A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate
Article
Yang, Shuang, Huo, Siqi, Wang, Jun, Zhang, Bin, Wang, Jingsheng, Ran, Shiya, Fang, Zhengping, Song, Pingan and Wang, Hao. 2021. "A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate." Composites Part B: Engineering. 207, pp. 1-11. https://doi.org/10.1016/j.compositesb.2020.108601
| Article Title | A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate |
|---|---|
| ERA Journal ID | 4883 |
| Article Category | Article |
| Authors | Yang, Shuang (Author), Huo, Siqi (Author), Wang, Jun (Author), Zhang, Bin (Author), Wang, Jingsheng (Author), Ran, Shiya (Author), Fang, Zhengping (Author), Song, Pingan (Author) and Wang, Hao (Author) |
| Journal Title | Composites Part B: Engineering |
| Journal Citation | 207, pp. 1-11 |
| Article Number | 108601 |
| Number of Pages | 11 |
| Year | 2021 |
| Publisher | Elsevier |
| Place of Publication | United Kingdom |
| ISSN | 1359-8368 |
| Digital Object Identifier (DOI) | https://doi.org/10.1016/j.compositesb.2020.108601 |
| Web Address (URL) | https://www.sciencedirect.com/science/article/pii/S1359836820336477 |
| Abstract | The design of highly fire-safe and smoke-suppressive single-component epoxy (EP) resins combining modest curing temperature and fast curing rate has been desirable yet very challenging in both academia and industry. Herein, we report a facile design of a phosphorus/imidazole-containing single-component EP system via incorporating 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and a flame-retardant curing agent cyclotriphosphazene-modified benzimidazole (BICP) into EP. Our results show that EP/DOPO/BICP exhibits a rapid modest-temperature curing feature because DOPO serves as a switch that triggers BICP to release benzimidazole (BIM) via substitution reaction in the initial curing stage. Moreover, as-prepared EP/DOPO/BICP shows outstanding fire retardancy, reflected by the high limited oxygen index (LOI) of 38.3% and UL-94 V-0 rating. Compared to the control EP system, the peak of heat release rate (PHRR) and total smoke production (TSP) of EP/DOPO/BICP remarkably decrease by ~74.5% and ~50.6%, respectively, which is superior to previously-reported flame-retardant P-containing epoxy counterparts. The significant enhancements in flame retardancy and smoke suppression are mainly due to the formation of a highly intumescent char layer and the reduced burning degree of pyrolysis fragments. This work offers a facile and scalable strategy for creating fast-curing, modest-temperature curable, highly fire-resistant and smoke-suppressive one-component epoxy systems applicable to large-scale industrial production. |
| Keywords | Single-component epoxy resin; Benzimidazole; Curing behaviors; Fire retardancy; Smoke suppression |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 401605. Functional materials |
| 401609. Polymers and plastics | |
| 401602. Composite and hybrid materials | |
| Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
| Institution of Origin | University of Southern Queensland |
| Byline Affiliations | Wuhan University of Technology, China |
| NingboTech University, China | |
| Centre for Future Materials | |
| Centre for Future Materials |
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Guo, Kun-Yu, Wu, Qian, Mao, Min, Chen, Heng, Zhang, Guo-Dong, Zhao, Li, Gao, Jie-Feng, Song, Pingan and Tang, Long-Cheng. 2020. "Water-based hybrid coatings toward mechanically flexible, super-hydrophobic and flame-retardant polyurethane foam nanocomposites with high-efficiency and reliable fire alarm response." Composites Part B: Engineering. 193, pp. 1-11. https://doi.org/10.1016/j.compositesb.2020.108017One-step and green synthesis of lightweight, mechanically flexible and flame-retardant polydimethylsiloxane foam nanocomposites via surface-assembling ultralow content of graphene derivative
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Xu, Xiaodong, Dai, Jinfeng, Ma, Zhewen, Liu, Lina, Zhang, Xinghong, Liu, Hongzhi, Tang, Long-Cheng, Huang, Guobo, Wang, Hao and Song, Pingan. 2020. "Manipulating interphase reactions for mechanically robust, flame-retardant and sustainable polylactide biocomposites." Composites Part B: Engineering. 190, pp. 1-15. https://doi.org/10.1016/j.compositesb.2020.107930Grafting Lignin with Bioderived Polyacrylates for Low-Cost, Ductile, and Fully Biobased Poly(lactic acid) Composite
Sun, Yiqi, Ma, Zhewen, Xu, Xiaodong, Liu, Xiaohuan, Liu, Lina, Huang, Guobo, Liu, Lei, Wang, Hao and Song, Pingan. 2020. "Grafting Lignin with Bioderived Polyacrylates for Low-Cost, Ductile, and Fully Biobased Poly(lactic acid) Composite." ACS Sustainable Chemistry and Engineering. 8 (5), pp. 2267-2276. https://doi.org/10.1021/acssuschemeng.9b06593A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances
