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites
Tang, Xue‐Gang, Hou, Meng, Ge, Lei, Zou, Jin, Truss, Rowan, Yang, Wei, Yang, Ming‐Bo, Zhu, Zhong-Hua and Bao, Rui‐Ying. 2012. "The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites." Journal of Applied Polymer Science. 125 (S1), pp. E592-E600. https://doi.org/10.1002/app.36671
Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction
Zhou, Wei, Ge, Lei, Chen, Zhi-Gang, Liang, Fengli, Xu, Hong-Yi, Motuzas, Julius, Julbe, Anne and Zhu, Zhonghua. 2011. "Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction." Chemistry of Materials. 23 (18), pp. 4193-4198. https://doi.org/10.1021/cm201439d
Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation
Ge, Lei, Zhou, Wei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation." Journal of Materials Chemistry A. 1 (21), pp. 6350-6358. https://doi.org/10.1039/c3ta11131h
Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface." RSC Advances: an international journal to further the chemical sciences. 3 (31), pp. 12641-12647. https://doi.org/10.1039/c3ra41208c
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 117 (8), pp. 4141-4151. https://doi.org/10.1021/jp312491m
Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture
Ge, Lei, Wang, Li, Rudolph, Victor and Zhu, Zhonghua. 2013. "Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture." RSC Advances: an international journal to further the chemical sciences. 3 (47), pp. 25360-25366. https://doi.org/10.1039/c3ra44250k
High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction
Ge, Lei, Yang, Ying, Wang, Li, Zhou, Wei, De Marco, Roland, Chen, Zhigang, Zou, Jin and Zhu, Zhonghua. 2015. "High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction." Carbon. 82 (C), pp. 417-424. https://doi.org/10.1016/j.carbon.2014.10.085
An experimental and simulation study of binary adsorption in metal–organic frameworks
Yang, Ying, Sitprasert, Chatcharin, Rufford, Thomas E., Ge, Lei, Shukla, Pradeep, Wang, Shaobin, Rudolph, Victor and Zhu, Zhonghua. 2015. "An experimental and simulation study of binary adsorption in metal–organic frameworks." Separation and Purification Technology. 146, pp. 136-142. https://doi.org/10.1016/j.seppur.2015.03.041
Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation
Lin, Rijia, Ge, Lei, Liu, Shaomin, Rudolph, Victor and Zhu, Zhonghua. 2015. "Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation." ACS Applied Materials and Interfaces. 7 (27), pp. 14750-14757. https://doi.org/10.1021/acsami.5b02680
Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand
Yang, Ying, Lin, Rijia, Ge, Lei, Hou, Lei, Bernhardt, Paul, Rufford, Thomas E., Wang, Shaobin, Rudolph, Victor, Wang, Yaoyu and Zhu, Zhonghua. 2015. "Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand." Dalton Transactions: an international journal of inorganic chemistry. 44 (17), pp. 8190-8197. https://doi.org/10.1039/C4DT03927K
Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler." Journal of Materials Chemistry A. 4 (16), pp. 6084-6090. https://doi.org/10.1039/c5ta10553f
Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation." ACS Applied Materials and Interfaces. 8 (46), pp. 32041-32049. https://doi.org/10.1021/acsami.6b11074
Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation
Lu, Xuemei, Peng, Yuelian, Ge, Lei, Lin, Rijia, Zhu, Zhonghua and Liu, Shaomin. 2016. "Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation." Journal of Membrane Science. 505, pp. 61-69. https://doi.org/10.1016/j.memsci.2015.12.042