Engineered Functional Segments Enabled Mechanically Robust, Intrinsically Fire-Retardant, Switchable, Degradable PolyureThane Adhesives
Article
Article Title | Engineered Functional Segments Enabled Mechanically Robust, Intrinsically Fire-Retardant, Switchable, Degradable PolyureThane Adhesives |
---|---|
ERA Journal ID | 1397 |
Article Category | Article |
Authors | Xue, Yijiao, Zhang, Meng, Huo, Siqi, Ma, Zhewen, Lynch, Mark, Tuten, Bryan T, Sun, Ziqi, Zheng, Wei, Zhou, Yonghong and Song, Pingan |
Journal Title | Advanced Functional Materials |
Journal Citation | 34 (49) |
Article Number | 2409139 |
Number of Pages | 10 |
Year | 2024 |
Publisher | John Wiley & Sons |
Place of Publication | Germany |
ISSN | 1616-301X |
1616-3028 | |
Digital Object Identifier (DOI) | https://doi.org/10.1002/adfm.202409139 |
Web Address (URL) | https://onlinelibrary.wiley.com/doi/10.1002/adfm.202409139 |
Abstract | Adhesives are being used ubiquitously, such as automotive, building, electronics, and beyond. Due to the lack of rational design strategies, they have yet to achieve a performance portfolio: mechanically robust, highly adhesive, fire-retardant, switchable, and sustainable (e.g., biobased, reusable, biodegradable) to ensure their practical applications. Herein, a fire-retardant phosphorus-containing pimaric acid bio-derivative, AD, as functional segments, is rationally engineered to prepare biobased polyurethane (PU) adhesive that realizes such an integrated performance portfolio. Because of dynamic hydrogen-bonding and π–π stacking of polar AD, the as-prepared PU adhesive exhibits an ultrahigh adhesion force of 38.8 N cm–1. As-prepared adhesive can be readily reused benefiting from its good solubility in ethanol and exhibits temperature-responsive switchable adhesion without degraded adhesion. Also, the adhesive shows intrinsic fire retardance due to its biphasic modes of action. The labile ester bonds in the structure enable the adhesive to completely degrade in the presence of lipase or dilute acid. Further demonstration of its promising applications as an adhesive for nanocomposite heat dissipators shows superior dissipating efficiencies to commercial heat sinks. This work offers a novel design approach for creating next-generation sustainable high-performance adhesives with functional integration and circular life cycles, which are anticipated to find extensive real-world applications. |
Contains Sensitive Content | Does not contain sensitive content |
ANZSRC Field of Research 2020 | 401609. Polymers and plastics |
Byline Affiliations | Chinese Academy of Forestry, China |
School of Engineering | |
Centre for Future Materials | |
Tongji University, China | |
School of Agriculture and Environmental Science | |
Queensland University of Technology |
https://research.usq.edu.au/item/z95y0/engineered-functional-segments-enabled-mechanically-robust-intrinsically-fire-retardant-switchable-degradable-polyurethane-adhesives
Download files
Published Version
Adv Funct Materials - 2024 - Xue - Engineered Functional Segments Enabled Mechanically Robust Intrinsically Fire‐Retardant.pdf | ||
License: CC BY 4.0 | ||
File access level: Anyone |
60
total views13
total downloads0
views this month0
downloads this month
Export as
Related outputs
Microplastics in soils: A comparative review on extraction, identification and quantification methods
Seo, Yoonjung, Chevali, Venkata, Lai, Yunru, Zhou, Zhezhe, Chen, Guangnan, Burey, Paulomi, Wang, Shaobin and Song, Pingan. 2025. "Microplastics in soils: A comparative review on extraction, identification and quantification methods." Journal of Environmental Management. 377. https://doi.org/10.1016/j.jenvman.2025.124556Preparation of multi-hydroxy chitosan derivative and its synergistic effect on fire performance and mechanical properties of epoxy resin
