Electrochemical reduction of CO2 to ethane through stabilization of an ethoxy intermediate

Article


Vasileff, Anthony, Zhu, Yanping, Zhi, Xing, Zhao, Yongqiang, Ge, Lei, Chen, Hao Ming, Zheng, Yao and Qiao, Shi-Zhang. 2020. "Electrochemical reduction of CO2 to ethane through stabilization of an ethoxy intermediate." Angewandte Chemie. 59 (4), pp. 19649-19653. https://doi.org/10.1002/anie.202004846
Article Title

Electrochemical reduction of CO2 to ethane through stabilization of an ethoxy intermediate

ERA Journal ID1313
Article CategoryArticle
AuthorsVasileff, Anthony (Author), Zhu, Yanping (Author), Zhi, Xing (Author), Zhao, Yongqiang (Author), Ge, Lei (Author), Chen, Hao Ming (Author), Zheng, Yao (Author) and Qiao, Shi-Zhang (Author)
Journal TitleAngewandte Chemie
Journal Citation59 (4), pp. 19649-19653
Number of Pages5
Year2020
Place of PublicationWeinheim, Germany
ISSN0044-8249
1433-7851
1521-3773
Digital Object Identifier (DOI)https://doi.org/10.1002/anie.202004846
Abstract

Electrochemical conversion of CO2 into ethane is seldom observed because of the generally higher selectivity towards methane, ethylene, and ethanol. Consequently, little experimental evidence for its reaction mechanism exists and thus remains largely unknown. Now, by combining electrochemistry with in situ X-ray absorption fine-structure and in situ Raman techniques, iodide-derived copper (ID-Cu) and oxide-derived copper (OD-Cu) systems were studied to obtain a deeper understanding of the CO2 to ethane mechanism. With trace iodine species on the surface and positively charged Cu species, production of ethane is significantly more favored on ID-Cu compared to OD-Cu, with higher selectivity and faster kinetics. For the first time, it is experimentally found that the formation of ethane follows the same pathway to ethylene and ethanol, and better stabilization of the late stage ethoxy intermediate can steer the reaction to ethane over ethanol.

KeywordsCO2 reduction; copper catalysts; in situ spectroscopy; Raman; XAFS
ANZSRC Field of Research 2020400404. Electrochemical energy storage and conversion
340601. Catalysis and mechanisms of reactions
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Byline AffiliationsUniversity of Adelaide
National Taiwan University, Taiwan
Centre for Future Materials
Institution of OriginUniversity of Southern Queensland
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Effect of oxidation and silane surface treatments of coal powders on relative permeability in packed coal beds
Ge, Lei, Soares, Fabio Terzini, Mahoney, Shilo, Hamilton, Christopher, Khan, Chawarwan, Steel, Karen, Rufford, Thomas E. and Rudolph, Victor. 2019. "Effect of oxidation and silane surface treatments of coal powders on relative permeability in packed coal beds." Journal of Natural Gas Science and Engineering. 69 (102931), pp. 1-9. https://doi.org/10.1016/j.jngse.2019.102931
Gas storage potential and electrohydraulic discharge (EHD) stimulation of coal seam interburden from the Surat Basin
Ren, Fei, Ge, Lei, Arami-Niya, Arash, Rufford, Thomas E., Xing, Huilin and Rudolph, Victor. 2019. "Gas storage potential and electrohydraulic discharge (EHD) stimulation of coal seam interburden from the Surat Basin." International Journal of Coal Geology. 208, pp. 24-36. https://doi.org/10.1016/j.coal.2019.04.001
Characterisation and evaluation of shockwave generation in water conditions for coal fracturing
Ren, Fei, Ge, Lei, Stelmashuk, Vitaliy, Rufford, Thomas E., Xing, Huilin and Rudolph, Victor. 2019. "Characterisation and evaluation of shockwave generation in water conditions for coal fracturing." Journal of Natural Gas Science and Engineering. 66, pp. 255-264. https://doi.org/10.1016/j.jngse.2019.04.005
Anisotropic coal permeability estimation by determining cleat compressibility using mercury intrusion porosimetry and stress–strain measurements
