A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate
Article
Yang, Shuang, Huo, Siqi, Wang, Jun, Zhang, Bin, Wang, Jingsheng, Ran, Shiya, Fang, Zhengping, Song, Pingan and Wang, Hao. 2021. "A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate." Composites Part B: Engineering. 207, pp. 1-11. https://doi.org/10.1016/j.compositesb.2020.108601
| Article Title | A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate |
|---|---|
| ERA Journal ID | 4883 |
| Article Category | Article |
| Authors | Yang, Shuang (Author), Huo, Siqi (Author), Wang, Jun (Author), Zhang, Bin (Author), Wang, Jingsheng (Author), Ran, Shiya (Author), Fang, Zhengping (Author), Song, Pingan (Author) and Wang, Hao (Author) |
| Journal Title | Composites Part B: Engineering |
| Journal Citation | 207, pp. 1-11 |
| Article Number | 108601 |
| Number of Pages | 11 |
| Year | 2021 |
| Publisher | Elsevier |
| Place of Publication | United Kingdom |
| ISSN | 1359-8368 |
| Digital Object Identifier (DOI) | https://doi.org/10.1016/j.compositesb.2020.108601 |
| Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S1359836820336477 |
| Abstract | The design of highly fire-safe and smoke-suppressive single-component epoxy (EP) resins combining modest curing temperature and fast curing rate has been desirable yet very challenging in both academia and industry. Herein, we report a facile design of a phosphorus/imidazole-containing single-component EP system via incorporating 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and a flame-retardant curing agent cyclotriphosphazene-modified benzimidazole (BICP) into EP. Our results show that EP/DOPO/BICP exhibits a rapid modest-temperature curing feature because DOPO serves as a switch that triggers BICP to release benzimidazole (BIM) via substitution reaction in the initial curing stage. Moreover, as-prepared EP/DOPO/BICP shows outstanding fire retardancy, reflected by the high limited oxygen index (LOI) of 38.3% and UL-94 V-0 rating. Compared to the control EP system, the peak of heat release rate (PHRR) and total smoke production (TSP) of EP/DOPO/BICP remarkably decrease by ~74.5% and ~50.6%, respectively, which is superior to previously-reported flame-retardant P-containing epoxy counterparts. The significant enhancements in flame retardancy and smoke suppression are mainly due to the formation of a highly intumescent char layer and the reduced burning degree of pyrolysis fragments. This work offers a facile and scalable strategy for creating fast-curing, modest-temperature curable, highly fire-resistant and smoke-suppressive one-component epoxy systems applicable to large-scale industrial production. |
| Keywords | Single-component epoxy resin; Benzimidazole; Curing behaviors; Fire retardancy; Smoke suppression |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 401605. Functional materials |
| 401609. Polymers and plastics | |
| 401602. Composite and hybrid materials | |
| Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
| Institution of Origin | University of Southern Queensland |
| Byline Affiliations | Wuhan University of Technology, China |
| NingboTech University, China | |
| Centre for Future Materials | |
| Centre for Future Materials |
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Sethurajaperumal, Abimannan, Manohar, Anagha, Banerjee, Arghya, Varrla, Eswaraiah, Wang, Hao and Ostrikov, Kostya (Ken). 2021. "A thermally insulating vermiculite nanosheet-epoxy nanocomposite paint as a fire-resistant wood coating." Nanoscale Advances. 3 (14), pp. 4235-4243. https://doi.org/10.1039/d1na00207dSolid Wastes Toward Flame Retardants for Polymeric Materials: A Review
