A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure

Article

Huo, Siqi, Wang, Cheng, Hu, Qinghua, Liu, Shi, Zhang, Qi and Liu, Zhitian. 2020. "A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure." Journal of Coatings Technology and Research. 17 (5), pp. 1401-1411. https://doi.org/10.1007/s11998-020-00360-1
Article Title

A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure

ERA Journal ID4912
Article CategoryArticle
AuthorsHuo, Siqi, Wang, Cheng, Hu, Qinghua, Liu, Shi, Zhang, Qi and Liu, Zhitian
Journal TitleJournal of Coatings Technology and Research
Journal Citation17 (5), pp. 1401-1411
Number of Pages11
Year2020
PublisherSpringer
Place of PublicationUnited Kingdom
ISSN1356-0751
1476-4865
1547-0091
1935-3804
Digital Object Identifier (DOI)https://doi.org/10.1007/s11998-020-00360-1
Web Address (URL)https://link.springer.com/article/10.1007/s11998-020-00360-1
AbstractAn intumescent fire-retardant coating (IFRC) with improved fire resistance and water tolerance was prepared in this work, resulting from the introduction of microcapsuled ammonium polyphosphate (MFAPP) and zinc borate (MFBZ). The as-prepared coating exhibited great fire resistance and smoke suppression. In the cone calorimetry test, adding only 6 wt% MFBZ dramatically reduced the peak heat release rate, total heat release, and total smoke release by ~ 23.4%, ~ 54.7%, and ~ 81.1%, respectively. In addition, the water resistance and thermal stability of the coatings were also characterized. The char yield of IFRC noticeably increased to 41.7%, indicating good high-temperature stability. Besides, the IFRC showed a water contact angle of 90.1° and maintained good structure and fire resistance after being soaked by water, indicating great water resistance. The enhanced performance portfolio was mainly due to the synergistic effects of ammonium polyphosphate, pentaerythritol, melamine, and zinc borate, and the hydrophobicity of melamine–formaldehyde resin (MF). This work offers an effective approach for the preparation of waterborne intumescent fire-retardant coatings with great fire resistance and water tolerance. Graphic abstract: [Figure not available: see fulltext.] © 2020, American Coatings Association.
KeywordsFire resistance
ANZSRC Field of Research 2020401602. Composite and hybrid materials
Public NotesFiles associated with this item cannot be displayed due to copyright restrictions.
Byline AffiliationsWuhan Institute of Technology, China
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A Liquid Phosphaphenanthrene-Derived Imidazole for Improved Flame Retardancy and Smoke Suppression of Epoxy Resin
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Sulfonated Block Ionomers Enable Transparent, Fire-Resistant, Tough yet Strong Polycarbonate
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Synthesis of s-triazine based tri-imidazole derivatives and their application as thermal latent curing agents for epoxy resin
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Synthesis of Fe@Ni nanoparticles-modified graphene/epoxy composites with enhanced microwave absorption performance
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Synthesis of a novel reactive flame retardant containing phosphaphenanthrene and triazine-trione groups and its application in unsaturated polyester resin
Huo, Siqi, Wang, Jun, Yang, Shuang, Cai, Haopeng, Zhang, Bin, Chen, Xi, Wu, Qilei and Yang, Lingfeng. 2018. "Synthesis of a novel reactive flame retardant containing phosphaphenanthrene and triazine-trione groups and its application in unsaturated polyester resin." Materials Research Express. 5 (3). https://doi.org/10.1088/2053-1591/aab2da
Synergistic effect between a novel triazine‐based flame retardant and DOPO/HPCP on epoxy resin
Huo, Siqi, Wang, Jun, Yang, Shuang, Cai, Haopeng, Zhang, Bin, Chen, Xi, Wu, Qilei and Yang, Lingfeng. 2018. "Synergistic effect between a novel triazine‐based flame retardant and DOPO/HPCP on epoxy resin." Polymers for Advanced Technologies. 29 (11), pp. 2774-2783. https://doi.org/10.1002/pat.4400
Study on properties of flame‐retardant cyanate esters modified with DOPO and triazine compounds
Chen, Xi, Wang, Jun, Huo, Siqi, Yang, Shuang, Zhang, Bin and Cai, Haopeng. 2018. "Study on properties of flame‐retardant cyanate esters modified with DOPO and triazine compounds." Polymers for Advanced Technologies. 29 (10), pp. 2574-2582. https://doi.org/10.1002/pat.4368
Preparation of flame-retardant cyanate ester resin combined with phosphorus-containing maleimide
Chen, Xi, Wang, Jun, Huo, Siqi, Yang, Shuang, Zhang, Bin and Cai, Haopeng. 2018. "Preparation of flame-retardant cyanate ester resin combined with phosphorus-containing maleimide." Journal of Thermal Analysis and Calorimetry: an international forum for thermal studies. 132 (3), pp. 1617-1628. https://doi.org/10.1007/s10973-018-6979-3
Low content Ag-coated poly(acrylonitrile) microspheres and graphene for enhanced microwave absorption performance epoxy composites
Zhang, Bin, Wang, Jun, Chen, Xiaocheng, Su, Xiaogang, Zou, Yi, Huo, Siqi, Chen, Wei and Wang, Junpeng. 2018. "Low content Ag-coated poly(acrylonitrile) microspheres and graphene for enhanced microwave absorption performance epoxy composites." Materials Research Express. 5 (4). https://doi.org/10.1088/2053-1591/aabd28
Graphitized nitrogen-doped porous carbon composites derived from ZIF-8 as efficient microwave absorption materials