Raza, Syed Shabbar, Ge, Lei, Rufford, Thomas E., Chen, Zhongwei and Rudolph, Victor. 2019. "Anisotropic coal permeability estimation by determining cleat compressibility using mercury intrusion porosimetry and stress–strain measurements." International Journal of Coal Geology. 205, pp. 75-86. https://doi.org/10.1016/j.coal.2019.02.011
Carbon monoliths by assembling carbon spheres for gas adsorption
Gao, Shuai, Ge, Lei, Villacorta, Byron S., Rufford, Thomas E. and Zhu, Zhonghua. 2019. "Carbon monoliths by assembling carbon spheres for gas adsorption." Industrial and Engineering Chemistry Research. 58 (12), pp. 4957-4969. https://doi.org/10.1021/acs.iecr.8b04891
High performance cobalt-free perovskite cathode for intermediate temperature solid oxide fuel cells
Niu, Yingjie, Zhou, Wei, Sunarso, Jaka, Ge, Lei, Zhu, Zhonghua and Shao, Zongping. 2010. "High performance cobalt-free perovskite cathode for intermediate temperature solid oxide fuel cells." Journal of Materials Chemistry. 20 (43), pp. 9619-9622. https://doi.org/10.1039/c0jm02816a
Evaluation of mixed‐conducting lanthanum‐strontium‐cobaltite ceramic membrane for oxygen separation
Ge, Lei, Shao, Zongping, Zhang, Kun, Ran, Ran, Diniz da Costa, J. C. and Liu, Shaomin. 2009. "Evaluation of mixed‐conducting lanthanum‐strontium‐cobaltite ceramic membrane for oxygen separation." AIChE Journal. 55 (10), pp. 2603-2613. https://doi.org/10.1002/aic.11857
Facile auto-combustion synthesis for oxygen separation membrane application
Ge, Lei, Ran, Ran, Zhou, Wei, Shao, Zongping, Liu, Shaomin, Jin, Wanqin and Xu, Nanping. 2009. "Facile auto-combustion synthesis for oxygen separation membrane application." Journal of Membrane Science. 329 (1), pp. 219-227. https://doi.org/10.1016/j.memsci.2008.12.040
Double-site yttria-doped Sr1−xYxCo1−yYyO3−δ perovskite oxides as oxygen semi-permeable membranes
Zhang, Kun, Ran, Ran, Ge, Lei, Shao, Zongping, Jin, Wanqin and Xu, Nanping. 2009. "Double-site yttria-doped Sr1−xYxCo1−yYyO3−δ perovskite oxides as oxygen semi-permeable membranes." Journal of Alloys and Compounds. 474 (1), pp. 477-483. https://doi.org/10.1016/j.jallcom.2008.06.120
Low-temperature synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ perovskite powder via asymmetric sol–gel process and catalytic auto-combustion
Ge, Lei, Ran, Ran, Shao, Zongping, Zhu, Zhonghua and Liu, Shaomin. 2009. "Low-temperature synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ perovskite powder via asymmetric sol–gel process and catalytic auto-combustion." Ceramics International. 35 (7), pp. 2809-2815. https://doi.org/10.1016/j.ceramint.2009.03.018
Effects of preparation methods on the oxygen nonstoichiometry, B-site cation valences and catalytic efficiency of perovskite La0.6Sr0.4Co0.2Fe0.8O3−δ
Ge, Lei, Zhu, Zhonghua, Shao, Zongping, Wang, Shaobin and Liu, Shaomin. 2009. "Effects of preparation methods on the oxygen nonstoichiometry, B-site cation valences and catalytic efficiency of perovskite La0.6Sr0.4Co0.2Fe0.8O3−δ." Ceramics International. 35 (8), pp. 3201-3206. https://doi.org/10.1016/j.ceramint.2009.05.024
Facile autocombustion synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) perovskite via a modified complexing sol–gel process with NH4NO3 as combustion aid
Ge, Lei, Zhou, Wei, Ran, Ran, Shao, Zongping and Liu, Shaomin. 2008. "Facile autocombustion synthesis of La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) perovskite via a modified complexing sol–gel process with NH4NO3 as combustion aid." Journal of Alloys and Compounds. 450 (1), pp. 338-347. https://doi.org/10.1016/j.jallcom.2006.10.142
Oxygen selective membranes based on B-site cation-deficient (Ba0.5Sr0.5)(Co0.8Fe0.2)yO3−δ perovskite with improved operational stability
Ge, Lei, Ran, Ran, Zhang, Kun, Liu, Shaomin and Shao, Zongping. 2008. "Oxygen selective membranes based on B-site cation-deficient (Ba0.5Sr0.5)(Co0.8Fe0.2)yO3−δ perovskite with improved operational stability." Journal of Membrane Science. 318 (1), pp. 182-190. https://doi.org/10.1016/j.memsci.2008.02.015
