Large interspaced layered potassium niobate nanosheet arrays as an ultrastable anode for potassium ion capacitor
Article
Pham, Hong Duc, Chodankar, Nilesh R., Jadhav, Sagar D., Jayaramulu, Kolleboyina, Nanjundan, Ashok Kumar and Dubal, Deepak P.. 2021. "Large interspaced layered potassium niobate nanosheet arrays as an ultrastable anode for potassium ion capacitor." Energy Storage Materials. 34, pp. 475-482. https://doi.org/10.1016/j.ensm.2020.10.013
Article Title | Large interspaced layered potassium niobate nanosheet arrays as an ultrastable anode for potassium ion capacitor |
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ERA Journal ID | 210414 |
Article Category | Article |
Authors | Pham, Hong Duc, Chodankar, Nilesh R., Jadhav, Sagar D., Jayaramulu, Kolleboyina, Nanjundan, Ashok Kumar and Dubal, Deepak P. |
Journal Title | Energy Storage Materials |
Journal Citation | 34, pp. 475-482 |
Number of Pages | 8 |
Year | 2021 |
Publisher | Elsevier |
Place of Publication | Netherlands |
ISSN | 2405-8289 |
2405-8297 | |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.ensm.2020.10.013 |
Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S2405829720303913 |
Abstract | Potassium-ion battery (KIB) is a promising technology for large-scale energy storage applications due to their low cost, theoretically high energy density and abundant resources. However, the development of KIBs is hindered by the sluggish K+ transport kinetics and the structural instability of the electrode materials during K+ intercalation/de-intercalation. In the present investigation, we have designed a potassium-ion capacitor (KIC) using layered potassium niobate (K4Nb6O17, KNO) nanosheet arrays as anode and orange-peel derived activated carbons (OPAC) as fast capacitive cathode materials. The systematic electrochemical analysis with the ex-situ characterizations demonstrates that KNO-anode exhibits highly stable layered structure with excellent reversibility during K+ insertion/de-insertion. After optimization, the fabricated KNO//OPAC delivers both a high energy density of 116 Wh/kg and high power density of 10,808 W/kg, which is significantly higher than other similar hybrid devices. The cell also displays long term cycling stability over 5000 cycles, with 87 % of capacity retention. This study highlights the utilization of layered nanosheet arrays of niobates to achieve superior K‐storage for KICs, paving the way towards the development of high‐performance anodes for post lithium‐ion batteries. |
Keywords | Energy density; Potassium Niobate; Potassium ion capacitor; Waste derived carbon |
ANZSRC Field of Research 2020 | 401703. Energy generation, conversion and storage (excl. chemical and electrical) |
4018. Nanotechnology | |
Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
Byline Affiliations | Queensland University of Technology |
Dongguk University, Korea | |
Indian Institute of Technology, India | |
School of Engineering |
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