A lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating
Article
Ma, Zhewen, Zhang, Jianzhong, Maluk, Cristian, Yu, Youming, Seraji, Seyed Mohsen, Yu, Bin, Wang, Hao and Song, Pingan. 2022. "A lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating." Matter. 5 (3), pp. 911-932. https://doi.org/10.1016/j.matt.2021.12.009
| Article Title | A lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating |
|---|---|
| ERA Journal ID | 213649 |
| Article Category | Article |
| Authors | Ma, Zhewen (Author), Zhang, Jianzhong (Author), Maluk, Cristian (Author), Yu, Youming (Author), Seraji, Seyed Mohsen (Author), Yu, Bin (Author), Wang, Hao (Author) and Song, Pingan (Author) |
| Journal Title | Matter |
| Journal Citation | 5 (3), pp. 911-932 |
| Number of Pages | 22 |
| Year | 2022 |
| Publisher | Cell Press |
| Place of Publication | United States |
| ISSN | 2590-2385 |
| 2590-2393 | |
| Digital Object Identifier (DOI) | https://doi.org/10.1016/j.matt.2021.12.009 |
| Web Address (URL) | https://www.sciencedirect.com/science/article/abs/pii/S2590238521006342 |
| Abstract | Fire-retardant coatings have demonstrated effective fire protection for various materials, ranging from flammable polymeric foam and wood to nonflammable steel. However, the poor cost effectiveness has significantly impeded their real-world applications. In nature, lava is a flowing, noncombustible molten liquid with a low thermal conductivity. We, herein, report a lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid coating comprising low-melting glass powders (GPs), such as ceramic precursors; boron nitride (BN) nanosheets as synergists; and a fire-retardant polymer as a coating base. Upon exposure to flame, the coating forms a lava-like noncombustible ceramic char layer that can serve as a robust fire shield for underlying substrates. The hybrid coating-treated polyurethane foam exhibits a rapid self-extinguishing behavior and increased compressive strength, outperforming its previous counterparts. Meanwhile, the hybrid coating offers exceptional fire protection for solid wood and steel. This work provides a bioinspired strategy for creating cost-effective fire-retardant coatings for diverse industrial applications and a fire-safe world. |
| Keywords | bioinspired design; organic-inorganic hybrid coating; fire retardants; fire retardancy; fire protection ceramic char layer |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 401605. Functional materials |
| 401602. Composite and hybrid materials | |
| Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
| Byline Affiliations | Zhejiang A & F University, China |
| University of Queensland | |
| Centre for Future Materials | |
| University of Science and Technology of China, Hefei, China | |
| Institution of Origin | University of Southern Queensland |
| Funding source | Australian Research Council (ARC) Grant ID FT190100188 |
| Funding source | Australian Research Council (ARC) Grant ID DP190102992 |
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Wang, Hao and Ning, Zhiliang. 2007. "Magnesium thixotropic structure produced by controlled nucleation method ." Tezhong Zhuzao Ji Youse Hejin (Special Casting and Nonferrous Alloys).In-situ Si/Al composite produced by semisolid metal processing
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Wang, H., Estrin, Y., Fu, H. M., Song, G. L. and Zuberova, Z.. 2007. "The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31." Advanced Engineering Materials. 9 (11), pp. 967-972. https://doi.org/10.1002/adem.200700200Effects of carbon nanotubes and metal catalysts on hydrogen storage in magnesium nanocomposite
Yao, X. D., Wu, C. Z., Wang, Hao, Cheng, H. M. and Lu, G. Q.. 2006. "Effects of carbon nanotubes and metal catalysts on hydrogen storage in magnesium nanocomposite." Journal of Nanoscience and Nanotechnology. 6 (2), pp. 494-498.In situ TiB-reinforced cu-based bulk metallic glass composites
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "In situ TiB-reinforced cu-based bulk metallic glass composites." Scripta Materialia. 54 (11), pp. 1961-1966. https://doi.org/10.1016/j.scriptamat.2006.01.048In-situ Cu-based bulk metallic glass composite
Wang, Hao, Fu, H. M., Zhang, H. F. and Hu, Z. Q.. 2006. "In-situ Cu-based bulk metallic glass composite." International Journal of Modern Physics B. 20 (25-27), pp. 3963-3968. https://doi.org/10.1142/S0217979206040696The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy
Fu, H. M., Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy." Scripta Materialia. 55 (2), pp. 147-150. https://doi.org/10.1016/j.scriptamat.2006.03.052Modeling of semisolid structure formation in controlled nucleation method
Yao, X. and Wang, H.. 2006. "Modeling of semisolid structure formation in controlled nucleation method ." International Journal of Modern Physics B. 20 (25-27), pp. 4123-4128. https://doi.org/10.1142/S0217979206040969In-situ Si/Al composite produced by semisolid metal processing
Wang, Hao. 2006. "In-situ Si/Al composite produced by semisolid metal processing ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2006. "Tungsten fibre reinforced Zr-based bulk metallic glass composites ." Bandyopadhyay, Sri, Zeng, Q., Berndt, Christopher C., Rizkalla, S., Gowripalan, N. and Matison, Janison (ed.) ACUN-5 International Composites Conference. Sydney, Australia 11 - 14 Jul 2006 Sydney, Australia.Tungsten fibre reinforced Zr-based bulk metallic glass composites
Wang, Hao, Zhang, H. F. and Hu, Z. Q.. 2007. "Tungsten fibre reinforced Zr-based bulk metallic glass composites." Materials and Manufacturing Processes. 22 (5-6), pp. 687-691. https://doi.org/10.1080/10426910701384922The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ
Kahandawa, Gayan C., Epaarachchi, Jayantha A., Wang, Hao and Aravinthan, Thiru. 2010. "The developments of structural health/integrity monitoring systems using FBG sensors at CEEFC of USQ." Goh, Steven C. and Wang, Hao (ed.) 2010 Southern Region Engineering Conference (SREC 2010). Toowoomba, Australia 11 - 12 Nov 2010 Toowoomba, Australia.Sustainable materials research at USQ
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Zhu, Zhengwang, Zhang, Haifeng, Wang, Hao, Ding, Bingzhe, Hu, Zhuang-Qi and Huang, Han. 2009. "Influence of casting temperature on microstructures and mechanical properties of Cu50Zr45.5Ti2.5Y2 metallic glass prepared using copper mold casting [+ Erratum]." Journal of Materials Research. 24 (10), pp. 3108-3115. https://doi.org/10.1557/jmr.2009.0373Deformation behavior of semisolid A356 alloy prepared by low temperature pouring
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Ning, Z. L., Wang, H., Liu, H. H., Cao, F. Y., Wang, S. T. and Sun, J. F.. 2010. "Effects of Nd on microstructures and properties at the elevated temperature of a Mg-0.3Zn-0.32Zr alloy." Materials and Design. 31 (9), pp. 4438-4444. https://doi.org/10.1016/j.matdes.2010.04.021The role of casting temperature in preparation of bulk metallic glasses
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Xu, Lihua, Fang, Zhengping, Song, Pingan and Peng, Mao. 2010. "Functionalization of carbon nanotubes by corona-discharge induced graft polymerization for the reinforcement of epoxy nanocomposites." Plasma Processes and Polymers. 7 (9), pp. 785-793. https://doi.org/10.1002/ppap.201000019Thermal degradation and flammability properties of HDPE/EVA/C60 nanocomposites
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