Synthesis, characterization and evaluation of cation-ordered LnBaCo2O5+δ as materials of oxygen permeation membranes and cathodes of SOFCs
Zhang, Kun, Ge, Lei, Ran, Ran, Shao, Zongping and Liu, Shaomin. 2008. "Synthesis, characterization and evaluation of cation-ordered LnBaCo2O5+δ as materials of oxygen permeation membranes and cathodes of SOFCs." Acta Materialia. 56 (17), pp. 4876-4889. https://doi.org/10.1016/j.actamat.2008.06.004
Properties and performance of A-site deficient (Ba0.5Sr0.5)1−xCo0.8Fe0.2O3−δ for oxygen permeating membrane
Ge, Lei, Zhou, Wei, Ran, Ran, Liu, Shaomin, Shao, Zongping, Jin, Wanqin and Xu, Nanping. 2007. "Properties and performance of A-site deficient (Ba0.5Sr0.5)1−xCo0.8Fe0.2O3−δ for oxygen permeating membrane." Journal of Membrane Science. 306 (1-2), pp. 318-328. https://doi.org/10.1016/j.memsci.2007.09.004
Orientated growth of copper-based MOF for acetylene storage
Wang, Zhanke, Ge, Lei, Li, Mengran, Lin, Rijia, Wang, Hao and Zhu, Zhonghua. 2019. "Orientated growth of copper-based MOF for acetylene storage." Chemical Engineering Journal. 357, pp. 320-327. https://doi.org/10.1016/j.cej.2018.09.148
Cracking behavior and mechanism of gibbsite crystallites during calcination
Zhang, Jinxuan, Ge, Lei, Chen, Zhi-Gang, Boom, Eric and Zhu, Zhonghua. 2019. "Cracking behavior and mechanism of gibbsite crystallites during calcination." Crystal Research and Technology: journal of experimental and industrial crystallography. 54 (1), pp. 1-7. https://doi.org/10.1002/crat.201800201
Defect-induced Pt-Co-Se coordinated sites with highly asymmetrical electronic distribution for boosting oxygen-involving electrocatalysis
Zhuang, Linzhou, Jia, Yi, Liu, Hongli, Wang, Xing, Hocking, Rosalie K., Liu, Hongwei, Chen, Jun, Ge, Lei, Zhang, Longzhou, Li, Mengran, Dong, Chung-Li, Huang, Yu-cheng, Chen, Shaohua, Yang, Dongjiang, Zhu, Zhonghua and Yao, Xiangdong. 2019. "Defect-induced Pt-Co-Se coordinated sites with highly asymmetrical electronic distribution for boosting oxygen-involving electrocatalysis." Advanced Materials. 31 (4), pp. 1-10. https://doi.org/10.1002/adma.201805581
Co-localization of glucose oxidase and catalase enabled by a self-assembly approach: matching between molecular dimensions and hierarchical pore sizes
Zhuang, Wei, Huang, Jinsha, Liu, Xiaojing, Ge, Lei, Niu, Huanqing, Wang, Zhenfu, Wu, Jinglan, Yang, Pengpeng, Chen, Yong and Ying, Hanjie. 2019. "Co-localization of glucose oxidase and catalase enabled by a self-assembly approach: matching between molecular dimensions and hierarchical pore sizes." Food Chemistry. 275, pp. 197-205. https://doi.org/10.1016/j.foodchem.2018.09.077
Bronze alloys with tin surface sites for selective electrochemical reduction of CO2
Vasileff, Anthony, Xu, Chaochen, Ge, Lei, Zheng, Yao and Qiao, Shi-Zhang. 2018. "Bronze alloys with tin surface sites for selective electrochemical reduction of CO2." Chemical Communications. 54 (99), pp. 13965-13968. https://doi.org/10.1039/c8cc08066f
Permeability enhancement of coal by chemical-free fracturing using high-voltage electrohydraulic discharge
Ren, Fei, Ge, Lei, Rufford, Thomas E., Xing, Huilin and Rudolph, Victor. 2018. "Permeability enhancement of coal by chemical-free fracturing using high-voltage electrohydraulic discharge." Journal of Natural Gas Science and Engineering. 57, pp. 1-10. https://doi.org/10.1016/j.jngse.2018.06.034
Effect of rheological properties of mesophase pitch and coal mixtures on pore development in activated carbon discs with high compressive strength
Gao, Shuai, Villacorta, Byron S., Ge, Lei, Steel, Karen, Rufford, Thomas E. and Zhu, Zhonghua. 2018. "Effect of rheological properties of mesophase pitch and coal mixtures on pore development in activated carbon discs with high compressive strength." Fuel Processing Technology. 177, pp. 219-227. https://doi.org/10.1016/j.fuproc.2018.04.032
