Synthesis of phenolic bio-resins for advanced composites in civil engineering structures
Paper
Paper/Presentation Title | Synthesis of phenolic bio-resins for advanced composites in civil engineering structures |
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Presentation Type | Paper |
Authors | Cardona, Francisco (Author), Aravinthan, Thiru (Author), Fedrigo, Jessica (Author) and Moscou, Clarisse (Author) |
Editors | Goh, Steven C. and Wang, Hao |
Journal or Proceedings Title | Proceedings of the 2010 Southern Region Engineering Conference (SREC 2010) |
Number of Pages | 7 |
Year | 2010 |
Place of Publication | Toowoomba, Australia |
ISBN | 9781618396150 |
Web Address (URL) of Paper | http://www.usq.edu.au/~/media/USQ/Engineer%20Summit/.../T3-3.ashx |
Web Address (URL) of Conference Proceedings | http://www.usq.edu.au/engsummit/proceedings |
Conference/Event | 2010 Southern Region Engineering Conference (SREC 2010) |
Event Details | 2010 Southern Region Engineering Conference (SREC 2010) Event Date 11 to end of 12 Nov 2010 Event Location Toowoomba, Australia |
Abstract | Novel composites bio-resins for civil engineering applications were synthesised and evaluated. PF phenolic resins were modified to enable their application in modern composites structures. A first modification consisted in the copolymerization of Phenol with Cardanol during the synthesis of resol PF resins. The modified phenolic resins (CPF) were prepared at various molar ratios of the total Phenol to Formaldehyde and with different weight ratios of Phenol to Cardanol. CPF resins with a maximum content of 40 wt% of Cardanol were synthesised and used. The CPF resins were applied as a plasticizer and toughening agents to the PF resins. Both resins (CPF/PF) were mixed in different proportions and their thermal and mechanical properties were established. A full miscibility of the two resins was observed with the formation of a single-phase system. An increases in the content of Cardanol resulted in a proportional increases in the flexural strength and in the fracture toughness together with a decreases in the flexural modulus of the cured CPF/PF resins. Further increased plasticizing and toughening effect was observed by the blending of the CPF/PF resins with propylene glycol (PG). The higher toughness and flexibility effect of the CPF resins was obtained with a F:P molar ratio equal to 1.25. An increases in the Cardanol content resulted in a proportional decreases in the final crosslink density and in the ultimate glass transition temperature of the cured composite resins. |
Keywords | phenolic resins; cardanol; fracture toughness; PG; flexural modulus; crosslink density |
ANZSRC Field of Research 2020 | 400505. Construction materials |
401602. Composite and hybrid materials | |
340204. Inorganic green chemistry | |
Public Notes | © (2010) by Mechatronics and Machine Vision in Practice. |
Byline Affiliations | Centre of Excellence in Engineered Fibre Composites |
Polytech Montpellier University, France |
https://research.usq.edu.au/item/q0243/synthesis-of-phenolic-bio-resins-for-advanced-composites-in-civil-engineering-structures
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