Gao, Chuanhua, Huo, Siqi and Cao, Zhenhu. 2021. "Solid Wastes Toward Flame Retardants for Polymeric Materials: A Review." Frontiers in Materials. 8, pp. 1-11. https://doi.org/10.3389/fmats.2021.712188Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings
Wang, Cheng, Huo, Siqi, Liu, Shi, Hu, Qinghua, Zhang, Qi and Liu, Zhitian. 2021. "Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings." Journal of Coatings Technology and Research. 18 (2), pp. 447-458. https://doi.org/10.1007/s11998-020-00413-5A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin
Jiang, Jiawei, Huo, Siqi, Zheng, Yi, Yang, Chengyun, Yan, Hongqiang, Ran, Shiya and Fang, Zhengping. 2021. "A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin." Polymers. 13 (21), pp. 1-15. https://doi.org/10.3390/polym13213648Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness
Sai, Ting, Su, Yukai, Shen, Haifeng, Ran, Shiya, Huo, Siqi, Guo, Zhenghong and Fang, Zhengping. 2021. "Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness." ACS Applied Materials and Interfaces. 13 (25), pp. 30061-30075. https://doi.org/10.1021/acsami.1c07153Exfoliated and functionalized boron nitride nanosheets towards improved fire resistance and water tolerance of intumescent fire retardant coating
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Xiao, Xianglian, Chevali, Venkata S., Song, Pingan, Yu, Bin, Yang, Yihu and Wang, Hao. 2020. "Enhanced toughness of PLLA/PCL blends using poly(d-lactide)-poly(ε-caprolactone)-poly(d-lactide) as compatibilizer." Composites Communications. 21, pp. 1-6. https://doi.org/10.1016/j.coco.2020.100385Bacteria-triggered pH-responsive osteopotentiating coating on 3D-printed polyetheretherketone scaffolds for infective bone defect repair
Deng, Yi, Shi, Xiuyuan, Chen, Yong, Yang, Weizhong, Ma, Yuan, Shi, Xiao-Lei, Song, Pingan, Dargusch, Matthew S. and Chen, Zhi-Gang. 2020. "Bacteria-triggered pH-responsive osteopotentiating coating on 3D-printed polyetheretherketone scaffolds for infective bone defect repair." Industrial and Engineering Chemistry Research. 59 (26), pp. 12123-12135. https://doi.org/10.1021/acs.iecr.0c02107Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation
Pan, Yangli, Xu, Xiaomin, Zhong, Yijun, Ge, Lei, Chen, Yubo, Veder, Jean-Pierre Marcel, Guan, Daqin, O’Hayre, Ryan, Li, Mengran, Wang, Guoxiong, Wang, Hao, Zhou, Wei and Shao, Zongping. 2020. "Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation." Nature Communications. 11, pp. 1-10. https://doi.org/10.1038/s41467-020-15873-xCurrent status of carbon fibre and carbon fibre composites recycling
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Wang, Yuan, Liu, Wei-Di, Shi, XIao-Lei, Hong, Min, Wang, Li-Jun, Li, Meng, Wang, Hao, Zou, Jin and Chen, Zhi-Gang. 2020. "Enhanced thermoelectric properties of nanostructured n-type Bi2Te3 by suppressing Te vacancy through non-equilibrium fast reaction." Chemical Engineering Journal. 391. https://doi.org/10.1016/j.cej.2019.123513Development of a new calcium sulfoaluminate (synthetic ye'elimite) blended PII 52.5 cement
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Ma, Y., Yang, X., Hu, J., Zhang, Z. and Wang, H.. 2019. "Accurate determination of the 'time-zero' of autogenous shrinkage in alkali-activated fly ash/slag system." Composites Part B: Engineering. 177, pp. 1-8. https://doi.org/10.1016/j.compositesb.2019.107367Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites
Ma, Xue, Li, Liang-feng, Zhang, Fan, Zhang, Zu-hua, Wang, Hao and Wang, En-ze. 2018. "Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites." China Foundry. 15 (3), pp. 167-172. https://doi.org/10.1007/s41230-018-7211-6New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers
Longhi, Marlon, Walkley, Brant, Rodriguez, Erich D, Kirchheim, Ana P, Zhang, Zuhua and Wang, Hao. 2019. "New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers." Composites Part B: Engineering. 176 (1). https://doi.org/10.1016/j.compositesb.2019.107172Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock
Xiao, Xianglian, Chevali, Venkata S., Song, Pingan, He, Dongning and Wang, Hao. 2019. "Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock." Composites Science and Technology. 184, pp. 1-8. https://doi.org/10.1016/j.compscitech.2019.107887Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis
Longhi, Marlon, Zhang, Zuhua, Rodriguez, Erich, Kirchheim, Ana and Wang, Hao. 2019. "Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis." Frontiers in Materials. 6, pp. 1-13. https://doi.org/10.3389/fmats.2019.00089A review on mixture design methods for geopolymer concrete
Li, Ning, Shi, Caijun, Zhang, Zuhua, Wang, Hao and Liu, Yiwei. 2019. "A review on mixture design methods for geopolymer concrete." Composites Part B: Engineering. 178, pp. 1-14. https://doi.org/10.1016/j.compositesb.2019.107490New Insights into the Degradation Behavior of Air Electrodes during Solid Oxide Electrolysis and Reversible Solid Oxide Cell Operation
Khan, Muhammad Shirjeel, Xu, Xiaoyong, Knibbe, Ruth, Rehman, Ateeq Ur, Li, Zhiheng, Yago, Anya Josefa, Wang, Hao and Zhu, Zhonghua. 2020. "New Insights into the Degradation Behavior of Air Electrodes during Solid Oxide Electrolysis and Reversible Solid Oxide Cell Operation ." Energy Technology: generation, conversion, storage, distribution. 8 (9). https://doi.org/10.1002/ente.202000241Thermal properties and flame retardancy of an intumescent flame-retarded epoxy system containing phosphaphenanthrene, triazine-trione and piperidine
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Zhang, Qianqian, Wang, Jun, Yang, Shuang, Cheng, Jianwen, Ding, Guoping, Hu, Yefa and Huo, Siqi. 2020. "Synthesis of a P/N/S-based flame retardant and its flame retardant effect on epoxy resin." Fire Safety Journal. 113, pp. 1-10. https://doi.org/10.1016/j.firesaf.2020.102994Synergistic effect of polyhedral iron-cobalt alloys and graphite nanosheets with excellent microwave absorption performance
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Wang, Yingwei, Dong, Xin, Huo, Siqi, Lv, Zhenhua, Ma, Zhongnan, Gao, Jinzhu, Gai, Xiuying and Wang, Rui. 2020. "Study on the plastic deformation zone of Q235 steel via hammering tight seam." Journal of Materials Research and Technology. 9 (4), pp. 7100-7103. https://doi.org/10.1016/j.jmrt.2020.04.030A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin
Cheng, Jianwen, Duan, Huajun, Yang, Shuang, Wang, Jun, Zhang, Qianqian, Ding, Guoping, Hu, Yefa and Huo, Siqi. 2020. "A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin." Journal of Applied Polymer Science. 137 (37). https://doi.org/10.1002/app.49090One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance
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Wu, Qilei, Jin, Huihui, Zhang, Bin, Huo, Siqi, Yang, Shuang, Su, Xiaogang and Wang, Jun. 2020. "Facile synthesis of cobalt-doped porous composites with amorphous carbon/zn shell for high-performance microwave absorption." Nanomaterials. 10 (2). https://doi.org/10.3390/nano10020330Facile synthesis of Co-embedded porous spherical carbon composites derived from Co3O4/ZIF-8 compounds for broadband microwave absorption
Wu, Qilei, Wang, Jun, Jin, Huihui, Dong, Yawen, Huo, Siqi, Yang, Shuang, Su, Xiaogang and Zhang, Bin. 2020. "Facile synthesis of Co-embedded porous spherical carbon composites derived from Co3O4/ZIF-8 compounds for broadband microwave absorption." Composites Science and Technology. 195. https://doi.org/10.1016/j.compscitech.2020.108206A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure
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Wang, Yanru, Cao, Yubin, Zhang, Peng, Ma, Yuwei, Zhao, Tiejun, Wang, Hao and Zhang, Zuhua. 2019. "Water absorption and chloride diffusivity of concrete under the coupling effect of uniaxial compressive load and freeze-thaw cycles." Construction and Building Materials. 209, pp. 566-576. https://doi.org/10.1016/j.conbuildmat.2019.03.091High Porosity in Nanostructured n-Type Bi2Te3 Obtaining Ultralow Lattice Thermal Conductivity
Wang, Yuan, Liu, Wei-Di, Gao, Han, Wang, Li-Jun, Li, Meng, Shi, Xiao-Lei, Hong, Min, Wang, Hao, Zou, Jin and Chen, Zhi-Gang. 2019. "High Porosity in Nanostructured n-Type Bi2Te3 Obtaining Ultralow Lattice Thermal Conductivity ." ACS Applied Materials and Interfaces. 11 (34), pp. 31237-31244. https://doi.org/10.1021/acsami.9b12079Enhanced mechanical properties at 400 °C of carbon fabric reinforced phthalonitrile composites by high temperature postcure
Sun, Bao-Gang, Lei, Qin, Guo, Ying, Shi, Han-Qiao, Sun, Jian-Bo, Yang, Kun-Xiao, Zhou, Heng, Li, Yuan-Qing, Hu, Ning, Wang, Hao and Fu, Shao-Yun. "Enhanced mechanical properties at 400 °C of carbon fabric reinforced phthalonitrile composites by high temperature postcure ." Composites Part B: Engineering. 166, pp. 681-687. https://doi.org/10.1016/j.compositesb.2019.02.066High-pressure steam: a facile strategy for the scalable fabrication of flattened bamboo biomass
Zhang, Xiaochun, Zhou, Zhezhe, Zhu, Yuding, Dai, Jinfeng, Yu, Youming and Song, Pingan. 2019. "High-pressure steam: a facile strategy for the scalable fabrication of flattened bamboo biomass." Industrial Crops and Products. 129, pp. 97-104. https://doi.org/10.1016/j.indcrop.2018.11.061Effect of drying procedures on pore structure and phase evolution of alkali-activated cements
Zhang, Zuhua, Zhu, Yingcan, Zhu, Huajun, Zhang, Yu, Provis, John L. and Wang, Hao. 2019. "Effect of drying procedures on pore structure and phase evolution of alkali-activated cements." Cement and Concrete Composites. 96, pp. 194-203. https://doi.org/10.1016/j.cemconcomp.2018.12.003Fire-resistant, strong and green polymer nanocomposites based on poly(lactic acid) and core-shell nanofibrous flame retardants
Feng, Jiabin, Sun, Yiqi, Song, Pingan, Lei, Weiwei, Wu, Qiang, Liu, Lina, Yu, Youming and Wang, Hao. 2017. "Fire-resistant, strong and green polymer nanocomposites based on poly(lactic acid) and core-shell nanofibrous flame retardants." ACS Sustainable Chemistry and Engineering. 5 (9), pp. 7894-7904. https://doi.org/10.1021/acssuschemeng.7b01430Coralloid-like nanostructured c-nSi/SiOx@Cy anodes for high performance lithium ion battery
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Wang, Zhanke, Ge, Lei, Li, Mengran, Lin, Rijia, Wang, Hao and Zhu, Zhonghua. 2019. "Orientated growth of copper-based MOF for acetylene storage." Chemical Engineering Journal. 357, pp. 320-327. https://doi.org/10.1016/j.cej.2018.09.148Cation and anion Co-doping synergy to improve structural stability of Li-and Mn-rich layered cathode materials for lithium-ion batteries
Chen, Guorong, An, Juan, Meng, Yiming, Yuan, Changzhou, Matthews, Bryan, Dou, Fei, Shi, Liyi, Zhou, Yongfeng, Song, Pingan, Wu, Gang and Zhang, Dengsong. 2019. "Cation and anion Co-doping synergy to improve structural stability of Li-and Mn-rich layered cathode materials for lithium-ion batteries." Nano Energy. 57, pp. 157-165. https://doi.org/10.1016/j.nanoen.2018.12.049Bioinspired design of strong, tough, and thermally stable polymeric materials via nanoconfinement
Song, Pingan, Dai, Jinfeng, Chen, Guorong, Yu, Youming, Fang, Zhengping, Lei, Weiwei, Fu, Shenyuan, Wang, Hao and Chen, Zhi-Gang. 2018. "Bioinspired design of strong, tough, and thermally stable polymeric materials via nanoconfinement." ACS Nano. 12 (9), pp. 9266-9278. https://doi.org/10.1021/acsnano.8b04002Lignin-derived porous carbon loaded with La(OH)3 nanorods for highly efficient removal of phosphate
