Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness

Article


Sai, Ting, Su, Yukai, Shen, Haifeng, Ran, Shiya, Huo, Siqi, Guo, Zhenghong and Fang, Zhengping. 2021. "Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness." ACS Applied Materials and Interfaces. 13 (25), pp. 30061-30075. https://doi.org/10.1021/acsami.1c07153
Article Title

Fabrication and Mechanism Study of Cerium-Based P, N-Containing Complexes for Reducing Fire Hazards of Polycarbonate with Superior Thermostability and Toughness

ERA Journal ID40638
Article CategoryArticle
AuthorsSai, Ting, Su, Yukai, Shen, Haifeng, Ran, Shiya, Huo, Siqi, Guo, Zhenghong and Fang, Zhengping
Journal TitleACS Applied Materials and Interfaces
Journal Citation13 (25), pp. 30061-30075
Number of Pages15
Year2021
PublisherAmerican Chemical Society
Place of PublicationUnited States
ISSN1944-8244
1944-8252
Digital Object Identifier (DOI)https://doi.org/10.1021/acsami.1c07153
Web Address (URL)https://pubs.acs.org/doi/10.1021/acsami.1c07153
Abstract

A superior comprehensive performance is essential for the extensive utilization of polymers. Current flame-retardant strategies for polycarbonates (PCs) usually realize satisfied fire resistance at the cost of thermostability, toughness, and/or mechanical robustness. Thus, we report a rare-earth-based P, N-containing complex with a lamellar aggregated structure [Ce(DPA)3] by a coordination reaction between a tailored ligand and cerium(III) nitrate. The results indicate that incorporating 3 wt % Ce(DPA)3 enables the resultant PC composite to achieve UL-94 V-0 rating, with a 55% reduction in the peak heat release rate. Besides, the initial (T5) and maximum (Tmax1 and Tmax2) decomposition temperatures are significantly increased by 21, 19, and 27 °C, respectively, in an air atmosphere. Moreover, the impact strength and elongation at break of the PC composite containing 3 wt % Ce(DPA)3 are greatly increased by 20 and 59%, respectively, relative to pristine PC, while its tensile strength (57 MPa) is still close to that of bulk PC (60 MPa). Notably, this work provides a novel methodology for revealing the evolution mechanisms of chemical structures of vapor and residual products during thermal decomposition, which is conducive to guiding fire and heat resistance modification of PC in the future.

Keywordsfire-retardant mechanisms; polycarbonate; rare-earth complexes; thermal resistance; toughen
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020401602. Composite and hybrid materials
Public NotesFiles associated with this item cannot be displayed due to copyright restrictions.
Byline AffiliationsNingboTech University, China
Zhejiang University, China
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A benzimidazolyl-substituted cyclotriphosphazene and its application in benzoxazine: Curing behaviors, thermal properties, and fire safety
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Inherent flame-retardant vinyl ester resins with improved heat resistance enabled by additional P/N-containing cross-linking points
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High-performance, intrinsically fire-safe, single-component epoxy resins and carbon fiber reinforced epoxy composites based on two phosphorus-derived imidazoliums
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Facile Approach for Preparing Chitosan/Phosphaphenanthrene-Containing Epoxy Resins with Superior Flame Retardancy and Mechanical Properties
Zhou, Pengcheng, Wang, Junjie, Bai, Ting, Chevali, Venkata, You, Dan and Huo, Siqi. 2023. "Facile Approach for Preparing Chitosan/Phosphaphenanthrene-Containing Epoxy Resins with Superior Flame Retardancy and Mechanical Properties." ACS Applied Polymer Materials. 5 (6), pp. 4256-4265. https://doi.org/10.1021/acsapm.3c00452
