Sunlight to heal mortar cracks: Photocatalytic self-healing mortar
Article
Article Title | Sunlight to heal mortar cracks: Photocatalytic self-healing mortar |
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ERA Journal ID | 21082 |
Article Category | Article |
Authors | Zhou, Yiming, Elchalakani, Mohamed, Du, Peng, Sun, Chuanzhi, Zhang, Zuhua and Wang, Hao |
Journal Title | Cement and Concrete Composites |
Journal Citation | 135, pp. 1-14 |
Article Number | 104816 |
Number of Pages | 14 |
Year | 2023 |
Publisher | Elsevier |
Place of Publication | United Kingdom |
ISSN | 0958-9465 |
1873-393X | |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.cemconcomp.2022.104816 |
Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S0958946522004097 |
Abstract | Using capsules containing repairing materials to heal concrete cracks has always been a method of great interest to achieve self-healing concrete. Breaking the capsules to release repairing materials is a challenging task. The current methods used to break capsules mainly rely on instant external forces, which implies that slowly developing cracks cannot be healed by capsules. In this paper, we present a novel photocatalytic self-healing mortar to solve this problem. To do so, NaHCO3, Ca(OH)2 and citric acid are inserted into macro capsules. Then, the photocatalyst TiO2 is added to the insoluble shells of capsules to allow them to be broken by sunlight. After shells of capsules are degraded by sunlight, NaHCO3, Ca(OH)2 and citric acid react in a wet environment to generate repairing materials that fill the cracks. To support the feasibility of the idea, physical and chemical experiments and characterization studies were conducted. Two-millimetre wide mortar cracks can be healed by the substances released from the photocatalytic capsules. The results of water permeability tests show that the two photocatalytic capsules can reach 52% healing efficiency. The characterization results show that the substances filling the cracks are unreacted NaHCO3, Ca(OH)2, citric acid and insoluble products of calcium salts. Our results suggest that sunlight can be used for the self-healing of mortar. |
Keywords | Capsules; Mortar; Photocatalysis; Self-healing; Sunlight |
ANZSRC Field of Research 2020 | 401602. Composite and hybrid materials |
Public Notes | File reproduced in accordance with the copyright policy of the publisher/author. |
Funder | Australian Research Council |
Byline Affiliations | University of Jinan, China |
University of Western Australia | |
Shandong University, China | |
Centre for Future Materials | |
Hunan University, China |
https://research.usq.edu.au/item/yy3x8/sunlight-to-heal-mortar-cracks-photocatalytic-self-healing-mortar
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