Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions

Article

Liu, Yiting, Li, Wen, Li, Kai, Annamalai, Pratheep Kumar, Pratt, Steven, Hassanpour, Morteza, Lu, Haiqin and Zhang, Zhanying. 2022. "Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions." Carbohydrate Polymers. 291. https://doi.org/10.1016/j.carbpol.2022.119602
Article Title

Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions

ERA Journal ID1568
Article CategoryArticle
AuthorsLiu, Yiting, Li, Wen, Li, Kai, Annamalai, Pratheep Kumar, Pratt, Steven, Hassanpour, Morteza, Lu, Haiqin and Zhang, Zhanying
Journal TitleCarbohydrate Polymers
Journal Citation291
Article Number119602
Number of Pages10
Year2022
PublisherElsevier
Place of PublicationUnited Kingdom
ISSN0144-8617
1879-1344
Digital Object Identifier (DOI)https://doi.org/10.1016/j.carbpol.2022.119602
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S0144861722005070
AbstractIn this study, sugarcane bagasse was pretreated with acid-catalyzed alcohols, i.e., ethanol (AE), ethylene glycol (AEG) and glycerol (AG) to prepare pulps for producing lignin-containing cellulose nanofibrils (LCNF) with tailored properties, such as hydrophilicity/hydrophobicity and dispersion stability. The results showed that AG-LCNF had the highest lignin content of 16% but relatively low hydrophobicity while AE-LCNF had a low lignin content of 11% but the highest hydrophobicity. LCNF diameter distribution, crystallinity, zeta potentials and thermal stability were also determined to understand the effects of pretreatment solvent. NMR analyses revealed that alcohols modified lignin at α-position by etherification and γ-position by esterification of aliphatic chains, subsequently affecting lignin oxidation by TEMPO in the LCNF production processes, LCNF properties and LCNF dispersion in different solvents. This study provided fundamental information in the design and tailored production of LCNF for various applications, such as manufacturing polymer composites and Pickering emulsions.
KeywordsHydrophobicity; Pretreatment; Lignin; Nanocellulose; Alcohol; Hydrophilicity
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020300705. Forestry biomass and bioproducts
340303. Nanochemistry
401807. Nanomaterials
Public NotesFiles associated with this item cannot be displayed due to copyright restrictions.
Byline AffiliationsGuangxi University, China
University of Queensland
Queensland University of Technology
Permalink -

https://research.usq.edu.au/item/z23x3/tailored-production-of-lignin-containing-cellulose-nanofibrils-from-sugarcane-bagasse-pretreated-by-acid-catalyzed-alcohol-solutions

Log in to edit
  • 74
    total views
  • 0
    total downloads
  • 4
    views this month
  • 0
    downloads this month

Export as

Related outputs

A low-cost, antimicrobial aloe-alginate hydrogel film containing Australian First Nations remedy ‘lemon myrtle oil’ (Backhousia citriodora) – Potential for incorporation into wound dressings
Seneviratne, Dinuki M., Raphael, Brooke, Whiteside, Eliza J., Windus, Louisa C.E., Kauter, Kate, Dearnaley, John D.W., Annamalai, Pratheep K., Ward, Raelene, Song, Pingan and Burey, Paulomi (Polly). 2024. " A low-cost, antimicrobial aloe-alginate hydrogel film containing Australian First Nations remedy ‘lemon myrtle oil’ (Backhousia citriodora) – Potential for incorporation into wound dressings." Heliyon. 10 (18). https://doi.org/10.1016/j.heliyon.2024.e37516
Enhancing the storage stability and shelf-life of plant-based Pickering emulsions through emulgel formation
Rawal, Kirti, Wang, Yumin, Annamalai, Pratheep Kumar, Bhandari, Bhesh and Prakash, Sangeeta. 2024. "Enhancing the storage stability and shelf-life of plant-based Pickering emulsions through emulgel formation." Innovative Food Science and Emerging Technologies. 97. https://doi.org/10.1016/j.ifset.2024.103795
Polyurethane foam: The foaming process and the effect of process parameters on properties
Haridevan, Hima, Septevani, Athanasia A., Evans, David A.C., Martin, Darren J. and Annamalai, Pratheep K.. 2024. "Polyurethane foam: The foaming process and the effect of process parameters on properties." Raghavan, Prasanth and Sreekala, M.S. (ed.) Handbook of Thermosetting Foams, Aerogels, and Hydrogels. Elsevier. pp. 93-118
Concrete self-healing performance using surface roughness parameters: Metrological approach
Sidiq, Amir, Setunge, Sujeeva, Annamalai, Pratheep Kumar, Gravina, Rebecca J. and Giustozzi, Filippo. 2024. "Concrete self-healing performance using surface roughness parameters: Metrological approach." Journal of Building Engineering. 90. https://doi.org/10.1016/j.jobe.2024.109433
Surfactant assisted tuning of electrical conductivity, electromagnetic interference shielding effectiveness, wetting properties of poly(lactic acid)-expanded graphite-magnetite nanocube hybrid bio-nanocomposites
Balakrishnan, Keerthana, Senthilkumar, Kanya Koothanatham, N, Gokila, Thangavelu, Rajendra Kumar Ramasamy, Annamalai, Pratheep Kumar and Raghava, Ramanujam Brahmadesam Thoopul Srinivasa. 2024. "Surfactant assisted tuning of electrical conductivity, electromagnetic interference shielding effectiveness, wetting properties of poly(lactic acid)-expanded graphite-magnetite nanocube hybrid bio-nanocomposites." European Polymer Journal. 214. https://doi.org/10.1016/j.eurpolymj.2024.113135
Exploring of Cellulose Nanocrystals from Lignocellulosic Sources as a Powerful Adsorbent for Wastewater Remediation
Norfarhana, A. S., Khoo, P. S., Ilyas, R. A., Ab Hamid, N. H., Aisyah, H. A., Norrrahim, Mohd Nor Faiz, Knight, V.F., Rani, M. S. A., Septevani, Athanasia Amanda, Syafri, Edi and Annamalai, Pratheep K.. 2024. "Exploring of Cellulose Nanocrystals from Lignocellulosic Sources as a Powerful Adsorbent for Wastewater Remediation." Journal of Polymers and the Environment. 32 (9), pp. 4071-4101. https://doi.org/10.1007/s10924-024-03227-3
