The role of rainwater-borne hydrogen peroxide in the release of arsenic from arsenopyrite

Article

Ma, Yingqun, Qin, Yanwen and Lin, Chuxia. 2014. "The role of rainwater-borne hydrogen peroxide in the release of arsenic from arsenopyrite." Chemosphere. 103, pp. 349-353. https://doi.org/10.1016/j.chemosphere.2013.11.021
Article Title

The role of rainwater-borne hydrogen peroxide in the release of arsenic from arsenopyrite

ERA Journal ID35098
Article CategoryArticle
AuthorsMa, Yingqun (Author), Qin, Yanwen (Author) and Lin, Chuxia (Author)
Journal TitleChemosphere
Journal Citation103, pp. 349-353
Number of Pages5
Year2014
PublisherElsevier
Place of PublicationOxford, United Kingdom
ISSN0045-6535
1465-9972
1879-1298
Digital Object Identifier (DOI)https://doi.org/10.1016/j.chemosphere.2013.11.021
Abstract

A microcosm experiment was conducted to examine the effects of hydrogen peroxide (at a concentration range of 5-50 μM) on the release of arsenic from the dissolution of arsenopyrite, a dominant arsenic-bearing mineral occurring in natural environments. This was to simulate the reaction between rainwater-borne hydrogen peroxide and arsenopyrite grains exposed on the land surfaces during rainfall events. The results showed that the release of arsenic from arsenopyrite was enhanced by the H2O2 at this concentration range. It was also evident that H2O2 played an indirect role in the transformation of arsenite into arsenate in the solutions, which might affect the fate of the liberated arsenic species due to the formation of FeAsO4 precipitates. The preliminary study sheds some light on the possible role of rainwater-borne H2O2 in the weathering of arsenopyrite, which could complicate the geochemical processes governing the release, transport and fate of arsenopyrite-derived arsenic in natural environments. This provides a rationale for conducting additional laboratory-based investigations to obtain further insights into the chemical mechanisms and kinetics, and the subsequent field-scale study to validate the research findings.

Keywordsarsenate; arsenite; arsenopyrite; Fenton reaction; hydrogen peroxide; rainwater
ANZSRC Field of Research 2020370704. Surface water hydrology
370302. Inorganic geochemistry
370505. Mineralogy and crystallography
Public Notes

© 2013 Elsevier Ltd. All rights reserved. Published online 5 Dec 2013. Published version deposited in accordance with the copyright policy of the publisher.

Byline AffiliationsChinese Research Academy of Environmental Sciences, China
Australian Centre for Sustainable Catchments
Institution of OriginUniversity of Southern Queensland
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