Huo, Siqi, Yang, Shuang, Wang, Jun, Cheng, Jianwen, Zhang, Qianqian, Hu, Yefa, Ding, Guoping, Zhang, Qiaoxin and Song, Pingan. 2020. "A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances." Journal of Hazardous Materials. 386, pp. 1-10. https://doi.org/10.1016/j.jhazmat.2019.121984A novel strategy for enhancing the flame resistance, dynamic mechanical and the thermal degradation properties of epoxy nanocomposites
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Liu, Hongzhi, Chen, Ning, Shan, Pengjia, Song, Pingan, Liu, Xuying and Chen, Jinzhou. 2019. "Toward Fully Bio-based and Supertough PLA Blends via in Situ Formation of Cross-Linked Biopolyamide Continuity Network." Macromolecules. 52 (21), pp. 8415-8429. https://doi.org/10.1021/acs.macromol.9b01398Highly transparent, healable, and durable anti-fogging coating by combining hydrophilic pectin and tannic acid with the poly(ethylene terephthalate)
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Yu, Zhi-Ran, Li, Shi-Neng, Zang, Jing, Zhang, Ming, Gong, Li-Xiu, Song, Pingan, Zhao, Li, Zhang, Guo-Dong and Tang, Long-Cheng. 2019. "Enhanced mechanical property and flame resistance of graphene oxide nanocomposite paper modified with functionalized silica nanoparticles." Composites Part B: Engineering. 177, pp. 1-9. https://doi.org/10.1016/j.compositesb.2019.107347Strengthening, toughing and thermally stable ultra-thin MXene nanosheets/polypropylene nanocomposites via nanoconfinement
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Wang, Jieming, Liu, Dan, Li, Quanxiang, Chen, Cheng, Chen, Zhiqiang, Song, Pingan, Hao, Jian, Li, Yingwei, Fakhrhoseini, Sobhan, Naebe, Minoo, Wang, Xungai and Lei, Weiwei. 2019. "Lightweight, Superelastic Yet Thermoconductive Boron Nitride Nanocomposite Aerogel for Thermal Energy Regulation." ACS Nano. 13 (7), pp. 7860-7870. https://doi.org/10.1021/acsnano.9b02182A facile method to improve thermal stability and flame retardancy of polyamide 6
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Gao, Chuanhua, Huo, Siqi and Cao, Zhenhu. 2021. "Solid Wastes Toward Flame Retardants for Polymeric Materials: A Review." Frontiers in Materials. 8, pp. 1-11. https://doi.org/10.3389/fmats.2021.712188Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings
Wang, Cheng, Huo, Siqi, Liu, Shi, Hu, Qinghua, Zhang, Qi and Liu, Zhitian. 2021. "Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings." Journal of Coatings Technology and Research. 18 (2), pp. 447-458. https://doi.org/10.1007/s11998-020-00413-5A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin
Jiang, Jiawei, Huo, Siqi, Zheng, Yi, Yang, Chengyun, Yan, Hongqiang, Ran, Shiya and Fang, Zhengping. 2021. "A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin." Polymers. 13 (21), pp. 1-15. https://doi.org/10.3390/polym13213648Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness
Sai, Ting, Su, Yukai, Shen, Haifeng, Ran, Shiya, Huo, Siqi, Guo, Zhenghong and Fang, Zhengping. 2021. "Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness." ACS Applied Materials and Interfaces. 13 (25), pp. 30061-30075. https://doi.org/10.1021/acsami.1c07153Exfoliated and functionalized boron nitride nanosheets towards improved fire resistance and water tolerance of intumescent fire retardant coating
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Xiao, Xianglian, Chevali, Venkata S., Song, Pingan, Yu, Bin, Yang, Yihu and Wang, Hao. 2020. "Enhanced toughness of PLLA/PCL blends using poly(d-lactide)-poly(ε-caprolactone)-poly(d-lactide) as compatibilizer." Composites Communications. 21, pp. 1-6. https://doi.org/10.1016/j.coco.2020.100385Bacteria-triggered pH-responsive osteopotentiating coating on 3D-printed polyetheretherketone scaffolds for infective bone defect repair
Deng, Yi, Shi, Xiuyuan, Chen, Yong, Yang, Weizhong, Ma, Yuan, Shi, Xiao-Lei, Song, Pingan, Dargusch, Matthew S. and Chen, Zhi-Gang. 2020. "Bacteria-triggered pH-responsive osteopotentiating coating on 3D-printed polyetheretherketone scaffolds for infective bone defect repair." Industrial and Engineering Chemistry Research. 59 (26), pp. 12123-12135. https://doi.org/10.1021/acs.iecr.0c02107Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation
Pan, Yangli, Xu, Xiaomin, Zhong, Yijun, Ge, Lei, Chen, Yubo, Veder, Jean-Pierre Marcel, Guan, Daqin, O’Hayre, Ryan, Li, Mengran, Wang, Guoxiong, Wang, Hao, Zhou, Wei and Shao, Zongping. 2020. "Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation." Nature Communications. 11, pp. 1-10. https://doi.org/10.1038/s41467-020-15873-xCurrent status of carbon fibre and carbon fibre composites recycling
Zhang, Jin, Chevali, Venkata S., Wang, Hao and Wang, Chun-Hui. 2020. "Current status of carbon fibre and carbon fibre composites recycling." Composites Part B: Engineering. 193, pp. 1-15. https://doi.org/10.1016/j.compositesb.2020.108053Enhanced thermoelectric properties of nanostructured n-type Bi2Te3 by suppressing Te vacancy through non-equilibrium fast reaction