Effect of Polyvinylpyrrolidone on the Structure Development, Electrical, Thermal, and Wetting Properties of Polyvinylidene Fluoride-Expanded Graphite Nanocomposites
Haridass, Reshma, Sabu, Aleena, Augustin, Nikhitha, Annamalai, Pratheep Kumar and Brahmadesam Thoopul Srinivasa, Ramanujam. 2024. "Effect of Polyvinylpyrrolidone on the Structure Development, Electrical, Thermal, and Wetting Properties of Polyvinylidene Fluoride-Expanded Graphite Nanocomposites." ACS Omega. 9 (1), pp. 178-195. https://doi.org/10.1021/acsomega.3c03083
Enhancement of the texture and microstructure of faba bean-based meat analogues with brewers' spent grain through enzymatic treatments
Fan, Yue, Zheng, Shiyu, Annamalai, Pratheep K., Bhandari, Bhesh and Prakash, Sangeeta. 2024. "Enhancement of the texture and microstructure of faba bean-based meat analogues with brewers' spent grain through enzymatic treatments." Sustainable Food Technology. 2 (3), pp. 826-836. https://doi.org/10.1039/d4fb00045e
Unravelling the role of poly(methyl methacrylate) (PMMA) molecular weight in poly(vinylidene fluoride) (PVDF)/PMMA/Expanded graphite (ExGr) blend nanocomposites: Insights into morphology, thermal behavior, electrical conductivity, and wetting property
Augustin, Nikhitha, Muraliharan, Pranesh, Sabu, Aleena, Senthilkumar, Kanya Koothanatham, Annamalai, Pratheep Kumar Annamalai and Ramanujam, Ramanujam Brahmadesam Thoopul Srinivasa. 2024. "Unravelling the role of poly(methyl methacrylate) (PMMA) molecular weight in poly(vinylidene fluoride) (PVDF)/PMMA/Expanded graphite (ExGr) blend nanocomposites: Insights into morphology, thermal behavior, electrical conductivity, and wetting property." Journal of Thermoplastic Composite Materials. 37 (8), pp. 2527-2570. https://doi.org/10.1177/08927057241238203
Functionalizing lignin by in situ solid-phase grafting ammonium polyphosphate for enhancing thermal, flame-retardant, mechanical, and UV-resistant properties of polylactic acid
Zhang, Yan, Liu, Linghui, Yao, Miaohong, Feng, Jiabing, Xue, Yijiao, Annamalai, Pratheep K., Chevali, Venkata, Dinh, Toan, Fang, Zhengping, Liu, Hongzhi and Song, Pingan. 2024. "Functionalizing lignin by in situ solid-phase grafting ammonium polyphosphate for enhancing thermal, flame-retardant, mechanical, and UV-resistant properties of polylactic acid." Chemical Engineering Journal. 495. https://doi.org/10.1016/j.cej.2024.153429
Achieving ultra-tear resistant high-performance natural rubber nanocomposite via bio-inspired lignocellulosic compatibilization
Hosseinmardi, Alireza, Amiralian, Nasim, Martin, Darren J. and Annamalai, Pratheep K.. 2024. "Achieving ultra-tear resistant high-performance natural rubber nanocomposite via bio-inspired lignocellulosic compatibilization." Industrial Crops and Products. 207 (Part 1). https://doi.org/10.1016/j.indcrop.2023.117729
Dispersion engineering of cellulose nanofibres in polyols: for controlled microstructure of high-performance polyurethane foam
Haridevan, Hima, Evans, David A. C., Martin, Darren J. and Annamalai, Pratheep K.. 2024. "Dispersion engineering of cellulose nanofibres in polyols: for controlled microstructure of high-performance polyurethane foam." Materials Advances. 5 (4), pp. 1540-1551. https://doi.org/10.1039/d3ma00865g
Enhancement of emulsion stability and functional properties of hemp protein-based dairy alternative by different treatments after cellulase hydrolysis
Rawal, Kirti, Annamalai, Pratheep Kumar, Ningtyas, Dian Widya and Prakash, Sangeeta. 2024. "Enhancement of emulsion stability and functional properties of hemp protein-based dairy alternative by different treatments after cellulase hydrolysis." International Journal of Food Science and Technology. 59 (1), pp. 639-648. https://doi.org/10.1111/ijfs.16735
Tuning the microstructure of polyurethane foam using nanocellulose for improved thermal insulation properties through an efficient dispersion methodology
Septevani, Athanasia A., Evans, David A.C., Martin, Darren J., Song, Pingan and Annamalai, Pratheep K.. 2023. "Tuning the microstructure of polyurethane foam using nanocellulose for improved thermal insulation properties through an efficient dispersion methodology." Polymer Composites. 44 (12), pp. 8857-8869. https://doi.org/10.1002/pc.27743
X-ray Tomographic Reconstruction for Understanding Lignin-Induced Changes in the Microstructure and Properties of Polyurethane Insulation Foam
Haridevan, Hima, Barkauskas, Deborah, Sokolowski, Kamil A., Evans, David A.C., Martin, Darren J. and Annamalai, Pratheep K.. 2023. "X-ray Tomographic Reconstruction for Understanding Lignin-Induced Changes in the Microstructure and Properties of Polyurethane Insulation Foam." ACS Applied Polymer Materials. 5 (9), pp. 6772-6780. https://doi.org/10.1021/acsapm.3c00380
Oat flour as a novel stabiliser for designing plant-based Pickering emulsion
Rawal, Kirti, Annamalai, Pratheep K., Bhandari, Bhesh and Prakash, Sangeeta. 2023. "Oat flour as a novel stabiliser for designing plant-based Pickering emulsion." Journal of Food Engineering. 340, p. 111300. https://doi.org/10.1016/j.jfoodeng.2022.111300
Transiting Exoplanet Monitoring Project (TEMP). I. Refined System Parameters and Transit Timing Variations of HAT-P-29b
Wang, Songhu, Wang, Xian-Yu, Wang, Yong-Hao, Liu, Hui-Gen, Hinse, Tobias C., Eastman, Jason, Bayliss, Daniel, Hori, Yasunori, Hu, Shao-Ming, Li, Kai, Liu, Jinzhong, Narita, Norio, Peng, Xiyan, Wittenmyer, R. A., Wu, Zhen-Yu, Zhang, Hui, Zhang, Xiaojia, Zhao, Haibin, Zhou, Ji-Lin, ..., Laughlin, Gregory. 2018. "Transiting Exoplanet Monitoring Project (TEMP). I. Refined System Parameters and Transit Timing Variations of HAT-P-29b." The Astronomical Journal. 156 (4), pp. 1-11. https://doi.org/10.3847/1538-3881/aadcfc
Innovation in nano-polysaccharides for eco-sustainability: From science to industrial applications
Singh, Preeti, Manzoor, Kaiser, Ikram, Saiqa and Annamalai, Pratheep Kumar. 2022. Innovation in nano-polysaccharides for eco-sustainability: From science to industrial applications. India. Elsevier.