A phosphorus-containing tertiary amine hardener enabled flame retardant, heat resistant and mechanically strong yet tough epoxy resins
Yang, Qingshan, Wang, Jun, Chen, Xi, Yang, Shuang, Huo, Siqi, Chen, Qiufei, Guo, Pengzong, Wang, Xiao, Liu, Fu, Chen, Wei, Song, Pingan and Wang, Hao. 2023. "A phosphorus-containing tertiary amine hardener enabled flame retardant, heat resistant and mechanically strong yet tough epoxy resins." Chemical Engineering Journal. 468. https://doi.org/10.1016/j.cej.2023.143811
Flame-retardant poly (L-lactic acid) with enhanced UV protection and well-preserved mechanical properties by a furan-containing polyphosphoramide
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Atom-economic synthesis of an oligomeric P/N-containing fire retardant towards fire-retarding and mechanically robust polylactide biocomposites
Feng, Jiabing, Lu, Yixia, Xie, Hongyan, Zhang, Yan, Huo, Siqi, Liu, Xiaohuan, Flynn, Matt, Xu, Zhiguang, Burey, Paulomi, Lynch, Mark, Wang, Hao and Song, Pingan. 2023. "Atom-economic synthesis of an oligomeric P/N-containing fire retardant towards fire-retarding and mechanically robust polylactide biocomposites." Journal of Materials Science and Technology. 160, pp. 86-95. https://doi.org/10.1016/j.jmst.2023.04.003
A novel hyperbranched phosphorus-boron polymer for transparent, flame-retardant, smoke-suppressive, robust yet tough epoxy resins
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One-step and green synthesis of a bio-based high-efficiency flame retardant for poly (lactic acid)
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Governing effects of melt viscosity on fire performances of polylactide and its fire-retardant systems
Yu, Yueming, Xi, Liangdong, Yao, Miaohong, Liu, Linghui, Zhang, Yan, Huo, Siqi, Fang, Zhengping and Song, Pingan. 2022. "Governing effects of melt viscosity on fire performances of polylactide and its fire-retardant systems." iScience. 25 (3), pp. 1-12. https://doi.org/10.1016/j.isci.2022.103950
A hyperbranched P/N/B-containing oligomer as multifunctional flame retardant for epoxy resins
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Interface nanoengineering of a core-shell structured biobased fire retardant for fire-retarding polylactide with enhanced toughness and UV protection
Yu, Yueming, Zhang, Yan, Xi, Liangdong, Zhao, Zhinuo, Huo, Siqi, Huang, Guobo, Fang, Zhengping and Song, Pingan. 2022. "Interface nanoengineering of a core-shell structured biobased fire retardant for fire-retarding polylactide with enhanced toughness and UV protection." Journal of Cleaner Production. 336, pp. 1-11. https://doi.org/10.1016/j.jclepro.2022.130372
Flame-retardant, transparent, mechanically-strong and tough epoxy resin enabled by high-efficiency multifunctional boron-based polyphosphonamide
Huo, Siqi, Zhou, Zhongxiao, Jiang, Jiawei, Sai, Ting, Ran, Shiya, Fang, Zhengping, Song, Pingan and Wang, Hao. 2022. "Flame-retardant, transparent, mechanically-strong and tough epoxy resin enabled by high-efficiency multifunctional boron-based polyphosphonamide." Chemical Engineering Journal. 427, pp. 1-15. https://doi.org/10.1016/j.cej.2021.131578
A Liquid Phosphaphenanthrene-Derived Imidazole for Improved Flame Retardancy and Smoke Suppression of Epoxy Resin
Huo, Siqi, Yang, Shuang, Wang, Jun, Cheng, Jianwen, Zhang, Qianqian, Hu, Yefa, Ding, Guoping, Zhang, Qiaoxin, Song, Pingan and Wang, Hao. 2020. "A Liquid Phosphaphenanthrene-Derived Imidazole for Improved Flame Retardancy and Smoke Suppression of Epoxy Resin." ACS Applied Polymer Materials. 2 (8), pp. 3566-3575. https://doi.org/10.1021/acsapm.0c00577
Recent advances in fire-retardant carbon-based polymeric nanocomposites through fighting free radicals