Silver-perovskite hybrid electrocatalysts for oxygen reduction reaction in alkaline media
Wang, Xixi, Ge, Lei, Zhu, Yinlong, Dai, Jie, Zhou, Wei and Shao, Zongping. 2018. "Silver-perovskite hybrid electrocatalysts for oxygen reduction reaction in alkaline media." Journal of the Electrochemical Society. 165 (9), pp. H524-H529. https://doi.org/10.1149/2.1131809jes
Smart, porous polymer coatings to bind clay minerals in coal bed methane wells
Ge, Lei, Hamilton, Christopher, Ferbina, Tasha Rahman and Rufford, Thomas E.. 2016. "Smart, porous polymer coatings to bind clay minerals in coal bed methane wells." 10th International Petroleum Technology Conference (IPTC 2016). Bangkok, Thailand 14 - 16 Nov 2016 https://doi.org/10.2523/IPTC-18722-MS
A phase inversion polymer coating to prevent swelling and spalling of clay fines in coal seam gas wells
Ge, Lei, Hamilton, Christopher, Febrina, Rahman Tasha, Rudolph, Victor and Rufford, Thomas E.. 2018. "A phase inversion polymer coating to prevent swelling and spalling of clay fines in coal seam gas wells." International Journal of Coal Science and Technology. 5 (2), pp. 179-190. https://doi.org/10.1007/s40789-018-0199-0
Affinity induced immobilization of adenylate cyclase from the crude cell lysate for ATP conversion
Zhu, Qianqian, Zhuang, Wei, Niu, Huanqing, Ge, Lei, Villacorta Hernandez, Byron, Wu, Jinglan, Wang, Kai, Liu, Dong, Chen, Yong, Zhu, Chenjie and Ying, Hanjie. 2018. "Affinity induced immobilization of adenylate cyclase from the crude cell lysate for ATP conversion." Colloids and Surfaces B: Biointerfaces. 164, pp. 155-164. https://doi.org/10.1016/j.colsurfb.2018.01.033
Enhanced anti-fouling property in membrane distillation by pore channel surface modification
Qiu, Haoran, Peng, Yuelian, Ge, Lei, Villacorta Hernandez, Byron and Zhu, Zhonghua. 2018. "Enhanced anti-fouling property in membrane distillation by pore channel surface modification." Applied Surface Science. 443, pp. 217-226. https://doi.org/10.1016/j.apsusc.2018.03.004
Metal organic frameworks based mixed matrix membrane: An overview on filler/polymer interface
Lin, Rijia, Villacorta Hernandez, Byron, Ge, Lei and Zhu, Zhonghua. 2018. "Metal organic frameworks based mixed matrix membrane: An overview on filler/polymer interface." Journal of Materials Chemistry A. 6 (2), pp. 293-312. https://doi.org/10.1039/C7TA07294E
Enabling process intensification by 3D printing of catalytic structures
Konarova, Muxina, Aslam, Waqas, Ge, Lei, Ma, Qing, Tang, Fengqiu, Rudolph, Victor and Beltramini, Jorge Norberto. 2017. "Enabling process intensification by 3D printing of catalytic structures." ChemCatChem. 9 (21), pp. 4132-4138. https://doi.org/10.1002/cctc.201700829
Rational design of a water-storable hierarchical architecture decorated with amorphous barium oxide and nickel nanoparticles as a solid oxide fuel cell anode with excellent sulfur tolerance
Song, Yufei, Wang, Wei, Ge, Lei, Xu, Xiaomin, Zhang, Zhenbao, Juliao, Paulo Sergio Barros, Zhou, Wei and Shao, Zongping. 2017. "Rational design of a water-storable hierarchical architecture decorated with amorphous barium oxide and nickel nanoparticles as a solid oxide fuel cell anode with excellent sulfur tolerance." Advanced Science. 4 (11). https://doi.org/10.1002/advs.201700337
Activated carbon derived from bio-waste hemp hurd and retted hemp hurd for CO2 adsorption
Liu, Shan, Ge, Lei, Gao, Shuai, Zhuang, Linzhou, Zhu, Zhonghua and Wang, Hao. 2017. "Activated carbon derived from bio-waste hemp hurd and retted hemp hurd for CO2 adsorption." Composites Communications. 5, pp. 27-30. https://doi.org/10.1016/j.coco.2017.06.002
Effect of sonication and hydrogen peroxide oxidation of carbon nanotube modifiers on the microstructure of pitch-derived activated carbon foam discs