Nanocellulose: a sustainable nanomaterial for controlled drug delivery applications
Pennells, Jordan, Martin, Darren J. and Annamalai, Pratheep Kumar. 2022. "Nanocellulose: a sustainable nanomaterial for controlled drug delivery applications." Singh, Preeti and Manzoor, Kaiser (ed.) Innovation in Nano-polysaccharides for Eco-sustainability: From Science to Industrial Applications. India. Elsevier. pp. 217-253
Toxicity assessment of historical aqueous film-forming foams (AFFFs) using cell-based assays
Ojo, Atinuke F., Peng, Cheng, Annamalai, Prasath, Mallavarapu, Mallavarapu and Ng, Jack C.. 2022. "Toxicity assessment of historical aqueous film-forming foams (AFFFs) using cell-based assays." Environmental Pollution. 310. https://doi.org/10.1016/j.envpol.2022.119806
hydrothermal co-liquefaction of biomass and plastic wastes into biofuel: Study on catalyst property, product distribution and synergistic effects
Mukundan, Swathi, Wagner, Jonathan L., Annamalai, Pratheep K., Ravindran, Devika Sudha, Krishnapillai, Girish Kumar and Beltramini, Jorge. 2022. "hydrothermal co-liquefaction of biomass and plastic wastes into biofuel: Study on catalyst property, product distribution and synergistic effects." Fuel Processing Technology. 238. https://doi.org/10.1016/j.fuproc.2022.107523
A cleaner processing approach for cellulose reinforced thermoplastic polyurethane nanocomposites
Amin, Khairatun Najwa Mohd, Chaleat, Celine, Edwards, Grant, Martin, Darren J. and Annamalai, ratheep Kumar. 2022. "A cleaner processing approach for cellulose reinforced thermoplastic polyurethane nanocomposites." Polymer Engineering and Science. 62 (3), pp. 949-961. https://doi.org/10.1002/pen.25899
Recent Advances in the Nanomaterials, Design, Fabrication Approaches of Thermoelectric Nanogenerators for Various Applications
Kim, Andrew, Kumar, Pawan, Annamalai, Pratheep Kumar and Patel, Rajkumar. 2022. "Recent Advances in the Nanomaterials, Design, Fabrication Approaches of Thermoelectric Nanogenerators for Various Applications." Advanced Materials Interfaces. 9 (35). https://doi.org/10.1002/admi.202201659
Rational analysis of dispersion and solubility of Kraft lignin in polyols for polyurethanes
Haridevan, Hima, Evans, David A.C., Martin, Darren J. and Annamalai, Pratheep K.. 2022. "Rational analysis of dispersion and solubility of Kraft lignin in polyols for polyurethanes." Industrial Crops and Products. 185. https://doi.org/10.1016/j.indcrop.2022.115129
Processing and rheological properties of polyol/cellulose nanofibre dispersions for polyurethanes
Haridevan, Hima, Chaleat, Celine, Pooley, Liam, Evans, David A.C., Halley, Peter J., Martin, Darren J. and Annamalai, Pratheep K.. 2022. "Processing and rheological properties of polyol/cellulose nanofibre dispersions for polyurethanes." Polymer. 255. https://doi.org/10.1016/j.polymer.2022.125130
High-Resolution R2R-Compatible Printing of Carbon Nanotube Conductive Patterns Enabled by Cellulose Nanocrystals
Corletto, Alexander, Hosseinmardi, Alireza, Annamalai, Pratheep Kumar, Martin, Darren J. and Shapter, Joseph G.. 2022. "High-Resolution R2R-Compatible Printing of Carbon Nanotube Conductive Patterns Enabled by Cellulose Nanocrystals." ACS Applied Nano Materials. 5 (1), pp. 1574-1587. https://doi.org/10.1021/acsanm.1c04320
A mixed acid methodology to produce thermally stable cellulose nanocrystal at high yield using phosphoric acid
Amin, Khairatun Najwa, Hosseinmardi, Alireza, Martin, Darren J. and Annamalai, Pratheep K.. 2022. "A mixed acid methodology to produce thermally stable cellulose nanocrystal at high yield using phosphoric acid." Journal of Bioresources and Bioproducts. 7 (2), pp. 99-108. https://doi.org/10.1016/j.jobab.2021.12.002
Lignocellulosic plant cell wall variation influences the structure and properties of hard carbon derived from sorghum biomass
Afzal, Rana Arslan, Pennells, Jordan, Yamauchi, Yusuke, Annamalai, Pratheep K., Nanjundan, Ashok Kumar and Martin, Darren J.. 2022. "Lignocellulosic plant cell wall variation influences the structure and properties of hard carbon derived from sorghum biomass." Carbon Trends. 7, pp. 1-12. https://doi.org/10.1016/j.cartre.2022.100168
A polyphosphoramide-grafted lignin enabled thermostable and fire-retardant polylactide with preserved mechanical properties
Liu, Lina, Shi, Bingbing, Zhang, Anlin, Xue, Yijiao, Zhang, Jianzhong, Dai, Jinfeng, Hassanpour, Morteza, Tang, Long-Cheng, Shi, Yongqian and Song, Pingan. 2022. "A polyphosphoramide-grafted lignin enabled thermostable and fire-retardant polylactide with preserved mechanical properties." Composites Part A: Applied Science and Manufacturing. 160. https://doi.org/10.1016/j.compositesa.2022.107028
Molecularly Engineered Lignin-Derived Additives Enable Fire-Retardant, UV-Shielding, and Mechanically Strong Polylactide Biocomposites
Yang, Haitang, Shi, Bingbing, Xue, Yijiao, Ma, Zhewen, Liu, Lina, Liu, Lei, Yu, Youming, Zhang, Zhanying, Annamalai, Pratheep K. and Song, Pingan. 2021. "Molecularly Engineered Lignin-Derived Additives Enable Fire-Retardant, UV-Shielding, and Mechanically Strong Polylactide Biocomposites." Biomacromolecules. 22 (4), pp. 1432-1444. https://doi.org/10.1021/acs.biomac.0c01656
Transiting Exoplanet Monitoring Project (TEMP). III. On the Relocation of the Kepler-9 b Transit