Yan, Jing, Jiang, Haiqing, Gao, Na, Zhang, Xiangnan, Liu, Xingyu, Huo, Siqi, Lu, Jing and Wang, Junjie. 2025. "Preparation of multi-hydroxy chitosan derivative and its synergistic effect on fire performance and mechanical properties of epoxy resin." Journal of Thermal Analysis and Calorimetry: an international forum for thermal studies. https://doi.org/10.1007/s10973-024-13982-zGraphene oxide-based nanofluidic membranes for reverse electrodialysis that generate electricity from salinity gradients
Yu, Changchun, Xiang, Yiming, Lawson, Tom, Zhou, Yandi, Song, Pingan, Chou, Shulei and Liu, Yong. 2025. "Graphene oxide-based nanofluidic membranes for reverse electrodialysis that generate electricity from salinity gradients." Carbon Energy. 7 (1). https://doi.org/10.1002/cey2.626Covalently engineering novel sandwich-like rGO@POSS nanofillers for high-performance dielectric energy storage of PVDF film capacitor
Liu, Hui, Ding, Mingming, Chen, Xuecheng, Ba, Zhaotian, Ma, Zhewen, Ma, Lili, Wen, Xin, Song, Pingan and Lei, Qingquan. 2025. "Covalently engineering novel sandwich-like rGO@POSS nanofillers for high-performance dielectric energy storage of PVDF film capacitor." Composites Science and Technology. 259. https://doi.org/10.1016/j.compscitech.2024.110938Closed-Loop Recyclable, Self-Catalytic Transesterification Vitrimer Coatings with Superior Adhesive Strength, Fire Retardancy, and Environmental Stability
Wang, Cheng, Ye, Guofeng, Zhang, Qi, Wang, Hao, Huo, Siqi and Liu, Zhitian. 2025. "Closed-Loop Recyclable, Self-Catalytic Transesterification Vitrimer Coatings with Superior Adhesive Strength, Fire Retardancy, and Environmental Stability." ACS Materials Letters. 7, pp. 210-219. https://doi.org/10.1021/acsmaterialslett.4c02235Synthesis of multifunctional Sb2MoO6 nanoflakes for boosting the fire safety and mechanical strength of ABS resin
Li, Weimei, Huo, Siqi, Huang, Guobo, Chen, Wei, Wang, Tianle and Song, Pingan. 2025. "Synthesis of multifunctional Sb2MoO6 nanoflakes for boosting the fire safety and mechanical strength of ABS resin." Polymer Degradation and Stability. 232. https://doi.org/10.1016/j.polymdegradstab.2024.111135A high-performance flame retardant liquid synthesized on the basis of DOPO hydrolysis products avoids the defects of DOPO
Liu, Peifeng, Wang, Xiang, Jiang, Xingwu, Huang, Jinzheng, Dong, Zhenzhen, Miao, Shicheng and Huo, Siqi. 2025. "A high-performance flame retardant liquid synthesized on the basis of DOPO hydrolysis products avoids the defects of DOPO." Polymer Degradation and Stability. 232. https://doi.org/10.1016/j.polymdegradstab.2024.111116Vertically aligned cellulose nanofiber/carbon nanotube aerogel-infused epoxy nanocomposites for highly efficient solar-thermal-electric conversion
Yan, Jiali, Sun, Yu, Jia, Tao, Tao, Bin, Hong, Min, Song, Pingan and Xu, Miaojun. 2025. "Vertically aligned cellulose nanofiber/carbon nanotube aerogel-infused epoxy nanocomposites for highly efficient solar-thermal-electric conversion." Journal of Materials Science and Technology. 214, pp. 313-321. https://doi.org/10.1016/j.jmst.2024.07.018Hydrophobic silicone modified membranes for efficient oil/water separation: Synthesis, fabrication and application
Pan, Long-Qian, Zheng, Qi-Na, Feng, Qu-Hao, Shen, Yan-Bin, Hu, Wen-Yu, Cao, Cheng-Fei, Zhang, Guo-Dong, Gao, Jie-Feng, Song, Pingan, Shi, Yong-Qian and Tang, Long-Cheng. 2025. "Hydrophobic silicone modified membranes for efficient oil/water separation: Synthesis, fabrication and application." Separation and Purification Technology. 353 (Part C). https://doi.org/10.1016/j.seppur.2024.128485The application of ammonium polyphosphate in unsaturated polyester resins: A mini review