Sai, Ting, Ran, Shiya, Guo, Zhenghong, Song, Pingan and Fang, Zhengping. 2022. "Recent advances in fire-retardant carbon-based polymeric nanocomposites through fighting free radicals ." SusMat. 2 (4), pp. 411-434. https://doi.org/10.1002/sus2.73
Green and Facile Synthesis of Bio-Based, Flame-Retardant, Latent Imidazole Curing Agent for Single-Component Epoxy Resin
Wang, Jingsheng, Huo, Siqi, Wang, Jun, Yang, Shuang, Chen, Kaiwen, Li, Chang, Fang, De, Fang, Zhengping, Song, Pingan and Wang, Hao. 2022. "Green and Facile Synthesis of Bio-Based, Flame-Retardant, Latent Imidazole Curing Agent for Single-Component Epoxy Resin ." ACS Applied Polymer Materials. 4 (5), pp. 3564-3574. https://doi.org/10.1021/acsapm.2c00138
Recent advances in fire-retardant rigid polyurethane foam
Zhu, Menghe, Ma, Zhewen, Liu, Lei, Zhang, Jianzhong, Huo, Siqi and Song, Pingan. 2021. "Recent advances in fire-retardant rigid polyurethane foam." Journal of Materials Science and Technology. 112, pp. 315-328. https://doi.org/10.1016/j.jmst.2021.09.062
Sulfonated Block Ionomers Enable Transparent, Fire-Resistant, Tough yet Strong Polycarbonate
Sai, Ting, Ran, Shiya, Huo, Siqi, Guo, Zhenghong, Song, Pingan and Fang, Zhengping. 2021. "Sulfonated Block Ionomers Enable Transparent, Fire-Resistant, Tough yet Strong Polycarbonate." Chemical Engineering Journal. 433, pp. 1-13. https://doi.org/10.1016/j.cej.2021.133264
Improved thermal stability of polyethylene with rare earth trifluoromethanesulfonate
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Construction of multilayer coatings for flame retardancy of ramie fabric using layer-by-layer assembly
Yan, Hongqiang, Zhao, Li, Fang, Zhengping and Wang, Hao. 2017. "Construction of multilayer coatings for flame retardancy of ramie fabric using layer-by-layer assembly." Journal of Applied Polymer Science. 134 (48), pp. 1-11. https://doi.org/10.1002/app.45556
Application of poly(diphenolic acid-phenyl phosphate)-based layer by layer nanocoating in flame retardant ramie fabrics
Yan, Hongqiang, Li, Nannan, Fang, Zhengping and Wang, Hao. 2017. "Application of poly(diphenolic acid-phenyl phosphate)-based layer by layer nanocoating in flame retardant ramie fabrics." Journal of Applied Polymer Science. 134 (20), pp. 1-13. https://doi.org/10.1002/app.44795
A phosphorus/silicon-based, hyperbranched polymer for high-performance, fire-safe, transparent epoxy resins
Shi, Qui, Huo, Siqi, Wang, Cheng, Ye, Guofeng, Yu, Lingfeng, Fang, Zhengping, Wang, Hao and Liu, Zhitian. 2022. "A phosphorus/silicon-based, hyperbranched polymer for high-performance, fire-safe, transparent epoxy resins." Polymer Degradation and Stability. 203, pp. 1-12. https://doi.org/10.1016/j.polymdegradstab.2022.110065
A phosphaphenanthrene-benzimidazole derivative for enhancing fire safety of epoxy resins
Xu, Yixiang, Wang, Junjie, Zhang, Wenbin, Huo, Siqi, Fang, Zhengping, Song, Pingan, Wang, Dong and Wang, Hao. 2022. "A phosphaphenanthrene-benzimidazole derivative for enhancing fire safety of epoxy resins." Reactive and Functional Polymers. 180, pp. 1-9. https://doi.org/10.1016/j.reactfunctpolym.2022.105390
Phenylboronic acid-decorated ZrP nanosheets for enhancing fire resistance, smoke suppression, and water/acid/alkali tolerance of intumescent coatings
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Flame-retardant single-component epoxy resin cured by benzimidazolyl-substituted cyclotriphosphazene: Storage stability, curing behaviors and flame retardancy
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Facile fabrication of single-component flame-retardant epoxy resin with rapid curing capacity and satisfied thermal resistance
