Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications
Article
Zhou, Rusen, Wang, Xiaoxiang, Zhou, Renwu, Weerasinghe, Janith, Zhang, Tianqi, Xin, Yanbin, Wang, Hao, Cullen, Patrick, Wang, Hongxia and Ostrikov, Kostya Ken. 2022. "Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications." Frontiers of Chemical Science and Engineering. 16 (4), pp. 475-483. https://doi.org/10.1007/s11705-021-2070-x
| Article Title | Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications |
|---|---|
| ERA Journal ID | 3959 |
| Article Category | Article |
| Authors | Zhou, Rusen, Wang, Xiaoxiang, Zhou, Renwu, Weerasinghe, Janith, Zhang, Tianqi, Xin, Yanbin, Wang, Hao, Cullen, Patrick, Wang, Hongxia and Ostrikov, Kostya Ken |
| Journal Title | Frontiers of Chemical Science and Engineering |
| Journal Citation | 16 (4), pp. 475-483 |
| Number of Pages | 9 |
| Year | 2022 |
| Publisher | Springer |
| Place of Publication | China |
| ISSN | 2095-0179 |
| 2095-0187 | |
| Digital Object Identifier (DOI) | https://doi.org/10.1007/s11705-021-2070-x |
| Web Address (URL) | https://link.springer.com/article/10.1007/s11705-021-2070-x |
| Abstract | Surface functionalization or modification to introduce more oxygen-containing functional groups to biochar is an effective strategy for tuning the physico-chemical properties and promoting follow-up applications. In this study, non-thermal plasma was applied for biochar surface carving before being used in contaminant removal and energy storage applications. The results showed that even a low dose of plasma exposure could introduce a high number density of oxygen-functional groups and enhance the hydrophilicity and metal affinity of the pristine biochar. The plasma-treated biochar enabled a faster metal-adsorption rate and a 40% higher maximum adsorption capacity of heavy metal ion Pb2+. Moreover, to add more functionality to biochar surface, biochar with and without plasma pre-treatment was activated by KOH at a temperature of 800 °C. Using the same amount of KOH, the plasma treatment resulted in an activated carbon product with the larger BET surface area and pore volume. The performance of the treated activated carbon as a supercapacitor electrode was also substantially improved by > 30%. This study may provide guidelines for enhancing the surface functionality and application performances of biochar using non-thermal-based techniques. |
| Keywords | non-thermal plasma; supercapacitor; wastewater treatment; biochar modification; surface functionalization |
| Contains Sensitive Content | Does not contain sensitive content |
| ANZSRC Field of Research 2020 | 401703. Energy generation, conversion and storage (excl. chemical and electrical) |
| Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
| Byline Affiliations | Dalian Maritime University, China |
| Queensland University of Technology | |
| University of Sydney | |
| Centre for Future Materials |
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Sun, Yiqi, Ma, Zhewen, Xu, Xiaodong, Liu, Xiaohuan, Liu, Lina, Huang, Guobo, Liu, Lei, Wang, Hao and Song, Pingan. 2020. "Grafting Lignin with Bioderived Polyacrylates for Low-Cost, Ductile, and Fully Biobased Poly(lactic acid) Composite." ACS Sustainable Chemistry and Engineering. 8 (5), pp. 2267-2276. https://doi.org/10.1021/acssuschemeng.9b06593Realizing simultaneous improvements in mechanical strength, flame retardancy and smoke suppression of ABS nanocomposites from multifunctional graphene
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Sethurajaperumal, Abimannan, Manohar, Anagha, Banerjee, Arghya, Varrla, Eswaraiah, Wang, Hao and Ostrikov, Kostya (Ken). 2021. "A thermally insulating vermiculite nanosheet-epoxy nanocomposite paint as a fire-resistant wood coating." Nanoscale Advances. 3 (14), pp. 4235-4243. https://doi.org/10.1039/d1na00207dControllable Polarization and Doping in Ferroelectric In2Se3 Monolayers and Heterobilayers via Intrinsic Defect Engineering
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Hoang, Minh Tam, Pham, Ngoc Du, Yang, Yang, Tiong, Vincent Tiing, Zhang, Chao, Gui, Ke, Chen, Hong, Chang, Jin, Wang, Jianpu, Golberg, Dmitri, Bell, John and Wang, Hongxia. 2020. "A facile, environmentally friendly synthesis of strong photo-emissive methylammonium lead bromide perovskite nanocrystals enabled by ionic liquids." Green Chemistry. 22 (11), pp. 3433-3440. https://doi.org/10.1039/d0gc01081bEnhanced perovskite electronic properties via a modified lead(ii) chloride Lewis acid-base adduct and their effect in high-efficiency perovskite solar cells
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Wang, Teng, Zhang, Shengli, Yan, Xingbin, Lyu, Miaoqiang, Wang, Lianzhou, Bell, John and Wang, Hongxia. 2017. "2-methylimidazole-derived Ni-Co layered double hydroxide nanosheets as high rate capability and high energy density storage material in hybrid supercapacitors." ACS Applied Materials and Interfaces. 9 (18), pp. 15510-15524. https://doi.org/10.1021/acsami.7b02987High capacitive amorphous barium nickel phosphate nanofibers for electrochemical energy storage
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Zhang, Shengli, Pham, Ngoc Duy, Tesfamichael, Tuquabo, Bell, John and Wang, Hongxia. 2018. "Thermal effect on CZTS solar cells in different process of ZnO/ITO window layer fabrication." Sustainable Materials and Technologies. 18, pp. 1-8. https://doi.org/10.1016/j.susmat.2018.e00078Octadecylamine-functionalized single-walled carbon nanotubes for facilitating the formation of a monolithic perovskite layer and stable solar cells