Wu, Qilei, Jin, Huihui, Chen, Wei, Huo, Siqi, Chen, Xi, Su, Xiaogang, Wang, Hang and Wang, Jun. 2018. "Graphitized nitrogen-doped porous carbon composites derived from ZIF-8 as efficient microwave absorption materials." Materials Research Express. 5 (6). https://doi.org/10.1088/2053-1591/aac67e
Flame-retardant performance and mechanism of epoxy thermosets modified with a novel reactive flame retardant containing phosphorus, nitrogen, and sulfur
Huo, Siqi, Wang, Jun, Yang, Shuang, Chen, Xi, Zhang, Bin, Wu, Qilei and Zhang, Bo. 2018. "Flame-retardant performance and mechanism of epoxy thermosets modified with a novel reactive flame retardant containing phosphorus, nitrogen, and sulfur." Polymers for Advanced Technologies. 29 (1), pp. 497-506. https://doi.org/10.1002/pat.4145
Enhanced microwave absorption property of epoxy nanocomposites based on PANI@Fe3O4@CNFs nanoparticles with three-phase heterostructure
Yang, Lingfeng, Cai, Haopeng, Zhang, Bin, Huo, Siqi and Chen, Xi. 2018. "Enhanced microwave absorption property of epoxy nanocomposites based on PANI@Fe3O4@CNFs nanoparticles with three-phase heterostructure." Materials Research Express. 5 (2). https://doi.org/10.1088/2053-1591/aaab8d
Synthesis of a novel reactive flame retardant containing phosphaphenanthrene and piperidine groups and its application in epoxy resin
Huo, Siqi, Wang, Jun, Yang, Shuang, Zhang, Bin, Chen, Xi, Wu, Qilei and Yang, Lingfeng. 2017. "Synthesis of a novel reactive flame retardant containing phosphaphenanthrene and piperidine groups and its application in epoxy resin." Polymer Degradation and Stability. 146, pp. 250-259. https://doi.org/10.1016/j.polymdegradstab.2017.10.015
Enhanced microwave absorption properties of epoxy composites containing graphene decorated with core–shell Fe3O4@polypyrrole nanoparticles
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Coprecipitation synthesis of hollow poly(acrylonitrile) microspheres@CoFe2O4 with graphene as lightweight microwave absorber
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Synthesis of a phosphorus/nitrogen-containing compound based on maleimide and cyclotriphosphazene and its flame-retardant mechanism on epoxy resin
Yang, Shuang, Wang, Jun, Huo, Siqi, Wang, Junpeng and Tang, Yushan. 2016. "Synthesis of a phosphorus/nitrogen-containing compound based on maleimide and cyclotriphosphazene and its flame-retardant mechanism on epoxy resin." Polymer Degradation and Stability. 126, pp. 9-16. https://doi.org/10.1016/j.polymdegradstab.2016.01.011
Synthesis of a novel phosphorus-nitrogen type flame retardant composed of maleimide, triazine-trione, and phosphaphenanthrene and its flame retardant effect on epoxy resin
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Synergistic flame-retardant effect of expandable graphite and phosphorus-containing compounds for epoxy resin: Strong bonding of different carbon residues
Yang, Shuang, Wang, Jun, Huo, Siqi, Wang, Mei, Wang, Junpeng and Zhang, Bin. 2016. "Synergistic flame-retardant effect of expandable graphite and phosphorus-containing compounds for epoxy resin: Strong bonding of different carbon residues." Polymer Degradation and Stability. 128, pp. 89-98. https://doi.org/10.1016/j.polymdegradstab.2016.03.017
Preparation and flame retardancy of DOPO–based epoxy resin containing bismaleimide
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A phosphorus-containing phenolic derivative and its application in benzoxazine resins: Curing behavior, thermal, and flammability properties
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Microwave absorption properties of lightweight absorber based on Fe50Ni50-coated poly(acrylonitrile) microspheres and reduced graphene oxide composites
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Synthesis of a Phosphorus/Nitrogen-Containing Additive with Multifunctional Groups and Its Flame-Retardant Effect in Epoxy Resin
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The synergistic effect of maleimide and phosphaphenanthrene groups on a reactive flame-retarded epoxy resin system
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Preparation and flame retardancy of an intumescent flame-retardant epoxy resin system constructed by multiple flame-retardant compositions containing phosphorus and nitrogen heterocycle
Yang, Shuang, Wang, Jun, Huo, Siqi, Cheng, Liufeng and Wang, Mei. 2015. "Preparation and flame retardancy of an intumescent flame-retardant epoxy resin system constructed by multiple flame-retardant compositions containing phosphorus and nitrogen heterocycle." Polymer Degradation and Stability. 119, pp. 251-259. https://doi.org/10.1016/j.polymdegradstab.2015.05.019
Preparation and flame retardancy of a compounded epoxy resin system composed of phosphorus/nitrogen-containing active compounds
Yang, Shuang, Wang, Jun, Huo, Siqi, Wang, Mei and Wang, Junpeng. 2015. "Preparation and flame retardancy of a compounded epoxy resin system composed of phosphorus/nitrogen-containing active compounds." Polymer Degradation and Stability. 121, pp. 398-406. https://doi.org/10.1016/j.polymdegradstab.2015.10.006
Oral hygiene care for critically ill patients to prevent ventilator-associated pneumonia
Shi, Zongdao, Xie, Huixu, Wang, Ping, Zhang, Qi, Wu, Yan, Chen, E., Ng, Linda, Worthington, Helen V., Needleman, Ian and Furness, Susan. 2013. "Oral hygiene care for critically ill patients to prevent ventilator-associated pneumonia." Cochrane Database of Systematic Reviews. 2013 (8). https://doi.org/10.1002/14651858.CD008367.pub2