Zhao, ZeKun, Wang, Jun, Wang, Jingsheng, Chen, Kaiwen, Zhang, Bin, Chen, Qiufei, Guo, Pengzong, Wang, Xiao, Liu, Fu, Huo, Siqi and Yang, Shuang. 2022. "Facile fabrication of single-component flame-retardant epoxy resin with rapid curing capacity and satisfied thermal resistance." Reactive and Functional Polymers. 170. https://doi.org/10.1016/j.reactfunctpolym.2021.105103
Corrigendum to ’A phosphorus/silicon-based, hyperbranched polymer for high-performance, fire-safe, transparent epoxy resins’ [Polymer Degradation and Stability, 203 (2022) 110065]
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Aqueous Self-Assembly of Bio-Based Flame Retardants for Fire-Retardant, Smoke-Suppressive, and Toughened Polylactic Acid
Liu, Linghui, Yao, Miaohong, Zhang, Huan, Zhang, Yan, Feng, Jiabeng, Fang, Zhengping and Song, Pingan. 2022. "Aqueous Self-Assembly of Bio-Based Flame Retardants for Fire-Retardant, Smoke-Suppressive, and Toughened Polylactic Acid." ACS Sustainable Chemistry and Engineering. 10 (49), p. 16313–16323. https://doi.org/10.1021/acssuschemeng.2c05298
Fully Biobased Surface-Functionalized Microcrystalline Cellulose via Green Self-Assembly toward Fire-Retardant, Strong, and Tough Epoxy Biocomposites
Lou, Gaobo, Ma, Zhewen, Dai, Jinfeng, Bai, Zhicheng, Fu, Shenyuan, Huo, Siqi, Qian, Lijun and Song, Pingan. 2021. "Fully Biobased Surface-Functionalized Microcrystalline Cellulose via Green Self-Assembly toward Fire-Retardant, Strong, and Tough Epoxy Biocomposites." ACS Sustainable Chemistry and Engineering. 9 (40), pp. 13595-13605. https://doi.org/10.1021/acssuschemeng.1c04718
Mechanically Strong, Thermally Healable, and Recyclable Epoxy Vitrimers Enabled by ZnAl-Layer Double Hydroxides
Li, Gaoming, Zhang, Ping, Huo, Siqi, Fu, Yingke, Chen, Lin, Wu, Yeping, Zhang, Yingyu, Chen, Mao, Zhao, Xiuli and Song, Pingan. 2021. "Mechanically Strong, Thermally Healable, and Recyclable Epoxy Vitrimers Enabled by ZnAl-Layer Double Hydroxides." ACS Sustainable Chemistry and Engineering. 9 (6), pp. 2580-2590. https://doi.org/10.1021/acssuschemeng.0c08636
A molecularly engineered bioderived polyphosphate for enhanced flame retardant, UV-blocking and mechanical properties of poly(lactic acid)
Zhang, Yan, Jing, Jian, Liu, Ting, Xi, Liangdong, Sai, Ting, Ran, Shiya, Fang, Zhengping, Huo, Siqi and Song, Pingan. 2021. "A molecularly engineered bioderived polyphosphate for enhanced flame retardant, UV-blocking and mechanical properties of poly(lactic acid)." Chemical Engineering Journal. 411, pp. 1-13. https://doi.org/10.1016/j.cej.2021.128493
A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate
Yang, Shuang, Huo, Siqi, Wang, Jun, Zhang, Bin, Wang, Jingsheng, Ran, Shiya, Fang, Zhengping, Song, Pingan and Wang, Hao. 2021. "A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate." Composites Part B: Engineering. 207, pp. 1-11. https://doi.org/10.1016/j.compositesb.2020.108601
Water governs the mechanical properties of poly(vinyl alcohol)
Li, Lujuan, Xu, Xiaodong, Liu, Lei, Song, Pingan, Cao, Qianqian, Xu, Zhiguang, Fang, Zhengping and Wang, Hao. 2021. "Water governs the mechanical properties of poly(vinyl alcohol)." Polymer. 213, pp. 1-12. https://doi.org/10.1016/j.polymer.2020.123330
Transparent, highly thermostable and flame retardant polycarbonate enabled by rod-like phosphorous-containing metal complex aggregates
Sai, Ting, Ran, Shiya, Guo, Zhenghong, Yan, Hongqiang, Zhang, Yan, Wang, Hao, Song, Pingan and Fang, Zhengping. 2021. "Transparent, highly thermostable and flame retardant polycarbonate enabled by rod-like phosphorous-containing metal complex aggregates." Chemical Engineering Journal. 409, pp. 1-15. https://doi.org/10.1016/j.cej.2020.128223
Phosphorus-containing flame retardant epoxy thermosets: Recent advances and future perspectives
