Semi-transparent, mechanically flexible, water-resistant, and flame-retardant sodium alginate/montmorillonite-based nanocomposite for fire alarm and protection

Article

Feng, Qu-Hao, Liu, Jun, Shen, Yan-Bin, Cao, Cheng-Fei, Hu, Wen-Yu, Liu, Teng-Teng, Fu, Yu-Ge, Shi, Qi-, Wan, Jun-Jie, Lv, Pei-Yuan, Wang, Ye-Jun, Zhang, Guo-Dong, Ma, Jun and Tang, Long-Cheng. 2025. "Semi-transparent, mechanically flexible, water-resistant, and flame-retardant sodium alginate/montmorillonite-based nanocomposite for fire alarm and protection." Composites Part A: Applied Science and Manufacturing. 190. https://doi.org/10.1016/j.compositesa.2024.108662
Article Title

Semi-transparent, mechanically flexible, water-resistant, and flame-retardant sodium alginate/montmorillonite-based nanocomposite for fire alarm and protection

ERA Journal ID4882
Article CategoryArticle
AuthorsFeng, Qu-Hao, Liu, Jun, Shen, Yan-Bin, Cao, Cheng-Fei, Hu, Wen-Yu, Liu, Teng-Teng, Fu, Yu-Ge, Shi, Qi-, Wan, Jun-Jie, Lv, Pei-Yuan, Wang, Ye-Jun, Zhang, Guo-Dong, Ma, Jun and Tang, Long-Cheng
Journal TitleComposites Part A: Applied Science and Manufacturing
Journal Citation190
Year2025
PublisherElsevier
Place of PublicationUnited Kingdom
ISSN1359-835X
1878-5840
Digital Object Identifier (DOI)https://doi.org/10.1016/j.compositesa.2024.108662
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S1359835X24006602
AbstractFire warning materials and sensors based on graphene and its derivatives have been developed to mitigate fire risks associated with flammable materials. However, such these nanomaterials face some challenges, e.g., high cost, poor water resistance, single-use fire alarm response, and a black coloration that restricts their applicability in certain scenarios. Herein, we reported a sodium alginate/montmorillonite (SA/MMT)-based hybrid nanocomposite via introducing hyperbranched polysiloxane (HSi) and calcium ions (Ca2+) for efficient fire protection. The optimized nanocomposite demonstrated semi-transparency, good mechanical flexibility and strength (tensile strength of ∼ 65 MPa), and remarkable water resistance. Additionally, it exhibited rapid flame alarm response (response time < 1 s), enhanced flame retardancy (retaining structural integrity after 120 s burning), and reliable cyclic fire alarm capability. When applied as a fireproof coating on flammable wood substrates, the nanocomposite coating also provided both outstanding fire shielding performance and rapid fire warning response. Therefore, this work provides a facile approach for designing and fabricating environmentally friendly fire-warning and flame-retardant composite materials.
KeywordsCyclic fire warning; Montmorillonite; Flame retardancy; Fire safety and protection
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020401602. Composite and hybrid materials
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Byline AffiliationsHangzhou Normal University, China
Centre for Future Materials
University of South Australia
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