Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions

Article


Liu, Yiting, Li, Wen, Li, Kai, Annamalai, Pratheep Kumar, Pratt, Steven, Hassanpour, Morteza, Lu, Haiqin and Zhang, Zhanying. 2022. "Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions." Carbohydrate Polymers. 291. https://doi.org/10.1016/j.carbpol.2022.119602
Article Title

Tailored production of lignin-containing cellulose nanofibrils from sugarcane bagasse pretreated by acid-catalyzed alcohol solutions

ERA Journal ID1568
Article CategoryArticle
AuthorsLiu, Yiting, Li, Wen, Li, Kai, Annamalai, Pratheep Kumar, Pratt, Steven, Hassanpour, Morteza, Lu, Haiqin and Zhang, Zhanying
Journal TitleCarbohydrate Polymers
Journal Citation291
Article Number119602
Number of Pages10
Year2022
PublisherElsevier
Place of PublicationUnited Kingdom
ISSN0144-8617
1879-1344
Digital Object Identifier (DOI)https://doi.org/10.1016/j.carbpol.2022.119602
Web Address (URL)https://www.sciencedirect.com/science/article/pii/S0144861722005070
AbstractIn this study, sugarcane bagasse was pretreated with acid-catalyzed alcohols, i.e., ethanol (AE), ethylene glycol (AEG) and glycerol (AG) to prepare pulps for producing lignin-containing cellulose nanofibrils (LCNF) with tailored properties, such as hydrophilicity/hydrophobicity and dispersion stability. The results showed that AG-LCNF had the highest lignin content of 16% but relatively low hydrophobicity while AE-LCNF had a low lignin content of 11% but the highest hydrophobicity. LCNF diameter distribution, crystallinity, zeta potentials and thermal stability were also determined to understand the effects of pretreatment solvent. NMR analyses revealed that alcohols modified lignin at α-position by etherification and γ-position by esterification of aliphatic chains, subsequently affecting lignin oxidation by TEMPO in the LCNF production processes, LCNF properties and LCNF dispersion in different solvents. This study provided fundamental information in the design and tailored production of LCNF for various applications, such as manufacturing polymer composites and Pickering emulsions.
KeywordsHydrophobicity; Pretreatment; Lignin; Nanocellulose; Alcohol; Hydrophilicity
Contains Sensitive ContentDoes not contain sensitive content
ANZSRC Field of Research 2020300705. Forestry biomass and bioproducts
340303. Nanochemistry
401807. Nanomaterials
Public NotesFiles associated with this item cannot be displayed due to copyright restrictions.
Byline AffiliationsGuangxi University, China
University of Queensland
Queensland University of Technology
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