Wang, Songhu, Wu, Dong-Hong, Addison, Brett C., Laughlin, Gregory, Liu, Hui-Gen, Wang, Yong-Hao, Yang, Taozhi, Yang, Ming, Yisikandeer, Abudusaimaitijiang, Hong, Renquan, Li, Bin, Liu, Jinzhong, Zhao, Haibin, Wu, Zhen-Yu, Hu, Shao-Ming, Zhou, Xu, Zhou, Ji-Lin, Zhang, Hui, Zheng, Jie, ..., Guo, Di-Fu. 2018. "Transiting Exoplanet Monitoring Project (TEMP). III. On the Relocation of the Kepler-9 b Transit." The Astronomical Journal. 155 (2), pp. 1-7. https://doi.org/10.3847/1538-3881/aaa253
Review on Colloidal Quantum Dots Luminescent Solar Concentrators
Kim, Andrew, Hosseinmardi, Alireza, Annamalai, Pratheep K., Kumar, Pawan and Patel, Rajkumar. 2021. "Review on Colloidal Quantum Dots Luminescent Solar Concentrators." Chemistry Select. 6 (20), pp. 4948-4967. https://doi.org/10.1002/slct.202100674
Toughening of natural rubber nanocomposites by the incorporation of nanoscale lignin combined with an industrially relevant leaching process
Hosseinmardi, Alireza, Amiralian, Nasim, Hayati, Amir Nemati, Martin, Darren J. and Annamalai, Pratheep K.. 2021. "Toughening of natural rubber nanocomposites by the incorporation of nanoscale lignin combined with an industrially relevant leaching process." Industrial Crops and Products. 159. https://doi.org/10.1016/j.indcrop.2020.113063
Dispersion Methodology for Technical Lignin into Polyester Polyol for High-Performance Polyurethane Insulation Foam
Haridevan, Hima, McLaggan, Martyn S., Evans, David A.C., Martin, Darren J., Seaby, Trent, Zhang, Zhanying and Annamalai, Pratheep K.. 2021. "Dispersion Methodology for Technical Lignin into Polyester Polyol for High-Performance Polyurethane Insulation Foam." ACS Applied Polymer Materials. 3 (7), pp. 3528-3537. https://doi.org/10.1021/acsapm.1c00430
Valorisation of technical lignin in rigid polyurethane foam: a critical evaluation on trends, guidelines and future perspectives
Haridevan, Hima, Evans, David A. C., Ragauskas, Arthur J., Martin, Darren J. and Annamalai, Pratheep K.. 2021. "Valorisation of technical lignin in rigid polyurethane foam: a critical evaluation on trends, guidelines and future perspectives." Green Chemistry. 23 (22), pp. 8725-8753. https://doi.org/10.1039/d1gc02744a
Enhanced dispersion of lignin in pet polyols for improved thermal insulation of polyurethane foams
Haridevan, Hima, Birnie, David, Evans, David A.C., Martin, Darren J. and Annamalai, Pratheep K.. 2021. "Enhanced dispersion of lignin in pet polyols for improved thermal insulation of polyurethane foams." Annual Technical Conference for Plastic Professionals (ANTEC 2021). Online 10 - 21 May 2021 United States.
3D enabled facile fabrication of substrates with human tongue characteristics for analysing the tribological behaviour of food emulsions
Fan, Juan, Annamalai, Pratheep K. and Prakash, Sangeeta. 2021. "3D enabled facile fabrication of substrates with human tongue characteristics for analysing the tribological behaviour of food emulsions." Innovative Food Science and Emerging Technologies. 73. https://doi.org/10.1016/j.ifset.2021.102803
An Overview of Cellulose-Based Nanogenerators
Annamalai, Pratheep K., Nanjundan, Ashok Kumar, Dubal, Deepak P. and Baek, Jong-Beom. 2021. "An Overview of Cellulose-Based Nanogenerators." Advanced Materials Technologies. 6 (3). https://doi.org/10.1002/admt.202001164
Potassium-Ion Storage in Cellulose-Derived Hard Carbon: The Role of Functional Groups
Nanjundan, Ashok, Gaddam, Rohit Ranganathan, Niaei, Amir H. Farokh, Annamalai, Pratheep K., Dubal, Deepak P., Martin, Darren James, Yamauchi, Yusuke, Searles, Debra J. and Zhao, Xiu Song. 2020. "Potassium-Ion Storage in Cellulose-Derived Hard Carbon: The Role of Functional Groups." Batteries & Supercaps. 3 (9), pp. 953-960. https://doi.org/10.1002/batt.202000116
Pyrolysis of brominated polyethylene as an alternative carbon fibre precursor
Laycock, Bronwyn, Wang, Xiaoyu, Liu, Ru-Fen, Annamalai, Pratheep Kumar, Cork, Jorja, Derstine, Chris, Mills, Michael and McFarland, Eric W.. 2020. "Pyrolysis of brominated polyethylene as an alternative carbon fibre precursor." Polymer Degradation and Stability. 172. https://doi.org/10.1016/j.polymdegradstab.2019.109057
Nanocellulose-based carbon as electrode materials for sodium-ion batteries
Ramanujam, B.T.S., Nanjundan, Ashok Kumar and Annamalai, Pratheep K.. 2020. "Nanocellulose-based carbon as electrode materials for sodium-ion batteries." Thoma, Sabu and Pottathara, Yasir Beeran (ed.) Nanocellulose Based Composites for Electronics. United Kingdom. Elsevier. pp. 295-312
Influence of Different Nanocellulose Additives on Processing and Performance of PAN-Based Carbon Fibers
Jiang, Edward, Maghe, Maxime, Zohdi, Nima, Amiralian, Nasim, Naebe, Minoo, Laycock, Bronwyn, Fox, Bronwyn L., Martin, Darren J. and Annamalai, Pratheep K.. 2019. "Influence of Different Nanocellulose Additives on Processing and Performance of PAN-Based Carbon Fibers." ACS Omega. 4 (6), pp. 9720-9730. https://doi.org/10.1021/acsomega.9b00266
Hybrid polyether-palm oil polyester polyol based rigid polyurethane foam reinforced with cellulose nanocrystal
Septevani, Athanasia A., Evans, David A.C., Martin, Darren J. and Annamalai, Pratheep K.. 2018. "Hybrid polyether-palm oil polyester polyol based rigid polyurethane foam reinforced with cellulose nanocrystal." Industrial Crops and Products. 112, pp. 378-388. https://doi.org/10.1016/j.indcrop.2017.12.032