Chu, Tao, Lu, Yixia, Hou, Boyou, Jafari, Pooya, Zhou, Zhezhe, Peng, Hong, Huo, Siqi and Song, Pingan. 2024. "The application of ammonium polyphosphate in unsaturated polyester resins: A mini review." Polymer Degradation and Stability. 225. https://doi.org/10.1016/j.polymdegradstab.2024.110796Pottery-Inspired Flexible Fire-Shielding Ceramifiable Silicone Foams for Exceptional Long-Term Thermal Protection
Chen, Zuan-Yu, Wu, Yu-Yue, Liu, Shuai-Chi, Li, Yang, Guan, Zi-Qi, Cao, cheng-Fei, Zhang, Guo-Dong, Tuten, Bryan T., Gao, Jie-Feng, Shi, Yong-Qian, Song, Pingan and Tang, Long-Cheng. 2024. "Pottery-Inspired Flexible Fire-Shielding Ceramifiable Silicone Foams for Exceptional Long-Term Thermal Protection." Advanced Functional Materials. 35 (3). https://doi.org/10.1002/adfm.202413362Metal-Organic Frameworks: A Solution for Greener Polymeric Materials with Low Fire Hazards
Sun, Xiuhong, Miao, Weijia, Pan, Ye-Tang, Song, Song, Gaan, Sabyasachi, Ibarra, Laia Haurie and Yang, Rongjie. 2024. "Metal-Organic Frameworks: A Solution for Greener Polymeric Materials with Low Fire Hazards." Advanced Sustainable Systems. https://doi.org/10.1002/adsu.202400768Valence Band Modification and Enhanced Phonon-Phonon Interactions for High Thermoelectric Performance in GeTe
Zhu, Jianglong, Li, Ruiheng, Tan, Xiaobo, Feng, Fan, Sun, Qiang, Song, Pingan, Hong, Min and Ang, Ran. 2024. "Valence Band Modification and Enhanced Phonon-Phonon Interactions for High Thermoelectric Performance in GeTe." Advanced Functional Materials. https://doi.org/10.1002/adfm.202417260Asymmetric Aramid Aerogel Composite with Durable and Covert Thermal Management via Janus Heat Transfer Structure
Wu, Jianpeng, Wang, Yu, Song, Pingan, Sang, Min, Fan, Ziyang, Xu, Yunqi, Wang, Xinyi, Liu, Shuai, Li, Zimu, Xuan, Shouhu, Leung, Ken Cham-Fai and Gong, Xinglong. 2024. "Asymmetric Aramid Aerogel Composite with Durable and Covert Thermal Management via Janus Heat Transfer Structure." Nano Letters: a journal dedicated to nanoscience and nanotechnology. 24 (44), p. 14020–14027. https://doi.org/10.1021/acs.nanolett.4c03652Low-Cost Hyperelastic Fuller-Dome-Structured Nanocellulose Aerogels by Dual Templates for Personal Thermal Management
Wang, Guang, Feng, Jiabing, Zhou, Zhezhe, Liu, Zheng, Wu, Jianpeng, Li, Jingchao, Gao, Qiang, Lynch, Mark, Li, Jianzhang and Song, Pingan. 2024. "Low-Cost Hyperelastic Fuller-Dome-Structured Nanocellulose Aerogels by Dual Templates for Personal Thermal Management." Advanced Materials. https://doi.org/10.1002/adma.202414896Superhydrophobic, Multifunctional, and Mechanically Durable Carbon Aerogel Composites for High-Performance Underwater Piezoresistive Sensing
Yang, Mingzhou, Wen, Jing, Han, Jiang, Zheng, Tingting, Li, Xinxin, Liu, Yuntao, Yan, Jun, Wu, Haidi, Huang, Xuewu, Xue, Huaiguo, Shi, Y., Tang, Longcheng, Song, Pingan and Gao, Jiefeng. 2024. "Superhydrophobic, Multifunctional, and Mechanically Durable Carbon Aerogel Composites for High-Performance Underwater Piezoresistive Sensing." ACS Applied Materials and Interfaces. 16 (46), pp. 64101-64112. https://doi.org/10.1021/acsami.4c16924Transparent, intrinsically fire-safe yet impact-resistant poly(carbonates-b-siloxanes) containing Schiff-base and naphthalene-sulfonate
Sai, Ting, Ye, Xiaodi, Wang, Bingtao, Guo, Zhenghong, Li, Juan, Fang, Zhengping and Huo, Siqi. 2024. "Transparent, intrinsically fire-safe yet impact-resistant poly(carbonates-b-siloxanes) containing Schiff-base and naphthalene-sulfonate." Journal of Materials Science and Technology. https://doi.org/10.1016/j.jmst.2024.11.023