Huo, Siqi, Song, Pingan, Yu, Bin, Ran, Shiya, Chevali, Venkata, Liu, Lei, Fang, Zhengping and Wang, Hao. 2021. "Phosphorus-containing flame retardant epoxy thermosets: Recent advances and future perspectives." Progress in Polymer Science. 114, pp. 1-36. https://doi.org/10.1016/j.progpolymsci.2021.101366
Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants
He, Wentao, Song, Pingan, Yu, Bin, Fang, Zhengping and Wang, Hao. 2020. "Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants." Progress in Materials Science. 114, pp. 1-49. https://doi.org/10.1016/j.pmatsci.2020.100687
Polyphosphoramide-intercalated MXene for simultaneously enhancing the thermal stability, flame retardancy and mechanical properties of polylactide
Xue, Yijiao, Feng, Jiabing, Huo, Siqi, Song, Pingan, Yu, Bin, Liu, Lei and Wang, Hao. 2020. "Polyphosphoramide-intercalated MXene for simultaneously enhancing the thermal stability, flame retardancy and mechanical properties of polylactide." Chemical Engineering Journal. 397, pp. 1-11. https://doi.org/10.1016/j.cej.2020.125336
Deposition growth of Zr-based MOFs on cerium phenylphosphonate lamella towards enhanced thermal stability and fire safety of polycarbonate
Sai, Ting, Ran, Shiya, Guo, Zhenghong, Yan, Hongqiang, Zhang, Yan, Song, Pingan, Zhang, Tao, Wang, Hao and Fang, Zhengping. 2020. "Deposition growth of Zr-based MOFs on cerium phenylphosphonate lamella towards enhanced thermal stability and fire safety of polycarbonate." Composites Part B: Engineering. 197, pp. 1-12. https://doi.org/10.1016/j.compositesb.2020.108064
Core–Shell Bioderived Flame Retardants Based on Chitosan/Alginate Coated Ammonia Polyphosphate for Enhancing Flame Retardancy of Polylactic Acid
Zhang, Yan, Xiong, Zhengquan, Ge, Haodong, Ni, Leikun, Zhang, Tao, Huo, Siqi, Song, Pingan and Fang, Zhengping. 2020. "Core–Shell Bioderived Flame Retardants Based on Chitosan/Alginate Coated Ammonia Polyphosphate for Enhancing Flame Retardancy of Polylactic Acid." ACS Sustainable Chemistry and Engineering. 8 (16), pp. 6402-6412. https://doi.org/10.1021/acssuschemeng.0c00634
A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances
Huo, Siqi, Yang, Shuang, Wang, Jun, Cheng, Jianwen, Zhang, Qianqian, Hu, Yefa, Ding, Guoping, Zhang, Qiaoxin and Song, Pingan. 2020. "A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances." Journal of Hazardous Materials. 386, pp. 1-10. https://doi.org/10.1016/j.jhazmat.2019.121984
Realizing simultaneous improvements in mechanical strength, flame retardancy and smoke suppression of ABS nanocomposites from multifunctional graphene
Huang, Guobo, Huo, Siqi, Xu, Xiaodong, Chen, Wei, Jin, Yanxian, Li, Rongrong, Song, Pingan and Wang, Hao. 2019. "Realizing simultaneous improvements in mechanical strength, flame retardancy and smoke suppression of ABS nanocomposites from multifunctional graphene." Composites Part B: Engineering. 177, pp. 1-10. https://doi.org/10.1016/j.compositesb.2019.107377
Synthesis of decorated graphene with P, N-containing compounds and its flame retardancy and smoke suppression effects on polylactic acid
Ran, Shiya, Fang, Fang, Guo, Zhenghong, Song, Pingan, Cai, Yingfeng, Fang, Zhengping and Wang, Hao. 2019. "Synthesis of decorated graphene with P, N-containing compounds and its flame retardancy and smoke suppression effects on polylactic acid." Composites Part B: Engineering. 170, pp. 41-50. https://doi.org/10.1016/j.compositesb.2019.04.037
Green and Scalable Fabrication of Core–Shell Biobased Flame Retardants for Reducing Flammability of Polylactic Acid
Xiong, Zhengquan, Zhang, Yan, Du, Xiaoyang, Song, Pingan and Fang, Zhengping. 2019. "Green and Scalable Fabrication of Core–Shell Biobased Flame Retardants for Reducing Flammability of Polylactic Acid." ACS Sustainable Chemistry and Engineering. 7 (9), pp. 8954-8963. https://doi.org/10.1021/acssuschemeng.9b01016
