Pyrolysis of brominated polyethylene as an alternative carbon fibre precursor

Article


Laycock, Bronwyn, Wang, Xiaoyu, Liu, Ru-Fen, Annamalai, Pratheep Kumar, Cork, Jorja, Derstine, Chris, Mills, Michael and McFarland, Eric W.. 2020. "Pyrolysis of brominated polyethylene as an alternative carbon fibre precursor." Polymer Degradation and Stability. 172. https://doi.org/10.1016/j.polymdegradstab.2019.109057
Article Title

Pyrolysis of brominated polyethylene as an alternative carbon fibre precursor

ERA Journal ID1691
Article CategoryArticle
AuthorsLaycock, Bronwyn, Wang, Xiaoyu, Liu, Ru-Fen, Annamalai, Pratheep Kumar, Cork, Jorja, Derstine, Chris, Mills, Michael and McFarland, Eric W.
Journal TitlePolymer Degradation and Stability
Journal Citation172
Article Number109057
Number of Pages11
Year2020
PublisherElsevier
Place of PublicationUnited Kingdom
ISSN0141-3910
0144-2880
1873-2321
Digital Object Identifier (DOI)https://doi.org/10.1016/j.polymdegradstab.2019.109057
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S0141391019303854
AbstractPolyethylene as a polymeric precursor for carbon fibre production has attracted much attention over recent years. Not only is it a low-cost commodity polymer, it has a higher theoretical carbon yield (at 100%) than polyacrylonitrile (at 67%) and is very readily melt processed into fibres. The challenge is to efficiently dehydrogenate and graphitize polyethylene fibres. This paper explores the use of bromine as a novel oxidant to functionalise polyethylene prior to carbonisation, leading to efficient cyclisation and carbonisation on heating. Through a process of low-temperature photo-induced liquid-phase bromination followed by dehydrobromination at moderate temperature and subsequent carbonisation to 800 °C, a carbonaceous product was obtained in high carbon yield (>90%). The effects of a range of process conditions, as well as the use of different types of polyethylene and polyethylene blends, were explored.
Keywordscarbon fibre; Polyethylene; Pyrolysis
ANZSRC Field of Research 2020401609. Polymers and plastics
340302. Macromolecular materials
Public NotesFiles associated with this item cannot be displayed due to copyright restrictions.
Byline AffiliationsUniversity of Queensland
Fonterra Research and Development Centre, New Zealand
Clean Diesel Technologies, United States
Dow Chemical Company, Germany
University of California Santa Barbara, United States
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