Liu, Xiaohuan, Zong, Enmin, Hu, Weijie, Song, Pingan, Wang, Jifu, Liu, Qingchun, Ma, Zhongqing and Fu, Shenyuan. 2018. "Lignin-derived porous carbon loaded with La(OH)3 nanorods for highly efficient removal of phosphate." ACS Sustainable Chemistry and Engineering. 7 (1), pp. 758-768. https://doi.org/10.1021/acssuschemeng.8b04382Mechanically robust, flame-retardant poly(lactic acid) biocomposites via combining cellulose nanofibers and ammonium polyphosphate
Yin, Weida, Chen, Lei, Lu, Fengzhu, Song, Pingan, Dai, Jinfeng and Meng, Linghui. 2018. "Mechanically robust, flame-retardant poly(lactic acid) biocomposites via combining cellulose nanofibers and ammonium polyphosphate." ACS Omega. 3 (5), pp. 5615-5626. https://doi.org/10.1021/acsomega.8b00540Fabrication of flame retardant benzoxazine semi-biocomposites reinforced by ramie fabrics with bio-based flame retardant coating
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Abdollahnejad, Zahra, Zhang, Zuhua, Wang, Hao and Mastali, Mohammad. 2018. "Comparative Study on the drying shrinkage and mechanical properties of geopolymer foam concrete incorporating different dosages of fiber, sand and foam agents." Hordijk, D. A. and Lukovic, M. (ed.) 2017 fib Symposium: High Tech Concrete. Maastricht, The Netherlands 12 - 14 Jun 2017 Switzerland. Springer. https://doi.org/10.1007/978-3-319-59471-2_6A lignin-based nano-adsorbent for superfast and highly selective removal of phosphate
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Zhang, Zuhua, Provis, John L., Reid, Andrew and Wang, Hao. 2018. "Efflorescence and subflorescence induced microstructural and mechanical evolution in fly ash-based geopolymers." Cement and Concrete Composites. 92, pp. 165-177. https://doi.org/10.1016/j.cemconcomp.2018.06.010Effect of welan gum on the hydration and hardening of Portland cement
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Fu, H. M., Qiu, D., Zhang, M. X., Wang, H., Kelly, P. M. and Taylor, J. A.. 2008. "The development of a new grain refiner for magnesium alloys using the edge-to-edge model." Journal of Alloys and Compounds. 456 (1-2), pp. 390-394. https://doi.org/10.1016/j.jallcom.2007.02.076Cu-based bulk amorphous alloy with larger glass-forming ability and supercooled liquid region
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Fu, H. M., Zhang, H. F., Wang, Hao, Zhang, Qingsheng and Hu, Z. Q.. 2005. "Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in-situ TiC particles." Scripta Materialia. 52 (7), pp. 669-673. https://doi.org/10.1016/j.scriptamat.2004.10.031Crystallization behavior of (Cu60Zr30Ti10)99Sn1 bulk metallic glass
Wang, Hao, Song, Xiaoping, Yao, Xiangdong, Zhang, Haifeng and Hu, Zhuangqui. 2005. "Crystallization behavior of (Cu60Zr30Ti10)99Sn1 bulk metallic glass." Journal of Materials Science and Technology. 21 (Supl 1), pp. 51-53.Preface to futures in mechanics of structures and materials conference. ACMSM20
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Wang, Hao and Ning, Zhiliang. 2007. "Magnesium thixotropic structure produced by controlled nucleation method ." Tezhong Zhuzao Ji Youse Hejin (Special Casting and Nonferrous Alloys).A practical thermodynamic method to calculate the best glass-forming composition for bulk metallic glasses
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Ning, Zhiliang, Cao, P., Wang, Hao, Sun, Jianfei and Liu, Diankun. 2007. "Effect of cooling conditions on grain size of AZ91 alloy." Journal of Materials Science and Technology. 23 (5), pp. 645-649.In-situ Si/Al composite produced by semisolid metal processing