Wang, Yuan, Liu, Wei-Di, Shi, XIao-Lei, Hong, Min, Wang, Li-Jun, Li, Meng, Wang, Hao, Zou, Jin and Chen, Zhi-Gang. 2020. "Enhanced thermoelectric properties of nanostructured n-type Bi2Te3 by suppressing Te vacancy through non-equilibrium fast reaction." Chemical Engineering Journal. 391. https://doi.org/10.1016/j.cej.2019.123513Development of a new calcium sulfoaluminate (synthetic ye'elimite) blended PII 52.5 cement
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Ma, Y., Yang, X., Hu, J., Zhang, Z. and Wang, H.. 2019. "Accurate determination of the 'time-zero' of autogenous shrinkage in alkali-activated fly ash/slag system." Composites Part B: Engineering. 177, pp. 1-8. https://doi.org/10.1016/j.compositesb.2019.107367Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites
Ma, Xue, Li, Liang-feng, Zhang, Fan, Zhang, Zu-hua, Wang, Hao and Wang, En-ze. 2018. "Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites." China Foundry. 15 (3), pp. 167-172. https://doi.org/10.1007/s41230-018-7211-6New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers
Longhi, Marlon, Walkley, Brant, Rodriguez, Erich D, Kirchheim, Ana P, Zhang, Zuhua and Wang, Hao. 2019. "New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers." Composites Part B: Engineering. 176 (1). https://doi.org/10.1016/j.compositesb.2019.107172Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock
Xiao, Xianglian, Chevali, Venkata S., Song, Pingan, He, Dongning and Wang, Hao. 2019. "Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock." Composites Science and Technology. 184, pp. 1-8. https://doi.org/10.1016/j.compscitech.2019.107887Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis
Longhi, Marlon, Zhang, Zuhua, Rodriguez, Erich, Kirchheim, Ana and Wang, Hao. 2019. "Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis." Frontiers in Materials. 6, pp. 1-13. https://doi.org/10.3389/fmats.2019.00089A review on mixture design methods for geopolymer concrete
Li, Ning, Shi, Caijun, Zhang, Zuhua, Wang, Hao and Liu, Yiwei. 2019. "A review on mixture design methods for geopolymer concrete." Composites Part B: Engineering. 178, pp. 1-14. https://doi.org/10.1016/j.compositesb.2019.107490New Insights into the Degradation Behavior of Air Electrodes during Solid Oxide Electrolysis and Reversible Solid Oxide Cell Operation
Khan, Muhammad Shirjeel, Xu, Xiaoyong, Knibbe, Ruth, Rehman, Ateeq Ur, Li, Zhiheng, Yago, Anya Josefa, Wang, Hao and Zhu, Zhonghua. 2020. "New Insights into the Degradation Behavior of Air Electrodes during Solid Oxide Electrolysis and Reversible Solid Oxide Cell Operation ." Energy Technology: generation, conversion, storage, distribution. 8 (9). https://doi.org/10.1002/ente.202000241Thermal properties and flame retardancy of an intumescent flame-retarded epoxy system containing phosphaphenanthrene, triazine-trione and piperidine
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Su, Xiaogang, Wang, Jun, Zhang, Xiaoxiao, Huo, Siqi, Dai, Wei and Zhang, Bin. 2020. "Synergistic effect of polyhedral iron-cobalt alloys and graphite nanosheets with excellent microwave absorption performance." Journal of Alloys and Compounds. 829. https://doi.org/10.1016/j.jallcom.2020.154426Study on the plastic deformation zone of Q235 steel via hammering tight seam
Wang, Yingwei, Dong, Xin, Huo, Siqi, Lv, Zhenhua, Ma, Zhongnan, Gao, Jinzhu, Gai, Xiuying and Wang, Rui. 2020. "Study on the plastic deformation zone of Q235 steel via hammering tight seam." Journal of Materials Research and Technology. 9 (4), pp. 7100-7103. https://doi.org/10.1016/j.jmrt.2020.04.030A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin
Cheng, Jianwen, Duan, Huajun, Yang, Shuang, Wang, Jun, Zhang, Qianqian, Ding, Guoping, Hu, Yefa and Huo, Siqi. 2020. "A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin." Journal of Applied Polymer Science. 137 (37). https://doi.org/10.1002/app.49090One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance
Su, Xiaogang, Wang, Jun, Zhang, Xiaoxiao, Huo, Siqi, Chen, Wei, Dai, Wei and Zhang, Bin. 2020. "One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance." Ceramics International. 46 (8), pp. 12353-12363. https://doi.org/10.1016/j.ceramint.2020.01.286Intumescent fire retardant coating with recycled powder from industrial effluent optimized using response surface methodology
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Etaati, Amir, Dehghani, Kamran, Ebrahimi, G. R. and Wang, Hao. 2013. "Predicting the flow stress behavior of Ni-42.5Ti-3Cu during hot deformation using constitutive equations." Metals and Materials International. 19 (1), pp. 5-9. https://doi.org/10.1007/s12540-013-1002-9Use of fixed wavelength Fibre-Bragg Grating (FBG) filters to capture time domain data from the distorted spectrum of an embedded FBG sensor to estimate strain with an artificial neural network
