Facile autocombustion synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) perovskite via a modified complexing sol–gel process with NH4NO3 as combustion aid
Article
Article Title | Facile autocombustion synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) perovskite via a modified complexing sol–gel process with NH4NO3 as combustion aid |
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ERA Journal ID | 1448 |
Article Category | Article |
Authors | Ge, Lei (Author), Zhou, Wei (Author), Ran, Ran (Author), Shao, Zongping (Author) and Liu, Shaomin (Author) |
Journal Title | Journal of Alloys and Compounds |
Journal Citation | 450 (1), pp. 338-347 |
Number of Pages | 10 |
Year | 2008 |
Publisher | Elsevier |
Place of Publication | Amsterdam, Netherlands |
ISSN | 0925-8388 |
1873-4669 | |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.jallcom.2006.10.142 |
Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S0925838806017610?via%3Dihub |
Abstract | Ammonia nitrate was applied as an oxidizer and combustion trigger to modify the normal combined EDTA-citrate complexing method into a process with autocombustion and low ignition temperature properties. Therefore, the synthesis procedure was greatly simplified. The effect of NH4NO3/metal ions to organic mole ratios and the heating temperature on the autocombustion behavior and the properties of the powders derived were investigated in detail. The critical amount of NH4NO3 for the autocombustion to occur was identified at the NO3- to citric acid to EDTA mole ratio of around 10:2:1. After the experimental optimization, well-crystallized nanostructured La0.6Sr0.4Co0.2Fe0.8O3- δ (LSCF) powder with a specific surface area as high as 21 m2/g was obtained; it is comparable with that obtained from a normal complexing process. By adjusting the combustion parameters, the properties of the powders then derived can be tailored for different applications, such as nanograined dense membrane for oxygen separation membrane, and porous cathode for fuel cells and sensors. |
Keywords | nanofabrication, oxide materials, sol–gel processes, chemical synthesis |
ANZSRC Field of Research 2020 | 340210. Solid state chemistry |
400409. Separation technologies | |
Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
Byline Affiliations | Nanjing University of Technology, China |
Nanjing Tech University, China | |
University of Queensland | |
Institution of Origin | University of Southern Queensland |
https://research.usq.edu.au/item/q540w/facile-autocombustion-synthesis-of-la0-6sr0-4co0-2fe0-8o3-lscf-perovskite-via-a-modified-complexing-sol-gel-process-with-nh4no3-as-combustion-aid
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