Improved flame resistance and thermo-mechanical properties of epoxy resin nanocomposites from functionalized graphene oxide via self-assembly in water
Fang, Fang, Ran, Shiya, Fang, Zhengping, Song, Pingan and Wang, Hao. 2019. "Improved flame resistance and thermo-mechanical properties of epoxy resin nanocomposites from functionalized graphene oxide via self-assembly in water." Composites Part B: Engineering. 165, pp. 406-416. https://doi.org/10.1016/j.compositesb.2019.01.086
A bio-based ionic complex with different oxidation states of phosphorus for reducing flammability and smoke release of epoxy resins
Fang, Fang, Huo, Siqi, Shen, Haifeng, Ran, Shiya, Wang, Hao, Song, Pingan and Fang, Zhengping. 2020. "A bio-based ionic complex with different oxidation states of phosphorus for reducing flammability and smoke release of epoxy resins." Composites Communications. 17, pp. 104-108. https://doi.org/10.1016/j.coco.2019.11.011
Solid Wastes Toward Flame Retardants for Polymeric Materials: A Review
Gao, Chuanhua, Huo, Siqi and Cao, Zhenhu. 2021. "Solid Wastes Toward Flame Retardants for Polymeric Materials: A Review." Frontiers in Materials. 8, pp. 1-11. https://doi.org/10.3389/fmats.2021.712188
Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings
Wang, Cheng, Huo, Siqi, Liu, Shi, Hu, Qinghua, Zhang, Qi and Liu, Zhitian. 2021. "Recycle of magnesium alloy scrap for improving fire resistance, thermal stability, and water tolerance of intumescent fire-retardant coatings." Journal of Coatings Technology and Research. 18 (2), pp. 447-458. https://doi.org/10.1007/s11998-020-00413-5
A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin
Jiang, Jiawei, Huo, Siqi, Zheng, Yi, Yang, Chengyun, Yan, Hongqiang, Ran, Shiya and Fang, Zhengping. 2021. "A Novel Synergistic Flame Retardant of Hexaphenoxycyclotriphosphazene for Epoxy Resin." Polymers. 13 (21), pp. 1-15. https://doi.org/10.3390/polym13213648
Exfoliated and functionalized boron nitride nanosheets towards improved fire resistance and water tolerance of intumescent fire retardant coating
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Thermal properties and flame retardancy of an intumescent flame-retarded epoxy system containing phosphaphenanthrene, triazine-trione and piperidine
Huo, Siqi, Liu, Zhitian and Wang, Jun. 2020. "Thermal properties and flame retardancy of an intumescent flame-retarded epoxy system containing phosphaphenanthrene, triazine-trione and piperidine." Journal of Thermal Analysis and Calorimetry: an international forum for thermal studies. 139 (2), pp. 1099-1110. https://doi.org/10.1007/s10973-019-08467-3
Synthesis of a P/N/S-based flame retardant and its flame retardant effect on epoxy resin
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Synergistic effect of polyhedral iron-cobalt alloys and graphite nanosheets with excellent microwave absorption performance
Su, Xiaogang, Wang, Jun, Zhang, Xiaoxiao, Huo, Siqi, Dai, Wei and Zhang, Bin. 2020. "Synergistic effect of polyhedral iron-cobalt alloys and graphite nanosheets with excellent microwave absorption performance." Journal of Alloys and Compounds. 829. https://doi.org/10.1016/j.jallcom.2020.154426
Study on the plastic deformation zone of Q235 steel via hammering tight seam
Wang, Yingwei, Dong, Xin, Huo, Siqi, Lv, Zhenhua, Ma, Zhongnan, Gao, Jinzhu, Gai, Xiuying and Wang, Rui. 2020. "Study on the plastic deformation zone of Q235 steel via hammering tight seam." Journal of Materials Research and Technology. 9 (4), pp. 7100-7103. https://doi.org/10.1016/j.jmrt.2020.04.030
A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin
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One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance
Su, Xiaogang, Wang, Jun, Zhang, Xiaoxiao, Huo, Siqi, Chen, Wei, Dai, Wei and Zhang, Bin. 2020. "One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance." Ceramics International. 46 (8), pp. 12353-12363. https://doi.org/10.1016/j.ceramint.2020.01.286
Intumescent fire retardant coating with recycled powder from industrial effluent optimized using response surface methodology
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Facile synthesis of cobalt-doped porous composites with amorphous carbon/zn shell for high-performance microwave absorption
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Facile synthesis of Co-embedded porous spherical carbon composites derived from Co3O4/ZIF-8 compounds for broadband microwave absorption
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Design of hierarchical 1D–2D NiCo2O4 as high-performance microwave absorber with strong loss and wide absorbing frequency
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The study of fibre/matrix bond strength in short hemp polypropylene composites from dynamic mechanical analysis
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Xu, Lihua, Fang, Zhengping, Song, Pingan and Peng, Mao. 2010. "Effects of corona discharge on the surface structure, morphology and properties of multi-walled carbon nanotubes." Applied Surface Science. 256 (21), pp. 6447-6453. https://doi.org/10.1016/j.apsusc.2010.04.033
Biodegradable aliphatic/aromatic copolymers based on terephthalic acid and poly(L-lactic acid): Synthesis, characterization and hydrolytic degradation
Wang, Bing-tao, Zhang, Yan, Song, Pingan, Guo, Zhenghong, Cheng, Jie and Fang, Zhengping. 2010. "Biodegradable aliphatic/aromatic copolymers based on terephthalic acid and poly(L-lactic acid): Synthesis, characterization and hydrolytic degradation." Chinese Journal of Polymer Science. 28 (1), pp. 405-415. https://doi.org/10.1007/s10118-010-9032-y
Functionalization of carbon nanotubes by corona-discharge induced graft polymerization for the reinforcement of epoxy nanocomposites
Xu, Lihua, Fang, Zhengping, Song, Pingan and Peng, Mao. 2010. "Functionalization of carbon nanotubes by corona-discharge induced graft polymerization for the reinforcement of epoxy nanocomposites." Plasma Processes and Polymers. 7 (9), pp. 785-793. https://doi.org/10.1002/ppap.201000019
Thermal degradation and flammability properties of HDPE/EVA/C60 nanocomposites
Liu, Hui, Song, Pingan, Fang, Zhengping, Shen, Lie and Peng, Mao. 2010. "Thermal degradation and flammability properties of HDPE/EVA/C60 nanocomposites." Thermochimica Acta. 506 (1), pp. 98-101. https://doi.org/10.1016/j.tca.2010.04.029
Synthesis, characterization, and properties of degradable poly(l-lactic acid)/poly(butylene terephthalate) copolyesters containing 1,4-cyclohexanedimethanol
Wang, Bingtao, Zhang, Yan, Song, Pingan, Guo, Zhenghong, Cheng, Jie and Fang, Zhengping. 2010. "Synthesis, characterization, and properties of degradable poly(l-lactic acid)/poly(butylene terephthalate) copolyesters containing 1,4-cyclohexanedimethanol." Journal of Applied Polymer Science. 120 (5), pp. 2985-2995. https://doi.org/10.1002/app.33373
Flame retardant mechanism of organo-bentonite in polypropylene
Du, Baoxian, Guo, Zhenghong, Song, Pingan, Liu, Hui, Fang, Zhengping and Wu, Yu. 2009. "Flame retardant mechanism of organo-bentonite in polypropylene." Applied Clay Science. 45 (3), pp. 178-184. https://doi.org/10.1016/j.clay.2009.05.003
Synthesis of a novel oligomeric intumescent flame retardant and its application in polypropylene
Song, Pingan, Fang, Zhengping, Tong, Lifang and Xu, Zhongbin. 2009. "Synthesis of a novel oligomeric intumescent flame retardant and its application in polypropylene." Polymer Engineering and Science. 48 (7), pp. 1326-1331. https://doi.org/10.1002/pen.21153
