Multi-shelled LiMn2O4 hollow microspheres as superior cathode materials for lithium-ion batteries

Article

Wang, Feng, Wang, Jiangyan, Ren, Hao, Tang, Hongjie, Yu, Ranbo and Wang, Dan. 2016. "Multi-shelled LiMn2O4 hollow microspheres as superior cathode materials for lithium-ion batteries." Inorganic Chemistry Frontiers. 3 (3), pp. 365-369. https://doi.org/10.1039/c5qi00213c
Article Title

Multi-shelled LiMn2O4 hollow microspheres as superior cathode materials for lithium-ion batteries

ERA Journal ID210596
Article CategoryArticle
AuthorsWang, Feng (Author), Wang, Jiangyan (Author), Ren, Hao (Author), Tang, Hongjie (Author), Yu, Ranbo (Author) and Wang, Dan (Author)
Journal TitleInorganic Chemistry Frontiers
Journal Citation3 (3), pp. 365-369
Number of Pages5
Year2016
Place of PublicationUnited Kingdom
ISSN2052-1545
2052-1553
Digital Object Identifier (DOI)https://doi.org/10.1039/c5qi00213c
Web Address (URL)http://pubs.rsc.org/en/Content/ArticleLanding/2016/QI/C5QI00213C#!divAbstract
Abstract

Owing to its environmental-benignity, low-cost and abundance, spinel LiMn2O4 has long been considered as a promising cathode material for lithium-ion batteries (LIBs). However, the low electronic conductivity, small lithium diffusion coefficient and poor capacity retention hindered its further development and application. Herein, we report the synthesis of multi-shelled LiMn2O4 hollow microspheres through a hard template method, with the composition, shell number, shell thickness and porosity accurately controlled. Benefitting from the structural superiorities of multi-shelled hollow structures, the triple-shelled LiMn2O4 hollow microsphere exhibits a better cycling stability than all the reported results based on un-coated or un-doped LiMn2O4 (the capacity fading rate is 0.10% per cycle).

ANZSRC Field of Research 2020340299. Inorganic chemistry not elsewhere classified
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Byline AffiliationsUniversity of Science and Technology Beijing, China
Chinese Academy of Sciences, China
Institution of OriginUniversity of Southern Queensland
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Facile molten salt synthesis of ordered perovskite Ba(Sr 1/3Nb 2/3)O3 powders
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Rapid molten salt synthesis of isotropic negative thermal expansion ScF3
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Zero thermal expansion and ferromagnetism in cubic sc1-xMxF3 (M = Ga, Fe) over a wide temperature range
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Microstructure construction and composition modification of CeO2 macrospheres with superior performance
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Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity
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A novel and highly efficient photocatalyst based on P 25- graphdiyne nanocomposite
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Elevated atmospheric [CO2] stimulates sugar accumulation and cellulose degradation rates of rice straw
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Cellular automaton modeling of semisolid microstructure formation
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