Comparison of copper scavenging capacity between two different red mud types

Article


Ma, Yingqun, Si, Chunhua and Lin, Chuxia. 2012. "Comparison of copper scavenging capacity between two different red mud types." Materials. 5 (9), pp. 1708-1721. https://doi.org/10.3390/ma5091708
Article Title

Comparison of copper scavenging capacity between two
different red mud types

ERA Journal ID123663
Article CategoryArticle
AuthorsMa, Yingqun (Author), Si, Chunhua (Author) and Lin, Chuxia (Author)
Journal TitleMaterials
Journal Citation5 (9), pp. 1708-1721
Number of Pages14
Year2012
PublisherMDPI AG
Place of PublicationBasel, Switzerland
ISSN1996-1944
Digital Object Identifier (DOI)https://doi.org/10.3390/ma5091708
Web Address (URL)http://www.mdpi.com/1996-1944/5/9
Abstract

A batch experiment was conducted to compare the Cu scavenging capacity between two different red mud types: the first one was a highly basic red mud derived from a
combined sintering and Bayer process, and the second one was a seawater-neutralized red mud derived from the Bayer process. The first red mud contained substantial amounts of CaCO3, which, in combination with the high OH− activity, favored the immobilization of water-borne Cu through massive formation of atacamite. In comparison, the seawater-neutralized red mud had a lower pH and was dominated by boehmite, which was likely to play a significant role in
Cu adsorption. Overall, it appears that Cu was more tightly retained by the CaCO3-dominated red mud than the boehmite-dominated red mud. It is concluded that the heterogeneity of
red mud has marked influences on its capacity to immobilize water-borne Cu and maintain the long-term stability of the immobilized Cu species. The research findings obtained from
this study have implications for the development of Cu immobilization technology by using appropriate waste materials generated from the aluminium industry.

Keywordsalumina; bauxite; red mud; calcite; alkaline; copper; boehmite; atacamite; metal immobilization
ANZSRC Field of Research 2020401999. Resources engineering and extractive metallurgy not elsewhere classified
401607. Metals and alloy materials
401102. Environmentally sustainable engineering
Public Notes

© 2012 by the authors. This publication is copyright. It may be reproduced in whole or in part for the purposes of study, research, or review, but is subject to the inclusion of an acknowledgment of the source. Open access journal.

Byline AffiliationsSouth China Agricultural University, China
Australian Centre for Sustainable Catchments
Institution of OriginUniversity of Southern Queensland
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