Kahandawa, G. C., Epaarachchi, J. A., Wang, H., Followell, D. and Birt, P.. 2013. "Use of fixed wavelength Fibre-Bragg Grating (FBG) filters to capture time domain data from the distorted spectrum of an embedded FBG sensor to estimate strain with an artificial neural network." Sensors and Actuators A: Physical. 194, pp. 1-7. https://doi.org/10.1016/j.sna.2012.12.028Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide
Zhang, Zuhua, Wang, Hao, Provis, John L., Bullen, Frank, Reid, Andrew and Zhu, Yingcan. 2012. "Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide." Thermochimica Acta. 539, pp. 23-33. https://doi.org/10.1016/j.tca.2012.03.021Numerical simulation of porous structure in foam concrete on thermal insulation property
Li, Qiang, Wang, Hao, Bullen, Frank and Reid, Andrew. 2012. "Numerical simulation of porous structure in foam concrete on thermal insulation property ." Jaafar, M, Azura, A. R., Leong, K. H. and Leong, A. Y. L. (ed.) 8th Asian-Australasian Conference on Composite Materials (ACCM 2012): Composites: Enabling Tomorrow's Industry Today. Kuala Lumpur, Malaysia 06 - 08 Nov 2012 Kowloon, Hong Kong.A study on the dynamic mechanical properties of silk fibre composites
Ho, Mei-po, Wang, Hao, Ho, Chun-kit and Lau, Kin-tak. 2012. "A study on the dynamic mechanical properties of silk fibre composites." Advanced Materials Research. 410, pp. 106-109. https://doi.org/10.4028/www.scientific.net/AMR.410.106Effects of ground granulated blast furnace slag on the mechanical and microstructure of fly ash-based geopolymer binders
Yang, T., Yao, X., Zhang, Z. and Wang, H.. 2012. "Effects of ground granulated blast furnace slag on the mechanical and microstructure of fly ash-based geopolymer binders." 8th Asian-Australasian Conference on Composite Materials (ACCM 2012): Composites: Enabling Tomorrow's Industry Today. Kuala Lumpur, Malaysia 06 - 08 Nov 2012 Kowloon, Hong Kong.Quantitative study of the reactivity of fly ash in geopolymerization by FTIR
Zhang, Zuhua, Wang, Hao and Provis, John L.. 2012. "Quantitative study of the reactivity of fly ash in geopolymerization by FTIR." Journal of Sustainable Cement-Based Materials. 1 (4), pp. 154-166. https://doi.org/10.1080/21650373.2012.752620Effect of degumming time on silkworm silk fibre for biodegradable polymer composites
Ho, Mei-po, Wang, Hao and Lau, Kin-tak. 2012. "Effect of degumming time on silkworm silk fibre for biodegradable polymer composites." Applied Surface Science. 258 (8), pp. 3948-3955. https://doi.org/10.1016/j.apsusc.2011.12.068Chemical treatments on plant-based natural fibre reinforced polymer composites: an overview
Kabir, M. M., Wang, H., Lau, K. T. and Cardona, F.. 2012. "Chemical treatments on plant-based natural fibre reinforced polymer composites: an overview ." Composites Part B: Engineering. 43 (7), pp. 2883-2892. https://doi.org/10.1016/j.compositesb.2012.04.053Interfacial bonding and degumming effects on silk fibre/polymer biocomposites
Ho, Mei-po, Wang, Hao, Lau, Kin-tak, Lee, Joong-hee and Hui, David. 2012. "Interfacial bonding and degumming effects on silk fibre/polymer biocomposites ." Composites Part B: Engineering. 43 (7), pp. 2801-2812. https://doi.org/10.1016/j.compositesb.2012.04.042Potential application of geopolymers as protection coatings for marine concrete III. Field experiment
Zhang, Zuhua, Yao, Xiao and Wang, Hao. 2012. "Potential application of geopolymers as protection coatings for marine concrete III. Field experiment ." Applied Clay Science. 67-68, pp. 57-60. https://doi.org/10.1016/j.clay.2012.05.008Signal monitoring system and methods of operating same
Kahandawa, Gayan Chanaka, Epaarachchi, Jayantha and Wang, Hao. 2013. Signal monitoring system and methods of operating same. WO/2013/151607New concept for optimal application of natural fibre reinforced plastic (NFRP) in building construction
Fajrin, Jauhar, Zhuge, Yan, Bullen, Frank and Wang, Hao. 2012. "New concept for optimal application of natural fibre reinforced plastic (NFRP) in building construction ." Noor, Norhazilan and Ismail, Mohammad (ed.) 8th Asia Pacific Structural Engineering and Construction Conference and 1st International Conference on Civil Engineering Research (APSEC-ICCER 2012): Sustaining the World with Better Structures and Construction Practice. Surabaya, Indonesia 02 - 04 Oct 2012 Johor, Malaysia.Reinforcement of polypropylene with hemp fibres
Yan, Z. L., Wang, H., Lau, K. T., Pather, S., Zhang, J. C., Lin, G. and Ding, Y.. 2013. "Reinforcement of polypropylene with hemp fibres." Composites Part B: Engineering. 46, pp. 221-226. https://doi.org/10.1016/j.compositesb.2012.09.027Effects of halloysite in kaolin on the formation and properties of geopolymers
Zhang, Z., Wang, H., Yao, X. and Zhu, Y.. 2012. "Effects of halloysite in kaolin on the formation and properties of geopolymers." Cement and Concrete Composites. 34 (5), pp. 709-715. https://doi.org/10.1016/j.cemconcomp.2012.02.003Critical factors on manufacturing processes of natural fibre composites
