Effects of anionic species of activators on the rheological properties and early gel characteristics of alkali-activated slag paste
Article
Article Title | Effects of anionic species of activators on the rheological properties and early gel characteristics of alkali-activated slag paste |
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ERA Journal ID | 4164 |
Article Category | Article |
Authors | Lu, Cuifang, Zhang, Zuhua, Hu, Jie, Yu, Qijun and Shi,Caijun |
Journal Title | Cement and Concrete Research |
Journal Citation | 162, pp. 1-21 |
Article Number | 106968 |
Number of Pages | 21 |
Year | 2022 |
Publisher | Elsevier |
Place of Publication | United Kingdom |
ISSN | 0008-8846 |
1873-3948 | |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.cemconres.2022.106968 |
Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S0008884622002605 |
Abstract | The effects of anionic species of Na2O·2SiO2-NaOH-Na2CO3 ternary activator on the rheology of alkali-activated slag (AAS) pastes are studied to obtain quantitative relationships between composition of activator and rheological parameters. The interstitial fluid chemistry, especially silicate species, OH− and CO32− ions, controls the precipitation of early gels and structural build-up by affecting the competition between dissolution and polymerization kinetics. Abundant Al3+, Ca2+ and Na+ in the interstitial solution participate into silicate oligomer structures, reducing polymerization degree of silicate species. This results in reduced concentration of Si-O-Si structure and increased Si-O-NB, while the later precipitates to form gel nano particles which are attractive, leading to yield stress-spurt, great flowability loss and rapid setting. The mixture activated by the blended of Na2O·2SiO2 and Na2CO3 tends to form C-A-S-H gel with lower Ca/Si due to the competitive effect of CO32−. This study provides essential information towards better control fresh properties of AAS mixtures. |
Keywords | Alkali-activated slag; Anionic species; Rheology; Silica gel; Ternary activator |
ANZSRC Field of Research 2020 | 4016. Materials engineering |
Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
Funder | National Natural Science Foundation of China |
Byline Affiliations | Hunan University, China |
South China University of Technology, China | |
Library Services |
https://research.usq.edu.au/item/yy3zx/effects-of-anionic-species-of-activators-on-the-rheological-properties-and-early-gel-characteristics-of-alkali-activated-slag-paste
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