Fabrication of fullerene (C60) decorated carbon nanotubes and their application in flame-retarding polypropylene
Song, Pingan, Shen, Yu, Du, Baoxian, Guo, Zhenghong and Fang, Zhengping. 2009. "Fabrication of fullerene (C60) decorated carbon nanotubes and their application in flame-retarding polypropylene." Nanoscale. 1 (1), pp. 118-121. https://doi.org/10.1039/B9NR00026G
Effects of reactive compatibilization on the morphological, thermal, mechanical and rheological properties of intumescent flame retarded polypropylene
Song, Pingan, Shen, Yu, Du, Baoxian, Peng, Mao, Shen, Lie and Fang, Zhengping. 2009. "Effects of reactive compatibilization on the morphological, thermal, mechanical and rheological properties of intumescent flame retarded polypropylene." ACS Applied Materials and Interfaces. 1 (2), pp. 452-459. https://doi.org/10.1021/am8001204
Fabrication of dendrimer-like fullerene (C60) decorated oligomeric intumescent flame retardant for reducing the thermal oxidation and flammability of polypropylene nanocomposites
Song, Pingan, Liu, Hui, Shen, Yu, Du, Baoxian, Fang, Zhengping and Wu, Yu. 2009. "Fabrication of dendrimer-like fullerene (C60) decorated oligomeric intumescent flame retardant for reducing the thermal oxidation and flammability of polypropylene nanocomposites." Journal of Materials Chemistry. 19 (9), pp. 1305-1313. https://doi.org/10.1039/b815610g
Surface-initiated graft polymerization on multiwalled carbon nanotubes pretreated by corona discharge at atmospheric pressure
Xu, Lihua, Fang, Zhengping, Song, Pingan and Peng, Mao. 2009. "Surface-initiated graft polymerization on multiwalled carbon nanotubes pretreated by corona discharge at atmospheric pressure." Nanoscale. 2 (3), pp. 389-393. https://doi.org/10.1039/B9NR00222G
Flame-retardant-wrapped carbon nanotubes for simultaneously improving the flame retardancy and mechanical properties of polypropylene
Song, Ping'an, Xu, Lihua, Guo, Zhenghong, Zhang, Yan and Fang, Zhengping. 2008. "Flame-retardant-wrapped carbon nanotubes for simultaneously improving the flame retardancy and mechanical properties of polypropylene." Journal of Materials Chemistry. 18 (42), pp. 5083-5091. https://doi.org/10.1039/b808309f
C60 reduces the flammability of polypropylene nanocomposites by in situ forming gelled-ball network
Song, Pingan, Zhu, Yan, Tong, Lifang and Fang, Zhengping. 2008. "C60 reduces the flammability of polypropylene nanocomposites by in situ forming gelled-ball network." Nanotechnology. 19 (22). https://doi.org/10.1088/0957-4484/19/22/225707
Polypropylene/clay nanocomposites prepared by in situ grafting–melt intercalation with a novel co-intercalating monomer
Song, Pingan, Tong, Lifang and Fang, Zhengping. 2008. "Polypropylene/clay nanocomposites prepared by in situ grafting–melt intercalation with a novel co-intercalating monomer." Journal of Applied Polymer Science. 110 (1), pp. 616-623. https://doi.org/10.1002/app.28689
Thermal degradation and flame retardancy of polypropylene/C60 nanocomposites
Fang, Zhengping, Song, Pingan, Tong, Lifang and Guo, Zhenghong. 2008. "Thermal degradation and flame retardancy of polypropylene/C60 nanocomposites." Thermochimica Acta. 473 (1), pp. 106-108. https://doi.org/10.1016/j.tca.2008.04.019
Effects of metal chelates on a novel oligomeric intumescent flame retardant system for polypropylene
Song, Pingan, Fang, Zhengping, Tong, Lifang, Jin, Yongming and Lu, Fengzhu. 2008. "Effects of metal chelates on a novel oligomeric intumescent flame retardant system for polypropylene." Journal of Analytical and Applied Pyrolysis. 82 (2), pp. 286-291. https://doi.org/10.1016/j.jaap.2008.04.008