Atomic Layer Deposition of Metal Oxide on Nanocellulose for Enabling Microscopic Characterization of Polymer Nanocomposites
Septevani, Athanasia A., Evans, David A. C., Hosseini, Alireza, Martin, Darren J., Simonsen, John, Conley Jr., John F. and Annamalai, Pratheep K.. 2018. "Atomic Layer Deposition of Metal Oxide on Nanocellulose for Enabling Microscopic Characterization of Polymer Nanocomposites." Small. 14 (46). https://doi.org/10.1002/smll.201803439
Chitosan-based bionanocomposites for biomedical application
Kumari, Sangeeta, Singh, Raj Pal, Chavan, Nayaku N and Annamalai, Pratheep K. 2018. "Chitosan-based bionanocomposites for biomedical application." Bioinspired, Biomimetic and Nanobiomaterials. 7 (4), pp. 219-227. https://doi.org/10.1680/jbibn.15.00015
Facile Tuning of the Surface Energy of Cellulose Nanofibers for Nanocomposite Reinforcement
Hosseinmardi, Alireza, Annamalai, Pratheep Kumar, Martine, Benoit, Pennells, Jordan, Martin, Darren J. and Amiralian, Nasim. 2018. "Facile Tuning of the Surface Energy of Cellulose Nanofibers for Nanocomposite Reinforcement." ACS Omega. 3 (11), pp. 15933-15942. https://doi.org/10.1021/acsomega.8b02104
A simple methodology for improving the performance and sustainability of rigid polyurethane foam by incorporating industrial lignin
Hayati, Amir Nemati, Evans, David Alwyn Charles, Laycock, Bronwyn, Martin, Darren James and Annamalai, Pratheep Kumar. 2018. "A simple methodology for improving the performance and sustainability of rigid polyurethane foam by incorporating industrial lignin." Industrial Crops and Products. 117, pp. 149-158. https://doi.org/10.1016/j.indcrop.2018.03.006
WES—Weihai Echelle Spectrograph
Gao, Dong-Yang, Ji, Hang-Xin, Cao, Chen, Hu, Shao-Ming, Wittenmyer, Robert A., Hu, Zhong-Wen, Grupp, Frank, Kellermann, Hanna, Li, Kai and Guo, Di-Fu. 2016. "WES—Weihai Echelle Spectrograph." Publications of the Astronomical Society of the Pacific. 128 (970). https://doi.org/10.1088/1538-3873/128/970/125002
The use of cellulose nanocrystals to enhance the thermal insulation properties and sustainability of rigid polyurethane foam
Septevani, Athanasia A., Evans, David A.C., Annamalai, Pratheep K. and Martin, Darren J.. 2017. "The use of cellulose nanocrystals to enhance the thermal insulation properties and sustainability of rigid polyurethane foam." Industrial Crops and Products. 107, pp. 114-121. https://doi.org/10.1016/j.indcrop.2017.05.039
Synthesis and characterization of cellulose nanocrystals as reinforcing agent in solely palm based polyurethane foam
Septevani, Athanasia Amanda, Annamalai, Pratheep K. and Martin, Darren J.. 2017. "Synthesis and characterization of cellulose nanocrystals as reinforcing agent in solely palm based polyurethane foam." 3rd International Symposium on Applied Chemistry (ISAC) 2017. Jakarta, Indonesia 23 - 24 Oct 2017 AIP Publishing. https://doi.org/10.1063/1.5011899
Conducting polymer–graphite binary and hybrid composites
Ramanujam, B.T.S. and Annamalai, Pratheep K.. 2017. "Conducting polymer–graphite binary and hybrid composites." Thakur, Vijay Kumar, Thakur, Manju Kumari and Pappu, Asokan (ed.) Hybrid Polymer Composite Materials. India. Elsevier. pp. 1-34
Influence of Moisture Dependency of Pressboard on Transformer Winding Clamping Pressure
Naranpanawe, Lakshitha, Ekanayake, Chandima, Saha, Tapan Kumar and Annamalai, Naranpanawe1, Chandima Ekanayake2, Tapan Kumar Saha1 and Pratheep K.. 2017. "Influence of Moisture Dependency of Pressboard on Transformer Winding Clamping Pressure." IEEE Transactions on Dielectrics and Electrical Insulation. 24 (5), pp. 3191-3200. https://doi.org/10.1109/Tdei.2017.006206
Cellulose Nanocrystals with Enhanced Thermal Stability Reinforced Thermoplastic Polyurethane
Amin, Khairatun Najwa, Annamalai, , Pratheep Kumar and Martin, Darren. 2017. "Cellulose Nanocrystals with Enhanced Thermal Stability Reinforced Thermoplastic Polyurethane." Malaysian Journal of Analytical Sciences. 21 (3), pp. 754-761. https://doi.org/10.17576/mjas-2017-2103-25
Cellulose Nanofibers as Rheology Modifiers and Enhancers of Carbonization Efficiency in Polyacrylonitrile
Jiang, Edward, Amiralian, Nasim, Maghe, Maxime, Laycock, Bronwyn, McFarland, Eric M, Fox, Bronwyn F, Martin, D.J. and Annamalai, Pratheep K.. 2017. "Cellulose Nanofibers as Rheology Modifiers and Enhancers of Carbonization Efficiency in Polyacrylonitrile." ACS Sustainable Chemistry and Engineering. 5 (4), pp. 3296-3304. https://doi.org/10.1021/acssuschemeng.6b03144
Reinforcement of natural rubber latex using lignocellulosic nanofibers isolated from spinifex grass
Hosseinmardi, Alireza, Annamalai, Pratheep K., Wang, Lianzhou, Martin, Darren and Amiralian, Nasim. 2017. "Reinforcement of natural rubber latex using lignocellulosic nanofibers isolated from spinifex grass." Nanoscale. 9 (27), pp. 9510-9519. https://doi.org/10.1039/c7nr02632c
Spinifex nanocellulose derived hard carbon anodes for high-performance sodium-ion batteries
Gaddam, Rohit Ranganathan., Jiang, Edward, Amiralian, Nasim, Annamalai, Pratheep K., Martin, Darren J., Nanjundan, Nanjundan and Zhao, X. S.. 2017. "Spinifex nanocellulose derived hard carbon anodes for high-performance sodium-ion batteries." Sustainable Energy & Fuels. 1 (5), pp. 1090-1097. https://doi.org/10.1039/c7se00169j