Gao, Shuai, Villacorta, Byron S., Ge, Lei, Rufford, Thomas E. and Zhu, Zhonghua. 2017. "Effect of sonication and hydrogen peroxide oxidation of carbon nanotube modifiers on the microstructure of pitch-derived activated carbon foam discs." Carbon. 124, pp. 142-151. https://doi.org/10.1016/j.carbon.2017.08.036
Effect of hydrogen peroxide oxidation of carbon nanotube additives on the microstructure of pitch-derived activated carbon foam
Villacorta, Byron, Gao, Shuai, Ge, Lei and Zhu, Zhonghua. 2016. "Effect of hydrogen peroxide oxidation of carbon nanotube additives on the microstructure of pitch-derived activated carbon foam." 23rd American Biennial Conference on Carbon (Carbon'97) 2016. Pennsylvania, United States 10 - 15 Jul 2016
Coal bed-methane reservoir simulation study
Khan, Chawarwan, Ge, Lei, Mahoney, Shilo A. and Honari, Vahab. 2015. "Coal bed-methane reservoir simulation study." AAPG Asia Pacific Region, Geoscience Technology Workshop (2015). Brisbane, Australia 12 - 13 Feb 2015
Functionalization of carbon nanotubes for catalytic applications
Wang, Li, Ge, Lei, Rufford, Thomas and Zhu, Zhonghua. 2015. "Functionalization of carbon nanotubes for catalytic applications." Chen, Ying (Ian) (ed.) Nanotubes and nanosheets: functionalization and applications of boron nitride and Other nanomaterials. Boca Raton, FL, United States. CRC Press. pp. 409-440
Measurements of gas-liquid relative permeability of Queensland coals
Ge, Lei, Khan, Chawarwan, Rufford, Thomas E. and Rudolph, Victor. 2015. "Measurements of gas-liquid relative permeability of Queensland coals." AAPG Asia Pacific Region, Geoscience Technology Workshop (2015). Brisbane, Australia 12 - 13 Feb 2015 Tulsa, OK United States.
The preparation of activated carbon discs from tar pitch and coal powder for adsorption of CO 2, CH 4 and N 2
Gao, Shuai, Ge, Lei, Rufford, Thomas E. and Zhu, Zhonghua. 2017. "The preparation of activated carbon discs from tar pitch and coal powder for adsorption of CO 2, CH 4 and N 2." Microporous and Mesoporous Materials. 238, pp. 19-26. https://doi.org/10.1016/j.micromeso.2016.08.004
Surface-etched halloysite nanotubes in mixed matrix membranes for efficient gas separation
Ge, Lei, Lin, Rijia, Wang, Li, Rufford, Thomas E., Villacorta, Byron, Liu, Shaomin, Liu, Lian X. and Zhu, Zhonghua. 2017. "Surface-etched halloysite nanotubes in mixed matrix membranes for efficient gas separation." Separation and Purification Technology. 173, pp. 63-71. https://doi.org/10.1016/j.seppur.2016.09.015
Systematic investigation on new SrCo1-yNbyO 3-δ ceramic membranes with high oxygen semi-permeability
Zhang, Kun, Ran, Ran, Ge, Lei, Shao, Zongping, Jin, Wanqin and Xu, Nanping. 2008. "Systematic investigation on new SrCo1-yNbyO 3-δ ceramic membranes with high oxygen semi-permeability." Journal of Membrane Science. 323 (2), pp. 436-443. https://doi.org/10.1016/j.memsci.2008.07.002
Controlling fines in coal seam gas wells using MgO nanoparticles
Ge, Lei, Guenot, Laetitia, Rufford, Thomas and Mohoney, Shilo. 2014. "Controlling fines in coal seam gas wells using MgO nanoparticles." Energy Future Conference (2014). Sydney, Australia 03 - 05 Nov 2014
Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction
Zhuang, Linzhou, Ge, Lei, Yang, Yisu, Li, Mengran, Jia, Yi, Yao, Xiangdong and Zhu, Zhonghua. 2017. "Ultrathin iron-cobalt oxides nanosheets with abundant oxygen vacancies for oxygen evolution reaction." Advanced Materials. 29 (17), p. 1606793. https://doi.org/10.1002/adma.201606793
Yolk-shell hybrid materials with a periodic mesoporous organosilica shell: ideal nanoreactors for selective alcohol oxidation
Liu, Jian, Yang, Heng Quan, Kleitz, Freddy, Chen, Zhi Gang, Yang, Tianyu, Strounina, Ekaterina, Lu, Gao Qing (Max) and Qiao, Shi Zhang. 2012. "Yolk-shell hybrid materials with a periodic mesoporous organosilica shell: ideal nanoreactors for selective alcohol oxidation." Advanced Functional Materials. 22 (3), pp. 591-599. https://doi.org/10.1002/adfm.201101900
