Synergistic band convergence and defect engineering boost thermoelectric performance of SnTe
Article
Article Title | Synergistic band convergence and defect engineering boost |
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ERA Journal ID | 4724 |
Article Category | Article |
Authors | Dong, Ximeng (Author), Cui, Wenlin (Author), Liu, Wei-Di (Author), Zheng, Shuqi (Author), Gao, Lei (Author), Yue, Luo (Author), Wu, Yue (Author), Wang, Boyi (Author), Zhang, Zipei (Author), Chen, Liqiang (Author) and Chen, Zhi-Gang (Author) |
Journal Title | Journal of Materials Science and Technology |
Journal Citation | 86, pp. 204-209 |
Number of Pages | 6 |
Year | 2021 |
Publisher | Elsevier |
Place of Publication | China |
ISSN | 1005-0302 |
Digital Object Identifier (DOI) | https://doi.org/10.1016/j.jmst.2021.01.040 |
Web Address (URL) | https://www.sciencedirect.com/science/article/abs/pii/S1005030221001833 |
Abstract | As an eco-friendly thermoelectric material, SnTe has attracted extensive attention. In this study, we use a stepwise strategy to enhance the thermoelectric performance of SnTe. Firstly, AgCl is doped into SnTe to realize band convergence and enlarge the band gap of AgCl-doped SnTe. AgCl-doping also induces dense point defects, strengthens the phonon scattering, and reduces the lattice thermal conductivity. Secondly, Sb is alloyed into AgCl-doped SnTe to further optimize the carrier concentration and simultaneously reduce the lattice thermal conductivity, leading to improved thermoelectric dimensionless figure of merit, ZT. Finally, (Sn0.81Sb0.19Te)0.93(AgCl)0.07 has approached the ZT value as high as ∼0.87 at 773 K, which is 272 % higher than that of pristine SnTe. This study indicates that stepwise AgCl-doping and Sb-alloying can significantly improve thermoelectric performance of SnTe due to synergistic band engineering, carrier concentration optimization and defect engineering. |
Keywords | Thermoelectric; SnTe; Stepwise optimize; Band structure; Lattice thermal conductivity |
ANZSRC Field of Research 2020 | 401603. Compound semiconductors |
401605. Functional materials | |
340301. Inorganic materials (incl. nanomaterials) | |
401807. Nanomaterials | |
Public Notes | Files associated with this item cannot be displayed due to copyright restrictions. |
Byline Affiliations | China University of Petroleum, China |
Centre for Future Materials | |
Global Energy Interconnection Research Institute, China | |
Institution of Origin | University of Southern Queensland |
https://research.usq.edu.au/item/q7556/synergistic-band-convergence-and-defect-engineering-boost-thermoelectric-performance-of-snte
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