Tiong, Vincent Tiing, Pham, Ngoc Duy, Wang, Teng, Zhu, Tianxiang, Zhao, Xinluo, Zhang, Yaohong, Shen, Qing, Bell, John, Hu, Linhua, Dai, Songyuan and Wang, Hongxia. 2018. "Octadecylamine-functionalized single-walled carbon nanotubes for facilitating the formation of a monolithic perovskite layer and stable solar cells." Advanced Functional Materials. 28 (10). https://doi.org/10.1002/adfm.201705545Morphology evolution and stability of Cu2ZnSnS4 nanocrystals in sodium halides salt solution
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Xiao, Xianglian, Chevali, Venkata S., Song, Pingan, Yu, Bin, Yang, Yihu and Wang, Hao. 2020. "Enhanced toughness of PLLA/PCL blends using poly(d-lactide)-poly(ε-caprolactone)-poly(d-lactide) as compatibilizer." Composites Communications. 21, pp. 1-6. https://doi.org/10.1016/j.coco.2020.100385Oriented graphenes from plasma-reformed coconut oil for supercapacitor electrodes
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Do, Thu Trang, Patil, Basanagouda B, Singh, Samarendra P, Yambem, Soniya D, Feron, Krishna, Ostrikov, Kostya (Ken), Bell, John M and Sonar, Prashant. 2018. "Vinylene and benzo[c] [1,2,5]thiadiazole: Effect of the pi-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistors." RSC Advances: an international journal to further the chemical sciences. 8 (68), pp. 38919-38928. https://doi.org/10.1039/c8ra08890jLow hysteresis perovskite solar cells using an electron-beam evaporated WO3-x thin film as the electron transport layer
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Pan, Yangli, Xu, Xiaomin, Zhong, Yijun, Ge, Lei, Chen, Yubo, Veder, Jean-Pierre Marcel, Guan, Daqin, O’Hayre, Ryan, Li, Mengran, Wang, Guoxiong, Wang, Hao, Zhou, Wei and Shao, Zongping. 2020. "Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation." Nature Communications. 11, pp. 1-10. https://doi.org/10.1038/s41467-020-15873-xCurrent status of carbon fibre and carbon fibre composites recycling
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Wang, Yuan, Liu, Wei-Di, Shi, XIao-Lei, Hong, Min, Wang, Li-Jun, Li, Meng, Wang, Hao, Zou, Jin and Chen, Zhi-Gang. 2020. "Enhanced thermoelectric properties of nanostructured n-type Bi2Te3 by suppressing Te vacancy through non-equilibrium fast reaction." Chemical Engineering Journal. 391. https://doi.org/10.1016/j.cej.2019.123513Development of a new calcium sulfoaluminate (synthetic ye'elimite) blended PII 52.5 cement
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Ma, Y., Yang, X., Hu, J., Zhang, Z. and Wang, H.. 2019. "Accurate determination of the 'time-zero' of autogenous shrinkage in alkali-activated fly ash/slag system." Composites Part B: Engineering. 177, pp. 1-8. https://doi.org/10.1016/j.compositesb.2019.107367Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites
Ma, Xue, Li, Liang-feng, Zhang, Fan, Zhang, Zu-hua, Wang, Hao and Wang, En-ze. 2018. "Microstructure and wear characteristics of ATZ ceramic particle reinforced gray iron matrix surface composites." China Foundry. 15 (3), pp. 167-172. https://doi.org/10.1007/s41230-018-7211-6New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers
Longhi, Marlon, Walkley, Brant, Rodriguez, Erich D, Kirchheim, Ana P, Zhang, Zuhua and Wang, Hao. 2019. "New selective dissolution process to quantify reaction extent and product stability in metakaolin-based geopolymers." Composites Part B: Engineering. 176 (1). https://doi.org/10.1016/j.compositesb.2019.107172Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock
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Longhi, Marlon, Zhang, Zuhua, Rodriguez, Erich, Kirchheim, Ana and Wang, Hao. 2019. "Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis." Frontiers in Materials. 6, pp. 1-13. https://doi.org/10.3389/fmats.2019.00089A review on mixture design methods for geopolymer concrete
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Zhang, Zuhua, Zhu, Yingcan, Zhu, Huajun, Zhang, Yu, Provis, John L. and Wang, Hao. 2019. "Effect of drying procedures on pore structure and phase evolution of alkali-activated cements." Cement and Concrete Composites. 96, pp. 194-203. https://doi.org/10.1016/j.cemconcomp.2018.12.003Fire-resistant, strong and green polymer nanocomposites based on poly(lactic acid) and core-shell nanofibrous flame retardants
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Song, Pingan, Dai, Jinfeng, Chen, Guorong, Yu, Youming, Fang, Zhengping, Lei, Weiwei, Fu, Shenyuan, Wang, Hao and Chen, Zhi-Gang. 2018. "Bioinspired design of strong, tough, and thermally stable polymeric materials via nanoconfinement." ACS Nano. 12 (9), pp. 9266-9278. https://doi.org/10.1021/acsnano.8b04002Fabrication of flame retardant benzoxazine semi-biocomposites reinforced by ramie fabrics with bio-based flame retardant coating
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Yan, Hongqiang, Wang, Huaqing, Cheng, Jie, Fang, Zhengping and Wang, Hao. 2015. "Effect of iron acetylacetonate on the crosslink structure, thermal and flammability properties of novel aromatic diamine-based benzoxazines containing cyano group." RSC Advances: an international journal to further the chemical sciences. 5 (24), pp. 18538-18545. https://doi.org/10.1039/c4ra15035jEffects of rare earth La on microstructure and properties of Ag-21Cu-25Sn alloy ribbon prepared by melt spinning
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