High aspect ratio nanocellulose from an extremophile spinifex grass by controlled acid hydrolysis
Amiralian, Nasim, Annamalai, . Pratheep K., Garvey, Christopher J., Jiang, Edward, Memmott, Paul and Martin, Darren J.. 2017. "High aspect ratio nanocellulose from an extremophile spinifex grass by controlled acid hydrolysis." Cellulose. 24 (9), pp. 3753-3766. https://doi.org/10.1007/s10570-017-1379-6
Effect of pressboard ageing on power transformer mechanical vibration characteristics
Naranpanawe, W. M. L. B., Bandara, K. M. K. S., Saha, T.K., Ekanayake, C. and Annamalai, Pratheep Kumar. 2016. "Effect of pressboard ageing on power transformer mechanical vibration characteristics." 2015 IEEE PES Asia-Pacific Power and Energy Engineering Conference (APPEEC 2015). Brisbane, Australia 15 - 18 Nov 2015 Australia. https://doi.org/10.1109/APPEEC.2015.7380951
Dip-and-Drag Lateral Force Spectroscopy for Measuring Adhesive Forces between Nanofibers
Dolan, Grace K., Yakubov, Gleb E., Greene, George W., Amiralian, NasimNasim, Annamalai, Pratheep K., Martin, Darren J. and Stokes, Jason R.. 2016. "Dip-and-Drag Lateral Force Spectroscopy for Measuring Adhesive Forces between Nanofibers." Langmuir: the ACS journal of surfaces and colloids. 32 (50), pp. 13340-13348. https://doi.org/10.1021/acs.langmuir.6b03467
Understanding the Ageing Aspects of Natural Ester Based Insulation liquid in Power Transformer
Badana, Kapila, Ekanayake, Chandima, Saha, Tapan Kumar and Annamalai, Pratheep Kumar. 2016. "Understanding the Ageing Aspects of Natural Ester Based Insulation liquid in Power Transformer." IEEE Transactions on Dielectrics and Electrical Insulation. 23 (1), pp. 246-257. https://doi.org/10.1109/Tdei.2015.004744
Systematic production of high quality and low cost cellulose nanofibres and their potential applications
Amiralian, Nasim, Annamalai, Pratheep and Martin, Darren J.. 2016. "Systematic production of high quality and low cost cellulose nanofibres and their potential applications." TAPPI International Conference on Nanotechnology for Renewable Materials 2016. Grenoble, France 13 - 16 Jun 2016 France.
Scalable processing of thermoplastic polyurethane nanocomposites toughened with nanocellulose
Amin, Khairatun Najwa Mohd, Amiralian, Nasim, Annamalai, Pratheep K., Edwards, Grant, Chaleat, Celine and Martin, Darren J.. 2016. "Scalable processing of thermoplastic polyurethane nanocomposites toughened with nanocellulose." Chemical Engineering Journal. 302, pp. 406-416. https://doi.org/10.1016/j.cej.2016.05.067
Cleaner and scalable processing of cellulose nanocrystal reinforced thermoplastic polyurethane nanocomposites
Mohd Amin, Khairatun Najwa, Amin, Mohd, Annamalai, Pratheep Kumar, Edwards, Grant A.B., Chaleat, Celine and Martin, Darren J.. 2016. "Cleaner and scalable processing of cellulose nanocrystal reinforced thermoplastic polyurethane nanocomposites." TAPPI International Conference on Nanotechnology for Renewable Materials 2016. Grenoble, France 13 - 16 Jun 2016 France.
Polymers from Biomass: Characterization, Modification, Degradation, and Applications
Adsul, Mukund, Tuli, Deepak K., Annamalai, Pratheep K., Depan, Dilip and Shankar, Shiv. 2016. "Polymers from Biomass: Characterization, Modification, Degradation, and Applications." International Journal of Polymer Science. 2016. https://doi.org/10.1155/2016/1857297
A systematic study substituting polyether polyol with palm kernel oil based polyester polyol in rigid polyurethane foam
Septevani, Athanasia A., Evans, David A.C., Chaleat, Celine, Martin, Darren J. and Annamalai, Pratheep K.. 2015. "A systematic study substituting polyether polyol with palm kernel oil based polyester polyol in rigid polyurethane foam." Industrial Crops and Products. 66, pp. 16-26. https://doi.org/10.1016/j.indcrop.2014.11.053
Production of cellulose nanocrystals via a scalable mechanical method
Amin, Khairatun Najwa Mohd, Annamalai, Pratheep Kumar, Morrow, Isabel Catherine and Martin, Darren. 2015. "Production of cellulose nanocrystals via a scalable mechanical method." RSC Advances: an international journal to further the chemical sciences. 5 (70), pp. 57133-57140. https://doi.org/10.1039/c5ra06862b
Easily deconstructed, high aspect ratio cellulose nanofibres from Triodia pungens; an abundant grass of Australia's arid zone
Amiralian, Nasim, Annamalai, Pratheep K., Memmott, Paul, Taran, Elena, Schmidt, Susanne and Martin, Darren J.. 2015. "Easily deconstructed, high aspect ratio cellulose nanofibres from Triodia pungens; an abundant grass of Australia's arid zone." RSC Advances: an international journal to further the chemical sciences. 5 (41), pp. 32124-32132. https://doi.org/10.1039/c5ra02936h
Isolation of cellulose nanofibrils from Triodia pungens via different mechanical methods
Amiralian, Nasim, Annamalai, Pratheep K., Memmott, Paul and Martin, Darren. J.. 2015. "Isolation of cellulose nanofibrils from Triodia pungens via different mechanical methods ." Cellulose. 22 (4), pp. 2483-2498. https://doi.org/10.1007/s10570-015-0688-x
Erratum to “Optimization of resin extraction from an Australian arid grass ‘Triodia pungens’ and its preliminary evaluation as an anti-termite timber coating” [Ind. Crops Prod. 59 (2014) 241–247]