Ho, Mei-po, Wang, Hao, Lee, Joong-Hee, Ho, Chun-kit, Lau, Kin-tak, Leng, Jinsong and Hui, David. 2012. "Critical factors on manufacturing processes of natural fibre composites." Composites Part B: Engineering. 43 (8), pp. 3549-3562. https://doi.org/10.1016/j.compositesb.2011.10.001Effect of silk fiber to the mechanical and thermal properties of its biodegradable composites
Ho, Mei-Po, Wang, Hao, Lau, Kin-Tak and Leng, Jinsong. 2013. "Effect of silk fiber to the mechanical and thermal properties of its biodegradable composites ." Journal of Applied Polymer Science. 127 (4), pp. 2389-2396. https://doi.org/10.1002/app.37539Mechanical properties of chemically-treated hemp fibre reinforced sandwich composites
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Easton, Mark A., Wang, Hao, Grandfield, John, Davidson, Cameron J., StJohn, David H., Sweet, Lisa D. and Couper, Malcolm J.. 2012. "Observation and prediction of the hot tear susceptibility of ternary Al-Si-Mg alloys." Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. 43 (9), pp. 3227-3238. https://doi.org/10.1007/s11661-012-1132-6Use of FBG sensors for SHM in aerospace structures
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Mo, Chun-li, Li, Qiang, Guo, Xu-ming and Wang, Hao. 2012. "Numerical simulation the temperature field of the multi-coil batch during annealing process in Bell-type furnace." 2nd International Conference on Advanced Engineering Materials and Technology (AEMT 2012). Zhuhai, China 06 Jul 2012 Zurich, Switzerland. https://doi.org/10.4028/www.scientific.net/AMR.538-541.637The effect of fibre chemical treatments on hemp reinforced composites
Wang, H., Kabir, M. M. and Lau, K. T.. 2011. "The effect of fibre chemical treatments on hemp reinforced composites ." 18th International Conference on Composite Materials (ICCM-18). Jeju, Korea 21 - 26 Aug 2011 Seoul, Korea.Natural fibre composites with QLD based fibres and vegetable oils
Manthey, N. W., Cardona, F., Aravinthan, T., Wang, H. and Cooney, T.. 2011. "Natural fibre composites with QLD based fibres and vegetable oils." Fragomeni, Sam, Venkatesan, Srikanth, Lam, Nelson T. K. and Setunge, Sujeeva (ed.) 21st Australasian Conference on the Mechanics of Structures and Materials (ACMSM 21). Melbourne, Australia 07 - 10 Dec 2010 Leiden, Netherlands.The implementation of statistical inference to study the bending strength of sustainable hybrid sandwich panel composite
Fajrin, Jauhar, Zhuge, Yan, Bullen, Frank and Wang, Hao. 2011. "The implementation of statistical inference to study the bending strength of sustainable hybrid sandwich panel composite." Advanced Materials Research. 250-253, pp. 956-961. https://doi.org/10.4028/www.scientific.net/AMR.250-253.956Effects of fly ash source and curing procedure on strength development of geopolymers
Zhang, Z., Wang, H., Reid, A. and Aravinthan, T.. 2011. "Effects of fly ash source and curing procedure on strength development of geopolymers." Fragomeni, Sam, Venkatesan, Srikanth, Lam, Nelson and Setunge, Sujeeva (ed.) 21st Australasian Conference on the Mechanics of Structures and Materials (ACMSM 21). Melbourne, Australia 07 - 10 Dec 2010 London, United Kingdom.Effect of chemical treatment on the mechanical and thermal properties of hemp fibre reinforced thermoset sandwich composites
Kabir, M. M., Wang, H., Cardona, F. and Aravinthan, T.. 2011. "Effect of chemical treatment on the mechanical and thermal properties of hemp fibre reinforced thermoset sandwich composites." Fragomeni, Sam, Venkatesan, Srikanth, Lam, Nelson T. K. and Setunge, Sujeeva (ed.) 21st Australasian Conference on the Mechanics of Structures and Materials (ACMSM 21). Melbourne, Australia 07 - 10 Dec 2010 Leiden, Netherlands. https://doi.org/10.1201/b10571-78Mechanical properties of an injected silk fibre reinforced PLA composite
Ho, Mei-Po, Lau, Kin-tak, Wang, Hao and Bhattacharyya, Debes. 2011. "Mechanical properties of an injected silk fibre reinforced PLA composite." Bhattacharyya, D., Lin, R. J. T. and Srivatsan, T. S. (ed.) 19th International Symposium on Processing and Fabrication of Advanced Materials (PFAM XIX). Auckland, New Zealand 14 - 17 Jan 2011 Auckland, New Zealand.Flexural strength of sandwich panel with lignocellulosic composites intermediate layer: a statistic approach
Fajrin, Jauhar, Zhuge, Yan, Bullen, Frank and Wang, Hao. 2011. "Flexural strength of sandwich panel with lignocellulosic composites intermediate layer: a statistic approach." International Journal of Protective Structures. 2 (4), pp. 453-464. https://doi.org/10.1260/2041-4196.2.4.453In vitro biodegradation behavior of magnesium and magnesium alloy
Wang, Hao and Shi, Zhiming. 2011. "In vitro biodegradation behavior of magnesium and magnesium alloy ." Journal of Biomedical Materials Research Part B: Applied Biomaterials. 98B (2), pp. 203-209. https://doi.org/10.1002/jbm.b.31769Numerical simulation of rolling process and microstructure evolution of AM50 Mg alloy during hot rolling process
