Can rainwater induce Fenton-driven degradation of herbicides in natural waters?

Article

Qin, Junhao, Li, Huashou, Lin, Chuxia and Chen, Gu. 2013. "Can rainwater induce Fenton-driven degradation of herbicides in natural waters?" Chemosphere. 92 (8), pp. 1048-1052. https://doi.org/10.1016/j.chemosphere.2013.03.003
Article Title

Can rainwater induce Fenton-driven degradation of herbicides in natural waters?

ERA Journal ID35098
Article CategoryArticle
AuthorsQin, Junhao (Author), Li, Huashou (Author), Lin, Chuxia (Author) and Chen, Gu (Author)
Journal TitleChemosphere
Journal Citation92 (8), pp. 1048-1052
Number of Pages5
Year2013
PublisherElsevier
Place of PublicationKidlington, Oxford. United Kingdom
ISSN0045-6535
1465-9972
1879-1298
Digital Object Identifier (DOI)https://doi.org/10.1016/j.chemosphere.2013.03.003
Abstract

Microcosm experiments were conducted to examine Fenton reaction-driven degradation of three common herbicides exposed to a variety of Fe2+–H2O2 combinations that are likely to be encountered in natural water environments. The results show that these combinations had significant (P < 0.05) effects on removing the water-borne herbicides. This discovery sheds some light on the possible role of rainwater-borne H2O2 in inducing Fenton reaction in many natural waters such as lakes, streams, estuaries and tidal
zones, fishponds and paddy fields that may contain ferrous ion at micromolar levels. The research findings obtained from this preliminary work provide a rationale for undertaking further study to confirm the presence of an overlooked naturally-occurring process that may lead to rapid dissipation of many herbicides and other organic pollutants in open water environments. Our immediate follow-up work is to continue the laboratory-scale investigations under more complex experimental conditions, including the uses of various natural water samples for the experiments. This will provide a basis for future field-based study.

KeywordsFenton reaction; herbicide; natural waters; hydrogen peroxide; ferrous ion; degradation
ANZSRC Field of Research 2020370704. Surface water hydrology
300201. Agricultural hydrology
410499. Environmental management not elsewhere classified
Public Notes

© 2013 Elsevier Ltd. Published version deposited in accordance with the copyright policy of the publisher.

Byline AffiliationsSouth China Agricultural University, China
Australian Centre for Sustainable Catchments
Institution of OriginUniversity of Southern Queensland
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