Amiralian, Nasim, Annamalai, Pratheep K., Fitzgerald, Chris, Memmott, Paul and Martin, Darren J.. 2015. "Erratum to “Optimization of resin extraction from an Australian arid grass ‘Triodia pungens’ and its preliminary evaluation as an anti-termite timber coating” [Ind. Crops Prod. 59 (2014) 241–247]." Industrial Crops and Products. 67, pp. 512-512. https://doi.org/10.1016/j.indcrop.2014.12.037
Optimisation of resin extraction from an Australian arid grass ‘Triodia pungens’ and its preliminary evaluation as an anti-termite timber coating
Amiralian, Nasim, Annamalai, Pratheep K., Fitzgerald, Chris, Memmott, Paul and Martin, Darren J.. 2014. "Optimisation of resin extraction from an Australian arid grass ‘Triodia pungens’ and its preliminary evaluation as an anti-termite timber coating." Industrial Crops and Products. 59, pp. 241-247. https://doi.org/10.1016/j.indcrop.2014.04.045
Stability of chitosan/montmorillonite nanohybrid towards enzymatic degradation on grafting with poly(lactic acid)
Depan, D., Annamalai, A. Pratheep, Singh, R. P. and Misra, R. D. K.. 2014. "Stability of chitosan/montmorillonite nanohybrid towards enzymatic degradation on grafting with poly(lactic acid)." Materials Science and Technology. 30 (5), pp. 587-592. https://doi.org/10.1179/1743284713y.0000000501
Can clay nanoparticles accelerate environmental biodegradation of polyolefins?
Annamalai, P. K. and Martin, D. J.. 2014. "Can clay nanoparticles accelerate environmental biodegradation of polyolefins?" Materials Science and Technology. 30 (5), pp. 593-602. https://doi.org/10.1179/1743284713y.0000000498
Water-Responsive Mechanically Adaptive Nanocomposites Based on Styrene–Butadiene Rubber and Cellulose Nanocrystals—Processing Matters
Annamalai, Pratheep K., Dagnon, Koffi L., Monemian, Seyedali, Foster, E. Johan, Rowan, Stuart J. and Weder, Christoph. 2014. "Water-Responsive Mechanically Adaptive Nanocomposites Based on Styrene–Butadiene Rubber and Cellulose Nanocrystals—Processing Matters ." ACS Applied Materials and Interfaces. 6 (2), pp. 967-76. https://doi.org/10.1021/am404382x
Studies on the feasibility of recycled polystyrene doped with NLO active meta-Nitroaniline for optoelectronics applications
Sureshkumar, M.S., Goyal, R.L., Negi, Y.s., Pratheepkumar, A., Reddy, K. Raghunatha, Singh, R.P., Dadge, J.W. and Aiyer, R.C.. 2011. "Studies on the feasibility of recycled polystyrene doped with NLO active meta-Nitroaniline for optoelectronics applications ." Polymers for Advanced Technologies. 22 (12), pp. 1865-1871. https://doi.org/10.1002/pat.1685
Bioinspired Mechanically Adaptive Polymer Nanocomposites with Water-Activated Shape-Memory Effect
Mendez, Julie, Annamalai, Pratheep K., Eichhorn, Stephen J., Rusli, Rafeadah, Rowan, Stuart J., Foste, E. Johan and Weder, Christoph. 2011. "Bioinspired Mechanically Adaptive Polymer Nanocomposites with Water-Activated Shape-Memory Effect." Macromolecules. 44 (17), pp. 6827-6835. https://doi.org/10.1021/ma201502k
Commercial aspects associated with bio-nanocomposites
Lonkar, Sunil P., Kumar, A. Pratheep and Singh, R. P.. 2011. "Commercial aspects associated with bio-nanocomposites." Nanocomposites with Biodegradable Polymers: Synthesis, Properties, and Future Perspectives. United Kingdom. Oxford University Press. pp. 400-420
Kinetics of mass transfer during vapour-induced phase separation (VIPS) process and its influence on poly-(vinylidene fluoride) (PVDF)membrane structure and surface morphology
Annamalai, Pratheep Kumar, Pochat-Bohatier, Celine, Bouyer, Denis, Li, Chia-Ling, Deratani, André and Wang, Da-Ming. 2011. "Kinetics of mass transfer during vapour-induced phase separation (VIPS) process and its influence on poly-(vinylidene fluoride) (PVDF)membrane structure and surface morphology ." Desalination and Water Treatment. 34 (1-3), pp. 204-210. https://doi.org/10.5004/dwt.2011.2809
Nanoscale particles for polymer degradation and stabilization—Trends and future perspectives
Annamalai, Annamalai Pratheep, Depan, Dilip, Tomer, Namrata Singh and Singh, Raj Pal. 2009. "Nanoscale particles for polymer degradation and stabilization—Trends and future perspectives ." Progress in Polymer Science. 34 (6), pp. 479-515. https://doi.org/10.1016/j.progpolymsci.2009.01.002
Cell proliferation and controlled drug release studies of nanohybrids based on chitosan-g-lactic acid and montmorillonite
Depan, Dilip, Annamalai, Annamalai Pratheep and Singh, Raj Pal. 2009. "Cell proliferation and controlled drug release studies of nanohybrids based on chitosan-g-lactic acid and montmorillonite." Acta Biomaterialia. 5 (1), pp. 93-100. https://doi.org/10.1016/j.actbio.2008.08.007
Single Step Synthesis and Properties of M/MFe2O4 and PVDF/M/MFe2O4 (M = Co, Ni) Magnetic Nanocomposites
Deka, Sasanka, Joy, P. A. and Annamalai, A. Pratheep. 2009. "Single Step Synthesis and Properties of M/MFe2O4 and PVDF/M/MFe2O4 (M = Co, Ni) Magnetic Nanocomposites ." Science of Advanced Materials. 1 (3), pp. 262-268. https://doi.org/10.1166/sam.2009.1053
Effect of γ-dose rate on crystallinity and morphological changes of γ-sterilized biomedical polypropylene