Wang, Hao. 2007. "In-situ Si/Al composite produced by semisolid metal processing." Materials and Manufacturing Processes. 22 (5-6), pp. 696-699. https://doi.org/10.1080/10426910701384963The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31
Wang, H., Estrin, Y., Fu, H. M., Song, G. L. and Zuberova, Z.. 2007. "The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31." Advanced Engineering Materials. 9 (11), pp. 967-972. https://doi.org/10.1002/adem.200700200Bulk metallic glass composites
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Yao, X. D., Wu, C. Z., Wang, Hao, Cheng, H. M. and Lu, G. Q.. 2006. "Effects of Carbon Nanotubes and Metal Catalysts on Hydrogen Storage in Magnesium Nanocomposites." Journal of Nanoscience and Nanotechnology. 6 (2), pp. 494-498. https://doi.org/10.1166/jnn.2006.098In situ TiB-reinforced cu-based bulk metallic glass composites
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "In situ TiB-reinforced cu-based bulk metallic glass composites." Scripta Materialia. 54 (11), pp. 1961-1966. https://doi.org/10.1016/j.scriptamat.2006.01.048Numerical simulation of dendrite growth during solidification
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Wang, Hao, Fu, H. M., Zhang, H. F. and Hu, Z. Q.. 2006. "In-situ Cu-based bulk metallic glass composite." International Journal of Modern Physics B. 20 (25-27), pp. 3963-3968. https://doi.org/10.1142/S0217979206040696The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy." Scripta Materialia. 55 (2), pp. 147-150. https://doi.org/10.1016/j.scriptamat.2006.03.052Modeling of semisolid structure formation in controlled nucleation method
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Wang, Hao. 2006. "In-situ Si/Al composite produced by semisolid metal processing ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "Tungsten fibre reinforced Zr-based bulk metallic glass composites ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2007. "Tungsten fibre reinforced Zr-based bulk metallic glass composites." Materials and Manufacturing Processes. 22 (5-6), pp. 687-691. https://doi.org/10.1080/10426910701384922Semisolid structure simulation in controlled nucleation process
Wang, H. and Yao, X. D.. 2006. "Semisolid structure simulation in controlled nucleation process." Solid State Phenomena. 116-117, pp. 614-617. https://doi.org/10.4028/www.scientific.net/SSP.116-117.614The effect of initial microstructure of A356 alloys on the mechanical behavior in the semisolid state
Ning, Zhiliang, Wang, Hao and Sun, Jianfei. 2006. "The effect of initial microstructure of A356 alloys on the mechanical behavior in the semisolid state." Solid State Phenomena. 116-117, pp. 449-452. https://doi.org/10.4028/www.scientific.net/SSP.116-117.449Semisolid casting of automotive component: water pump lid
Wang, Hao and Xu, Jun. 2006. "Semisolid casting of automotive component: water pump lid." Solid State Phenomena. 116-117, pp. 88-91. https://doi.org/10.4028/www.scientific.net/SSP.116-117.88The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ
Kahandawa, Gayan C., Epaarachchi, Jayantha A., Wang, Hao and Aravinthan, Thiru. 2010. "The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ." Goh, Steven C. and Wang, Hao (ed.) 2010 Southern Region Engineering Conference (SREC 2010). Toowoomba, Australia 11 - 12 Nov 2010 Toowoomba, Australia.Sustainable materials research at USQ
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Ning, Z. L., Wang, H., Liu, H. H., Cao, F. Y., Wang, S. T. and Sun, J. F.. 2010. "Effects of Nd on microstructures and properties at the elevated temperature of a Mg-0.3Zn-0.32Zr alloy." Materials and Design. 31 (9), pp. 4438-4444. https://doi.org/10.1016/j.matdes.2010.04.021The role of casting temperature in preparation of bulk metallic glasses