Hua, Fuan, Zhang, Chaoyi, Li, Qiang, Yu, Baoyi, Liu, Weihua, Li, Runxia, Xie, Shuisheng, Huang, Guojie, Cheng, Lei, Fu, Yao and Wang, Hao. 2011. "Numerical simulation of rolling process and microstructure evolution of AM50 Mg alloy during hot rolling process ." Advanced Materials Research. 291-294, pp. 449-454. https://doi.org/10.4028/www.scientific.net/AMR.291-294.449Deformation behaviour of aluminum alloy A356 in semisolid state
Wang, H. and Ning, Z. L.. 2009. "Deformation behaviour of aluminum alloy A356 in semisolid state ." Aravinthan, Thiru, Karunasena, Warna (Karu) and Wang, Hao (ed.) 20th Australasian Conference on the Mechanics of Structures and Materials (ACMSM20). Toowoomba, Australia 02 - 05 Dec 2008 London, United Kingdom.Influence of casting temperature on the thermal stability of Cu- and Zr-based metallic glasses: theoretical analysis and experiments
Zhu, Z. W., Zhang, H. F., Wang, H., Ding, B. Z. and Hu, Z. Q.. 2008. "Influence of casting temperature on the thermal stability of Cu- and Zr-based metallic glasses: theoretical analysis and experiments." Journal of Materials Research. 23 (10), pp. 2714-2719. https://doi.org/10.1557/jmr.2008.0335Solidification microstructure modelling using cellular automaton method
Wang, H. and Li, Q.. 2008. "Solidification microstructure modelling using cellular automaton method." International Conference on Frontiers in Materials Science and Technology (FMST 2008). Brisbane, Australia 26 - 28 Mar 2008 Zurich, Switzerland. https://doi.org/10.4028/www.scientific.net/AMR.32.271The development of a new grain refiner for magnesium alloys using the edge-to-edge model
Fu, H. M., Qiu, D., Zhang, M. X., Wang, H., Kelly, P. M. and Taylor, J. A.. 2008. "The development of a new grain refiner for magnesium alloys using the edge-to-edge model." Journal of Alloys and Compounds. 456 (1-2), pp. 390-394. https://doi.org/10.1016/j.jallcom.2007.02.076Cu-based bulk amorphous alloy with larger glass-forming ability and supercooled liquid region
Fu, H. M., Zhang, H. F., Wang, H. and Hu, Z. Q.. 2008. "Cu-based bulk amorphous alloy with larger glass-forming ability and supercooled liquid region." Journal of Alloys and Compounds. 458 (1-2), pp. 390-393. https://doi.org/10.1016/j.jallcom.2007.03.114Study of biodegradation of pure magnesium
Ren, Yibin, Wang, Hao, Huang, Jingjing, Zhang, Bingchun and Yang, Ke. 2007. "Study of biodegradation of pure magnesium." Kim, Young-Ha, Cho, Chong-Su, Kang, Inn-Kyu, Kim, Suk Young and Kwon, Oh Hyeong (ed.) ASBM7: 7th Asian Symposium on Biomedical Materials. Jeju, Korea 20 - 23 Aug 2006 Switzerland. John Wiley & Sons. https://doi.org/10.4028/www.scientific.net/KEM.342-343.601The use of simulated games in an undergraduate course manufacturing processes
Pather, Selvan and Wang, Hao. 2009. "The use of simulated games in an undergraduate course manufacturing processes." Kestell, Colin, Grainger, Steven and Cheung, John (ed.) 20th Annual Conference for the Australasian Association of Engineering Education (AAEE 2009). Adelaide, Australia 06 - 09 Dec 2009 Adelaide, Australia.Influence of casting temperature on microstructures and mechanical properties of Cu50Zr45.5Ti2.5Y2 metallic glass prepared using copper mold casting
Zhu, Zhengwang, Zhang, Haifeng, Wang, Hao, Ding, Bingzhe, Hu, Zhuang-Qi and Huang, Han. 2009. "Influence of casting temperature on microstructures and mechanical properties of Cu50Zr45.5Ti2.5Y2 metallic glass prepared using copper mold casting ." Journal of Materials Research. 24 (10), pp. 3108-3115. https://doi.org/10.1557/jmr.2009.0373Development of hot drawing process for nitinol tube
Chen, Wei, Wang, H., Zhang, Lei and Tang, Xiushan. 2009. "Development of hot drawing process for nitinol tube." International Journal of Modern Physics B. 23 (6/7), pp. 1968-1974. https://doi.org/10.1142/S0217979209061913Study of bio-corrosion of pure magnesium
Ren, Yibin, Huang, Jingjing, Yang, Ke, Zhang, Bingchun, Yao, Zhiming and Wang, Hao. 2005. "Study of bio-corrosion of pure magnesium." Acta Metallurgica Sinica (English Letters). 41 (11), pp. 1228-1232.Hydrogen storage of magnesium-based nanocomposites system
Yao, X., Wu, C. Z., Wang, H., Cheng, H. M. and Lu, G. Q. Max. 2005. "Hydrogen storage of magnesium-based nanocomposites system." Journal of Materials Science and Technology. 21 (1 (Supplement)), pp. 57-60.Fabrication of bulk amorphous Mg65Cu25Gd10 alloy of 12mm rod by water quenching
Liu, W. Y., Zhang, H. F., Hu, Z. Q., Wang, H. and Yao, X. D.. 2005. "Fabrication of bulk amorphous Mg65Cu25Gd10 alloy of 12mm rod by water quenching." Ke, W., Han, E. H., Han, Y. F., Kainer, K. and Luo, A. A. (ed.) Magnesium – Science, Technology and Applications. Zurich, Switzerland. Trans Tech Publications. pp. 211-214Modeling of columnar-to-equiaxed transition in solidified Al-Si alloys
