Tuning the microstructure of polyurethane foam using nanocellulose for improved thermal insulation properties through an efficient dispersion methodology
Article
Septevani, Athanasia A., Evans, David A.C., Martin, Darren J., Song, Pingan and Annamalai, Pratheep K.. 2023. "Tuning the microstructure of polyurethane foam using nanocellulose for improved thermal insulation properties through an efficient dispersion methodology." Polymer Composites. 44 (12), pp. 8857-8869. https://doi.org/10.1002/pc.27743
| Article Title | Tuning the microstructure of polyurethane foam using nanocellulose for improved thermal insulation properties through an efficient dispersion methodology |
|---|---|
| ERA Journal ID | 1690 |
| Article Category | Article |
| Authors | Septevani, Athanasia A., Evans, David A.C., Martin, Darren J., Song, Pingan and Annamalai, Pratheep K. |
| Journal Title | Polymer Composites |
| Journal Citation | 44 (12), pp. 8857-8869 |
| Number of Pages | 13 |
| Year | 2023 |
| Publisher | John Wiley & Sons |
| Place of Publication | United States |
| ISSN | 0272-8397 |
| 1548-0569 | |
| Digital Object Identifier (DOI) | https://doi.org/10.1002/pc.27743 |
| Web Address (URL) | https://4spepublications.onlinelibrary.wiley.com/doi/10.1002/pc.27743 |
| Abstract | Nanocellulose is explored as an eco-friendly cell modifier and reinforcer for improving the thermal insulation and mechanical performance of rigid polyurethane foam (RPUF). In this study, we report on a promising method for achieving 'solvent-free' dispersion of cellulose nanocrystals (CNCs) into polyether polyol for the production of RPUF. This was achieved through wet grinding of CNC powder in polyol in an agitator bead mill and the dispersion of CNCs in polyol was superior to classical ultrasonication. While the improvements (reduction) in thermal conductivity, due to the nucleation effect of CNCs, in the RPUF from the milling method is comparable to that from the ultrasonication method, it should be noted that it was achieved despite of a reduction in closed cell content (similar to 80%) and at a similar average cell size. This effect has been attributed to either superior dispersion quality of the milling method and/or involvement of a zirconium impurity within the CNC-RPUF. Research Highlights center dot Enhanced properties of polyurethane foam using well-dispersed nanocellulose. center dot Superior dispersion of nanocellulose in polyol using agitator bead mill. center dot Involvement of zirconium for tuning microstructure of polyurethane foam. |
| Keywords | biomaterials; dispersion; microstructure; nanocomposites; polyurethaneReceived |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 401602. Composite and hybrid materials |
| 401605. Functional materials | |
| Byline Affiliations | University of Queensland |
| National Research and Innovation Agency, Indonesia | |
| Andalas University, Indonesia | |
| Centre for Future Materials |
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| Polymer Composites - 2023 - Septevani - Tuning the microstructure of polyurethane foam using nanocellulose for improved.pdf | ||
| License: CC BY-NC 4.0 | ||
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