Wang, Hao. 2010. "The role of casting temperature in preparation of bulk metallic glasses ." Chandra, T., Wanderka, N., Reimers, W. and Ionescu, M. (ed.) 6th International Conference on Processing and Manufacturing of Advanced Materials (THERMEC 2009): Processing, Fabrication, Properties, Applications. Berlin, Germany 25 - 29 Aug 2009 Switzerland. https://doi.org/10.4028/www.scientific.net/MSF.638-642.1671Characteristics of a silk fibre reinforced biodegradable plastic
Ho, Mei-Po, Lau, Kin-Tak, Wang, Hao and Bhattacharyya, Debes. 2011. "Characteristics of a silk fibre reinforced biodegradable plastic." Composites Part B: Engineering. 42 (2), pp. 117-122. https://doi.org/10.1016/j.compositesb.2010.10.007Effects of natural fibre surface on composite properties: a review
Kabir, M. M., Wang, H., Aravinthan, T., Cardona, F. and Lau, K. -T.. 2011. "Effects of natural fibre surface on composite properties: a review." Cowled, Craig J. L. (ed.) 1st International Postgraduate Conference on Engineering, Designing and Developing the Built Environment for Sustainable Wellbeing (eddBE 2011). Brisbane, Australia 27 - 29 Apr 2011 Brisbane, Australia.A review on the tensile properties of natural fiber reinforced polymer composites
Ku, H., Wang, H., Pattarachaiyakoop, N. and Trada, M.. 2011. "A review on the tensile properties of natural fiber reinforced polymer composites ." Composites Part B: Engineering. 42 (4), pp. 856-873. https://doi.org/10.1016/j.compositesb.2011.01.010Cellular automaton modeling of semisolid microstructure formation
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Kahandawa, Gayan C., Epaarachchi, Jayantha A., Wang, Hao, Followell, David, Birt, Peter, Canning, John and Stevenson, Michael. 2010. "An investigation of spectral response of embedded Fibre Bragg Grating (FBG) sensors in a hollow composite cylindrical beam under pure torsion and combined loading." Teh, Kian, Davies, Ian and Howard, Ian (ed.) 6th Australasian Congress on Applied Mechanics (ACAM 6). Perth, Western Australia 12 - 15 Dec 2010 Perth, Australia.Effects of the self distortions of embedded FBG sensors on spectral response due to torsional and combined loads
Kahandawa, Gayan C., Epaarachchi, Jayantha A., Wang, Hao and Canning, John. 2010. "Effects of the self distortions of embedded FBG sensors on spectral response due to torsional and combined loads." 3rd Asia-Pacific Workshop on Structural Health Monitoring (APWSHM 2010). Tokyo, Japan 30 Nov - 02 Dec 2010 Tokyo, Japan.Natural fibre composites with epoxidized vegetable oil (EVO) resins: a review
Manthey, N. W., Cardona, F., Aravinthan, T., Wang, H. and Cooney, T.. 2010. "Natural fibre composites with epoxidized vegetable oil (EVO) resins: a review." Goh, Steven C. and Wang, Hao (ed.) 2010 Southern Region Engineering Conference (SREC 2010). Toowoomba, Australia 11 - 12 Nov 2010 Toowoomba, Australia.Magnesium and magnesium alloys as degradable metallic biomaterials
Wang, H., Shi, Z. M. and Yang, K.. 2008. "Magnesium and magnesium alloys as degradable metallic biomaterials." Bell, John, Yan, Cheng, Ye, Lin and Zhang, Liangchi (ed.) International Conference on Frontiers in Materials Science and Technology (FMST 2008). Brisbane, Australia 26 - 28 Mar 2008 Zurich, Switzerland. https://doi.org/10.4028/www.scientific.net/AMR.32.207Present status and future trends in production of semisolid materials
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Zhu, Zhengwang, Zhang, Haifeng, Wang, Hao, Ding, Bingzhe, Hu, Zhuang-Qi and Huang, Han. 2010. "Erratum: “Influence of casting temperature on microstructures and mechanical properties of Cu50Zr45.5Ti2.5Y2 metallic glass prepared using copper mold casting” [J. Mater. Res. 24, 3108 (2009)] ." Journal of Materials Research. 25 (3), pp. 605-605. https://doi.org/10.1557/JMR.2010.0080Effects of corona discharge on the surface structure, morphology and properties of multi-walled carbon nanotubes