Yao, Xiangdong, Wang, Hao, He, B. and Zhou, X.. 2005. "Modeling of columnar-to-equiaxed transition in solidified Al-Si alloys." Zhong, Z., Saka, H., Kim, T. H., Holm, E. A., Han, Y. and Xie, X. (ed.) 5th Pacific Rim International Conference on Advanced Materials and Processing (PRICM 5). Beijing, China 02 - 05 Nov 2004 Zurich, Switzerland. Scientific.Net. https://doi.org/10.4028/www.scientific.net/MSF.475-479.3141Formation and mechanical properties of Mg65Cu25Er10 and Mg65Cu15Ag10Er10 bulk amorphous alloys
Liu, Weili, Zhang, H. F., Hu, Z. Q. and Wang, Hao. 2005. "Formation and mechanical properties of Mg65Cu25Er10 and Mg65Cu15Ag10Er10 bulk amorphous alloys." Journal of Alloys and Compounds. 397 (1-2), pp. 202-206. https://doi.org/10.1016/j.jallcom.2005.01.043Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in-situ TiC particles
Fu, H. M., Zhang, H. F., Wang, Hao, Zhang, Qingsheng and Hu, Z. Q.. 2005. "Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in-situ TiC particles." Scripta Materialia. 52 (7), pp. 669-673. https://doi.org/10.1016/j.scriptamat.2004.10.031Crystallization behavior of (Cu60Zr30Ti10)99Sn1 bulk metallic glass
Wang, Hao, Song, Xiaoping, Yao, Xiangdong, Zhang, Haifeng and Hu, Zhuangqui. 2005. "Crystallization behavior of (Cu60Zr30Ti10)99Sn1 bulk metallic glass." Journal of Materials Science and Technology. 21 (Supl 1), pp. 51-53.Preface to futures in mechanics of structures and materials conference. ACMSM20
Aravinthan, Thiru, Karunasena, Warna (Karu) and Wang, Hao. 2009. "Preface to futures in mechanics of structures and materials conference. ACMSM20." Aravinthan, Thiru, Karunasena, Warna (Karu) and Wang, Hao (ed.) 20th Australasian Conference on the Mechanics of Structures and Materials (ACMSM20). Toowoomba, Australia 02 - 05 Dec 2008 London, United Kingdom.Magnesium thixotropic structure produced by controlled nucleation method
Wang, Hao and Ning, Zhiliang. 2007. "Magnesium thixotropic structure produced by controlled nucleation method ." Tezhong Zhuzao Ji Youse Hejin (Special Casting and Nonferrous Alloys).A practical thermodynamic method to calculate the best glass-forming composition for bulk metallic glasses
Wang, Hao, Fu, H. M., Zhang, H. F. and Hu, Z. Q.. 2007. "A practical thermodynamic method to calculate the best glass-forming composition for bulk metallic glasses." International Journal of Nonlinear Sciences and Numerical Simulation. 8 (2), pp. 171-178. https://doi.org/10.1515/IJNSNS.2007.8.2.171Effect of cooling conditions on grain size of AZ91 alloy
Ning, Zhiliang, Cao, P., Wang, Hao, Sun, Jianfei and Liu, Diankun. 2007. "Effect of cooling conditions on grain size of AZ91 alloy." Journal of Materials Science and Technology. 23 (5), pp. 645-649.In-situ Si/Al composite produced by semisolid metal processing
Wang, Hao. 2007. "In-situ Si/Al composite produced by semisolid metal processing." Materials and Manufacturing Processes. 22 (5-6), pp. 696-699. https://doi.org/10.1080/10426910701384963The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31
Wang, H., Estrin, Y., Fu, H. M., Song, G. L. and Zuberova, Z.. 2007. "The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31." Advanced Engineering Materials. 9 (11), pp. 967-972. https://doi.org/10.1002/adem.200700200Bulk metallic glass composites
Wang, Hao. 2005. "Bulk metallic glass composites." Journal of Materials Science and Technology. 21 (Supl 1), pp. 86-90.Semisolid structure formation and semisolid casting
Wang, Hao. 2005. "Semisolid structure formation and semisolid casting." Journal of Materials Science and Technology. 21 (Supl 1), pp. 65-71.Effects of Carbon Nanotubes and Metal Catalysts on Hydrogen Storage in Magnesium Nanocomposites
Yao, X. D., Wu, C. Z., Wang, Hao, Cheng, H. M. and Lu, G. Q.. 2006. "Effects of Carbon Nanotubes and Metal Catalysts on Hydrogen Storage in Magnesium Nanocomposites." Journal of Nanoscience and Nanotechnology. 6 (2), pp. 494-498. https://doi.org/10.1166/jnn.2006.098In situ TiB-reinforced cu-based bulk metallic glass composites
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "In situ TiB-reinforced cu-based bulk metallic glass composites." Scripta Materialia. 54 (11), pp. 1961-1966. https://doi.org/10.1016/j.scriptamat.2006.01.048Numerical simulation of dendrite growth during solidification
Yao, X., Wang, H., He, B. and Zhou, X.. 2006. "Numerical simulation of dendrite growth during solidification." International Journal of Nonlinear Sciences and Numerical Simulation. 7 (2), pp. 171-176. https://doi.org/10.1515/IJNSNS.2006.7.2.171In-situ Cu-based bulk metallic glass composite
Wang, Hao, Fu, H. M., Zhang, H. F. and Hu, Z. Q.. 2006. "In-situ Cu-based bulk metallic glass composite." International Journal of Modern Physics B. 20 (25-27), pp. 3963-3968. https://doi.org/10.1142/S0217979206040696The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy." Scripta Materialia. 55 (2), pp. 147-150. https://doi.org/10.1016/j.scriptamat.2006.03.052Modeling of semisolid structure formation in controlled nucleation method