Hierarchical structures of single-crystalline anatase TiO2 nanosheets dominated by {001} facets
Fang, Wen Qi, Zhou, Ji Zhi, Liu, Jian, Chen, Zhi Gang, Yang, Chen, Sun, Cheng Hua, Qian, Guang Ren, Zou, Jin, Qiao, Shi Zhang and Yang, Hua Gui. 2011. "Hierarchical structures of single-crystalline anatase TiO2 nanosheets dominated by {001} facets." Chemistry: A European Journal. 17 (5), pp. 1423-1427. https://doi.org/10.1002/chem.201002582
Circularly polarized patch antenna with frequency reconfiguration
Gu, Hui, Wang, Jianpeng and Ge, Lei. 2015. "Circularly polarized patch antenna with frequency reconfiguration." IEEE Antennas and Wireless Propagation Letters. 14, pp. 1770-1773. https://doi.org/10.1109/LAWP.2015.2423321
360° beam-steering reconfigurable wideband substrate integrated waveguide horn antenna
Ge, Lei, Luk, Kwai Man and Chen, Shichang. 2016. "360° beam-steering reconfigurable wideband substrate integrated waveguide horn antenna." IEEE Transactions on Antennas and Propagation. 64 (12), pp. 5005-5011. https://doi.org/10.1109/TAP.2016.2617820
Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction
Zhou, Wei, Sunarso, Jaka, Chen, Zhi Gang, Ge, Lei, Motuzas, Julius, Zou, Jin, Wang, Guoxiong, Julbe, Anne and Zhu, Zhonghua. 2011. "Novel B-site ordered double perovskite Ba2Bi 0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction." Energy and Environmental Science. 4 (3), pp. 872-875. https://doi.org/10.1039/c0ee00451k
Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation
Sun, Hongqi, Wang, Yuxian, Liu, Shizhen, Ge, Lei, Wang, Li, Zhu, Zhonghua and Wang, Shaobin. 2013. "Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation." Chemical Communications. 49 (85), pp. 9914-9916. https://doi.org/10.1039/C3CC43401J
In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption
Yang, Ying, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2014. "In situ synthesis of zeolitic imidazolate frameworks/carbon nanotube composites with enhanced CO2 adsorption." Dalton Transactions: an international journal of inorganic chemistry. 43 (19), pp. 7028-7036. https://doi.org/10.1039/c3dt53191k
Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance
Lin, Rijia, Ge, Lei, Hou, Lei, Strounina, Ekaterina, Rudolph, Victor and Zhu, Zhonghua. 2014. "Mixed matrix membranes with strengthened MOFs/polymer interfacial interaction and improved membrane performance." ACS Applied Materials and Interfaces. 6 (8), pp. 5609-5618. https://doi.org/10.1021/am500081e
Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells
Niu, Yingjie, Sunarso, Jaka, Zhou, Wei, Liang, Fengli, Ge, Lei, Zhu, Zhonghua and Shao, Zongping. 2011. "Evaluation and optimization of Bi1−xSrxFeO3−δ perovskites as cathodes of solid oxide fuel cells." International Journal of Hydrogen Energy. 36 (4), pp. 3179-3186. https://doi.org/10.1016/j.ijhydene.2010.11.109
Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells
Zhou, Wei, Sunarso, Jaka, Motuzas, Julius, Liang, Fengli, Chen, Zhigang, Ge, Lei, Liu, Shaomin, Julbe, Anne and Zhu, Zhonghua. 2011. "Deactivation and regeneration of oxygen reduction reactivity on double perovskite Ba2Bi0.1Sc0.2Co1.7O6−x cathode for intermediate-temperature solid oxide fuel cells." Chemistry of Materials. 23 (6), pp. 1618-1624. https://doi.org/10.1021/cm103534x
Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays
Ge, Lei, Chen, Jiuling, Chen, Jun, Zhu, Zhonghua and Rudolph, Victor. 2012. "Study on the controllable scale-up growth of vertically-aligned carbon nanotube arrays." Journal of Nanoscience and Nanotechnology. 12 (3), pp. 2722-2732. https://doi.org/10.1166/jnn.2012.5726
A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles
Wang, Li, Ge, Lei, Rufford, Thomas E., Chen, Jiuling, Zhou, Wei, Zhu, Zhonghua and Rudolph, Victor. 2011. "A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles." Carbon. 49 (6), pp. 2022-2032. https://doi.org/10.1016/j.carbon.2011.01.028
Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location
Ge, Lei, Zhu, Zhonghua, Li, Feng, Liu, Shaomin, Wang, Li, Tang, Xuegang and Rudolph, Victor. 2011. "Investigation of gas permeability in carbon nanotube (CNT)− polymer matrix membranes via modifying CNTs with functional groups/metals and controlling modification location." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 115 (14), pp. 6661-6670. https://doi.org/10.1021/jp1120965
Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane
Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Enhanced gas permeability by fabricating functionalized multi-walled carbon nanotubes and polyethersulfone nanocomposite membrane." Separation and Purification Technology. 78 (1), pp. 76-82. https://doi.org/10.1016/j.seppur.2011.01.024
Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen
Wang, Li, Chen, Jiuling, Ge, Lei, Zhu, Zhonghua and Rudolph, Victor. 2011. "Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-Free hydrogen." Energy and Fuels. 25 (8), pp. 3408-3416. https://doi.org/10.1021/ef200719v
Vertically-aligned carbon nanotube membranes for hydrogen separation
Ge, Lei, Wang, Li, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Vertically-aligned carbon nanotube membranes for hydrogen separation." RSC Advances: an international journal to further the chemical sciences. 2 (12), pp. 5329-5336. https://doi.org/10.1039/c2ra00031h
Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer
Ge, Lei, Du, Aijun, Hou, Meng, Rudolph, Victor and Zhu, Zhonghua. 2012. "Enhanced hydrogen separation by vertically-aligned carbon nanotube membranes with zeolite imidazolate frameworks as a selective layer." RSC Advances: an international journal to further the chemical sciences. 2 (31), pp. 11793-11800. https://doi.org/10.1039/c2ra21460a
Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation
Ge, Lei, Zhou, Wei, Du, Aijun and Zhu, Zhonghua. 2012. "Porous polyethersulfone-supported zeolitic imidazolate framework membranes for hydrogen separation." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 116 (24), pp. 13264-13270. https://doi.org/10.1021/jp3035105
The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites
Tang, Xue‐Gang, Hou, Meng, Ge, Lei, Zou, Jin, Truss, Rowan, Yang, Wei, Yang, Ming‐Bo, Zhu, Zhong-Hua and Bao, Rui‐Ying. 2012. "The preparation, structures, and properties of poly (vinylidene fluoride)/multiwall carbon nanotubes nanocomposites." Journal of Applied Polymer Science. 125 (S1), pp. E592-E600. https://doi.org/10.1002/app.36671
Anti-fouling membranes by manipulating surface wettability and their anti-fouling mechanism
Lu, Xuemei, Peng, Yuelian, Qiu, Haoran, Liu, Xinrui and Ge, Lei. 2017. "Anti-fouling membranes by manipulating surface wettability and their anti-fouling mechanism." Desalination. 413, pp. 127-135. https://doi.org/10.1016/j.desal.2017.02.022
Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction
Zhou, Wei, Ge, Lei, Chen, Zhi-Gang, Liang, Fengli, Xu, Hong-Yi, Motuzas, Julius, Julbe, Anne and Zhu, Zhonghua. 2011. "Amorphous iron oxide decorated 3D heterostructured electrode for highly efficient oxygen reduction." Chemistry of Materials. 23 (18), pp. 4193-4198. https://doi.org/10.1021/cm201439d
Calcium looping for CO2 capture at a constant high temperature
Yin, Junjun, Qin, Changlei, Feng, Bo, Ge, Lei, Luo, Cong, Liu, Wenqiang and An, Hui. 2013. "Calcium looping for CO2 capture at a constant high temperature." Energy and Fuels. 28 (1), pp. 307-318. https://doi.org/10.1021/ef401399c
Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation
Ge, Lei, Zhou, Wei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation." Journal of Materials Chemistry A. 1 (21), pp. 6350-6358. https://doi.org/10.1039/c3ta11131h
Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Difference in the cooperative interaction between carbon nanotubes and Ru particles loaded on their internal/external surface." RSC Advances: an international journal to further the chemical sciences. 3 (31), pp. 12641-12647. https://doi.org/10.1039/c3ra41208c
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang, Li, Chen, Jiuling, Ge, Lei, Rudolph, Victor and Zhu, Zhonghua. 2013. "Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere." The Journal of Physical Chemistry C: Energy, Materials, and Catalysis. 117 (8), pp. 4141-4151. https://doi.org/10.1021/jp312491m
Two‐step boron and nitrogen doping in graphene for enhanced synergistic catalysis
Zheng, Yao, Jiao, Yan, Ge, Lei, Jaroniec, Mietek and Qiao, Shi Zhang. 2013. "Two‐step boron and nitrogen doping in graphene for enhanced synergistic catalysis." Angewandte Chemie. 52 (11), pp. 3110-3116. https://doi.org/10.1002/anie.201209548
Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture
Ge, Lei, Wang, Li, Rudolph, Victor and Zhu, Zhonghua. 2013. "Hierarchically structured metal–organic framework/vertically-aligned carbon nanotubes hybrids for CO 2 capture." RSC Advances: an international journal to further the chemical sciences. 3 (47), pp. 25360-25366. https://doi.org/10.1039/c3ra44250k
High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction
Ge, Lei, Yang, Ying, Wang, Li, Zhou, Wei, De Marco, Roland, Chen, Zhigang, Zou, Jin and Zhu, Zhonghua. 2015. "High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction." Carbon. 82 (C), pp. 417-424. https://doi.org/10.1016/j.carbon.2014.10.085
An experimental and simulation study of binary adsorption in metal–organic frameworks
Yang, Ying, Sitprasert, Chatcharin, Rufford, Thomas E., Ge, Lei, Shukla, Pradeep, Wang, Shaobin, Rudolph, Victor and Zhu, Zhonghua. 2015. "An experimental and simulation study of binary adsorption in metal–organic frameworks." Separation and Purification Technology. 146, pp. 136-142. https://doi.org/10.1016/j.seppur.2015.03.041
Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation
Lin, Rijia, Ge, Lei, Liu, Shaomin, Rudolph, Victor and Zhu, Zhonghua. 2015. "Mixed-matrix membranes with metal–organic framework-decorated CNT fillers for efficient CO2 separation." ACS Applied Materials and Interfaces. 7 (27), pp. 14750-14757. https://doi.org/10.1021/acsami.5b02680
Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand
Yang, Ying, Lin, Rijia, Ge, Lei, Hou, Lei, Bernhardt, Paul, Rufford, Thomas E., Wang, Shaobin, Rudolph, Victor, Wang, Yaoyu and Zhu, Zhonghua. 2015. "Synthesis and characterization of three amino-functionalized metal–organic frameworks based on the 2-aminoterephthalic ligand." Dalton Transactions: an international journal of inorganic chemistry. 44 (17), pp. 8190-8197. https://doi.org/10.1039/C4DT03927K
Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Propylene/propane selective mixed matrix membranes with grape-branched MOF/CNT filler." Journal of Materials Chemistry A. 4 (16), pp. 6084-6090. https://doi.org/10.1039/c5ta10553f
Highly active nickel-cobalt/nanocarbon thin films as efficient water splitting electrodes
Bayatsarmadi, Bita, Zheng, Yao, Russo, Valeria, Ge, Lei, Casari, Carlo Spartaco and Qiao, Shi-Zhang. 2016. "Highly active nickel-cobalt/nanocarbon thin films as efficient water splitting electrodes." Nanoscale. 8 (43). https://doi.org/10.1039/c6nr06961d
Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation
Lin, Rijia, Ge, Lei, Diao, Hui, Rudolph, Victor and Zhu, Zhonghua. 2016. "Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation." ACS Applied Materials and Interfaces. 8 (46), pp. 32041-32049. https://doi.org/10.1021/acsami.6b11074
Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation
Lu, Xuemei, Peng, Yuelian, Ge, Lei, Lin, Rijia, Zhu, Zhonghua and Liu, Shaomin. 2016. "Amphiphobic PVDF composite membranes for anti-fouling direct contact membrane distillation." Journal of Membrane Science. 505, pp. 61-69. https://doi.org/10.1016/j.memsci.2015.12.042