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Wang, Bing-tao, Zhang, Yan, Song, Pingan, Guo, Zhenghong, Cheng, Jie and Fang, Zhengping. 2010. "Biodegradable aliphatic/aromatic copolymers based on terephthalic acid and poly(L-lactic acid): Synthesis, characterization and hydrolytic degradation." Chinese Journal of Polymer Science. 28 (1), pp. 405-415. https://doi.org/10.1007/s10118-010-9032-yFunctionalization of carbon nanotubes by corona-discharge induced graft polymerization for the reinforcement of epoxy nanocomposites
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Wang, Bingtao, Zhang, Yan, Song, Pingan, Guo, Zhenghong, Cheng, Jie and Fang, Zhengping. 2010. "Synthesis, characterization, and properties of degradable poly(l-lactic acid)/poly(butylene terephthalate) copolyesters containing 1,4-cyclohexanedimethanol." Journal of Applied Polymer Science. 120 (5), pp. 2985-2995. https://doi.org/10.1002/app.33373Use of wireless tablet PCs as an effective learning and teaching enhancement tool
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Song, Pingan, Fang, Zhengping, Tong, Lifang and Xu, Zhongbin. 2009. "Synthesis of a novel oligomeric intumescent flame retardant and its application in polypropylene." Polymer Engineering and Science. 48 (7), pp. 1326-1331. https://doi.org/10.1002/pen.21153Fabrication of fullerene (C60) decorated carbon nanotubes and their application in flame-retarding polypropylene
Song, Pingan, Shen, Yu, Du, Baoxian, Guo, Zhenghong and Fang, Zhengping. 2009. "Fabrication of fullerene (C60) decorated carbon nanotubes and their application in flame-retarding polypropylene." Nanoscale. 1 (1), pp. 118-121. https://doi.org/10.1039/B9NR00026GEffects of reactive compatibilization on the morphological, thermal, mechanical and rheological properties of intumescent flame retarded polypropylene
Song, Pingan, Shen, Yu, Du, Baoxian, Peng, Mao, Shen, Lie and Fang, Zhengping. 2009. "Effects of reactive compatibilization on the morphological, thermal, mechanical and rheological properties of intumescent flame retarded polypropylene." ACS Applied Materials and Interfaces. 1 (2), pp. 452-459. https://doi.org/10.1021/am8001204Fabrication of dendrimer-like fullerene (C60) decorated oligomeric intumescent flame retardant for reducing the thermal oxidation and flammability of polypropylene nanocomposites
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Xu, Lihua, Fang, Zhengping, Song, Pingan and Peng, Mao. 2009. "Surface-initiated graft polymerization on multiwalled carbon nanotubes pretreated by corona discharge at atmospheric pressure." Nanoscale. 2 (3), pp. 389-393. https://doi.org/10.1039/B9NR00222GDevelopment of bulk metallic glass composites
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Ning, Zhiliang, Wu, Peilian, Wang, Hao, Cao, Fuyang and Sun, Jianfei. 2007. "Effect of pouring temperature on thixotropic microstructure formation of AZ91." Rare Metals. 26 (S1), pp. 180-184.Flame-retardant-wrapped carbon nanotubes for simultaneously improving the flame retardancy and mechanical properties of polypropylene
Song, Ping'an, Xu, Lihua, Guo, Zhenghong, Zhang, Yan and Fang, Zhengping. 2008. "Flame-retardant-wrapped carbon nanotubes for simultaneously improving the flame retardancy and mechanical properties of polypropylene." Journal of Materials Chemistry. 18 (42), pp. 5083-5091. https://doi.org/10.1039/b808309fC60 reduces the flammability of polypropylene nanocomposites by in situ forming gelled-ball network
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