Yao, X. and Wang, H.. 2006. "Modeling of semisolid structure formation in controlled nucleation method ." International Journal of Modern Physics B. 20 (25-27), pp. 4123-4128. https://doi.org/10.1142/S0217979206040969In-situ Si/Al composite produced by semisolid metal processing
Wang, Hao. 2006. "In-situ Si/Al composite produced by semisolid metal processing ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "Tungsten fibre reinforced Zr-based bulk metallic glass composites ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2007. "Tungsten fibre reinforced Zr-based bulk metallic glass composites." Materials and Manufacturing Processes. 22 (5-6), pp. 687-691. https://doi.org/10.1080/10426910701384922Semisolid structure simulation in controlled nucleation process
Wang, H. and Yao, X. D.. 2006. "Semisolid structure simulation in controlled nucleation process." Solid State Phenomena. 116-117, pp. 614-617. https://doi.org/10.4028/www.scientific.net/SSP.116-117.614The effect of initial microstructure of A356 alloys on the mechanical behavior in the semisolid state
Ning, Zhiliang, Wang, Hao and Sun, Jianfei. 2006. "The effect of initial microstructure of A356 alloys on the mechanical behavior in the semisolid state." Solid State Phenomena. 116-117, pp. 449-452. https://doi.org/10.4028/www.scientific.net/SSP.116-117.449Semisolid casting of automotive component: water pump lid
Wang, Hao and Xu, Jun. 2006. "Semisolid casting of automotive component: water pump lid." Solid State Phenomena. 116-117, pp. 88-91. https://doi.org/10.4028/www.scientific.net/SSP.116-117.88The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ
Kahandawa, Gayan C., Epaarachchi, Jayantha A., Wang, Hao and Aravinthan, Thiru. 2010. "The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ." Goh, Steven C. and Wang, Hao (ed.) 2010 Southern Region Engineering Conference (SREC 2010). Toowoomba, Australia 11 - 12 Nov 2010 Toowoomba, Australia.Sustainable materials research at USQ
Wang, Hao. 2010. "Sustainable materials research at USQ." Goh, Steven C. and Wang, Hao (ed.) 2010 Southern Region Engineering Conference (SREC 2010). Toowoomba, Australia 11 - 12 Nov 2010 Toowoomba, Australia .Deformation behavior of semisolid A356 alloy prepared by low temperature pouring
Ning, Z. L., Wang, H. and Sun, J. F.. 2010. "Deformation behavior of semisolid A356 alloy prepared by low temperature pouring." Materials and Manufacturing Processes. 25 (7), pp. 648-653. https://doi.org/10.1080/10426910903447279Effects of Nd on microstructures and properties at the elevated temperature of a Mg-0.3Zn-0.32Zr alloy
Ning, Z. L., Wang, H., Liu, H. H., Cao, F. Y., Wang, S. T. and Sun, J. F.. 2010. "Effects of Nd on microstructures and properties at the elevated temperature of a Mg-0.3Zn-0.32Zr alloy." Materials and Design. 31 (9), pp. 4438-4444. https://doi.org/10.1016/j.matdes.2010.04.021The role of casting temperature in preparation of bulk metallic glasses
Wang, Hao. 2010. "The role of casting temperature in preparation of bulk metallic glasses ." Chandra, T., Wanderka, N., Reimers, W. and Ionescu, M. (ed.) 6th International Conference on Processing and Manufacturing of Advanced Materials (THERMEC 2009): Processing, Fabrication, Properties, Applications. Berlin, Germany 25 - 29 Aug 2009 Switzerland. https://doi.org/10.4028/www.scientific.net/MSF.638-642.1671Characteristics of a silk fibre reinforced biodegradable plastic
Ho, Mei-Po, Lau, Kin-Tak, Wang, Hao and Bhattacharyya, Debes. 2011. "Characteristics of a silk fibre reinforced biodegradable plastic." Composites Part B: Engineering. 42 (2), pp. 117-122. https://doi.org/10.1016/j.compositesb.2010.10.007Effects of natural fibre surface on composite properties: a review
Kabir, M. M., Wang, H., Aravinthan, T., Cardona, F. and Lau, K. -T.. 2011. "Effects of natural fibre surface on composite properties: a review." Cowled, Craig J. L. (ed.) 1st International Postgraduate Conference on Engineering, Designing and Developing the Built Environment for Sustainable Wellbeing (eddBE 2011). Brisbane, Australia 27 - 29 Apr 2011 Brisbane, Australia.A review on the tensile properties of natural fiber reinforced polymer composites
Ku, H., Wang, H., Pattarachaiyakoop, N. and Trada, M.. 2011. "A review on the tensile properties of natural fiber reinforced polymer composites ." Composites Part B: Engineering. 42 (4), pp. 856-873. https://doi.org/10.1016/j.compositesb.2011.01.010Cellular automaton modeling of semisolid microstructure formation
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Kabir, Mohammad Mazedul, Islam, Md Mainul and Wang, Hao. 2010. "Mechanical and thermal properties of untreated and chemically treated jute fibre reinforced composites." 1st International Conference on Mechanical, Industrial and Energy Engineering (ICMIEE 2010) . Khulna, Bangladesh 23 - 24 Dec 2010 Khulna, Bangladesh.An investigation of spectral response of embedded Fibre Bragg Grating (FBG) sensors in a hollow composite cylindrical beam under pure torsion and combined loading
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