Alariqi, Sameh A.S., Annamalai, A. Pratheep, Rao, B.S.M. and Singh, R.P.. 2009. "Effect of γ-dose rate on crystallinity and morphological changes of γ-sterilized biomedical polypropylene." Polymer Degradation and Stability. 94 (2), pp. 272-277. https://doi.org/10.1016/j.polymdegradstab.2008.10.027
Biocomposites of cellulose reinforced starch: improvement of properties by photo-induced crosslinking
Kumar, Annamalai Pratheep and Singh, Raj Pal. 2008. "Biocomposites of cellulose reinforced starch: improvement of properties by photo-induced crosslinking." Bioresource Technology. 99 (18), pp. 8803-8809. https://doi.org/10.1016/j.biortech.2008.04.045
Novel hybrid of clay, cellulose, and thermoplastics. I. Preparation and characterization of composites of ethylene–propylene copolymer
Kumar, Annamalai Pratheep and Singh, Raj Pal. 2007. "Novel hybrid of clay, cellulose, and thermoplastics. I. Preparation and characterization of composites of ethylene–propylene copolymer." Journal of Applied Polymer Science. 104 (4), pp. 2672-2682. https://doi.org/10.1002/app.25659
Photo-stabilization of EPDM-clay nanocomposites: effect of antioxidant on the preparation and durability
Lonkar, Sunil P., Annamalai, A. Pratheep and Singh, Raj Pal. 2007. "Photo-stabilization of EPDM-clay nanocomposites: effect of antioxidant on the preparation and durability." Polymers for Advanced Technologies. 18 (11), pp. 891-900. https://doi.org/10.1002/pat.925
Stabilization of γ-sterilized biomedical polyolefins by synergistic mixtures of oligomeric stabilizers. Part II. Polypropylene matrix
Alariqi, Sameh A.S., Kumar, A. Pratheep, Rao, B.S.M. Rao and Singh, R.P.. 2007. "Stabilization of γ-sterilized biomedical polyolefins by synergistic mixtures of oligomeric stabilizers. Part II. Polypropylene matrix ." Polymer Degradation and Stability. 92 (2), pp. 299-309. https://doi.org/10.1016/j.polymdegradstab.2006.10.010
Photo-/Bio-degradability of Agro Waste and Ethylene–Propylene Copolymers Composites Under Abiotic and Biotic Environments
Kumar, A. Pratheep, Pandey, Jitendra K., Kumar, Bijendra and Singh, R. P.. 2006. "Photo-/Bio-degradability of Agro Waste and Ethylene–Propylene Copolymers Composites Under Abiotic and Biotic Environments." Journal of Polymers and the Environment. 14 (2), pp. 203-212. https://doi.org/10.1007/s10924-006-0012-9
Preparation and characterization of novel hybrid of chitosan-g-lactic acid and montmorillonite
Depan, Dilip, Annamalai, Annamalai Pratheep and Singh, Raj Pal. 2006. "Preparation and characterization of novel hybrid of chitosan-g-lactic acid and montmorillonite." Journal of Biomedical Materials Research Part A. 78 (2), pp. 372-82. https://doi.org/10.1002/jbm.a.30738
Stabilization of γ-sterilized biomedical polyolefins by synergistic mixtures of oligomeric stabilizers
Alariqi, Sameh. A.S., Annamalai, A. Pratheep, Rao, B.S.M., Tevtia, Amit K. and Singh, R.P.. 2006. "Stabilization of γ-sterilized biomedical polyolefins by synergistic mixtures of oligomeric stabilizers ." Polymer Degradation and Stability. 91 (10), pp. 2451-2464. https://doi.org/10.1016/j.polymdegradstab.2006.03.010
Biodegradation of γ-sterilised biomedical polyolefins under composting and fungal culture environments
Alariqi, Sameh A.S., Kumar, A. Pratheep, Rao, B.S.M. and Singh, R.P.. 2006. "Biodegradation of γ-sterilised biomedical polyolefins under composting and fungal culture environments." Polymer Degradation and Stability. 91 (5), pp. 1105-1116. https://doi.org/10.1016/j.polymdegradstab.2005.07.004
An overview on the degradability of polymer nanocomposites
Pandey, Jitendra K., Reddy, K. Raghunatha, Kumar, A. Pratheep and Singh, R.P.. 2005. "An overview on the degradability of polymer nanocomposites." Polymer Degradation and Stability. 88 (2), pp. 234-250. https://doi.org/10.1016/j.polymdegradstab.2004.09.013
Recent Advances in Biodegradable Nanocomposites
Pandey, Jitendra K., Kumar, A. Pratheep, Misra, Manjusri, Mohanty, Amar K., Drzal, Lawrence T. and Singh, Raj. 2005. "Recent Advances in Biodegradable Nanocomposites ." Journal of Nanoscience and Nanotechnology. 5 (4), pp. 497-526. https://doi.org/10.1166/jnn.2005.111
Degradability of composites, prepared from ethylene–propylene copolymer and jute fiber under accelerated aging and biotic environments
Annamalai, Annamalai Pratheep, Singh, Raj Pal and Sarwade, Bhimrao D.. 2005. "Degradability of composites, prepared from ethylene–propylene copolymer and jute fiber under accelerated aging and biotic environments." Materials Chemistry and Physics. 92 (2-3), pp. 458-469. https://doi.org/10.1016/j.matchemphys.2005.01.027
Synthesis, characterization, and performance evaluation of novel stabilized TDI-based polyurethane coatings under accelerated weathering
Kumar, A. Pratheep, Reddy, K. Raghunatha, Rana, Sravendra, Lonkar, Sunil P., Raut, K.G. and Singh, Raj Pal. 2005. "Synthesis, characterization, and performance evaluation of novel stabilized TDI-based polyurethane coatings under accelerated weathering." Journal of Vinyl and Additive Technology. 11 (1), pp. 13-20. https://doi.org/10.1002/vnl.20032
Biodegradation of packaging materials: Composting of polyolefins
Pandey, Jitendra K., Kumar, A. Pratheep and Singh, R.P.. 2003. "Biodegradation of packaging materials: Composting of polyolefins." Macromolecular Symposia. 197 (1), pp. 411-420. https://doi.org/10.1002/masy.200350735