Atomic Insights into Phase Evolution in Ternary Transition-Metal Dichalcogenides Nanostructures
Article
Article Title | Atomic Insights into Phase Evolution in Ternary Transition-Metal Dichalcogenides Nanostructures |
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ERA Journal ID | 3432 |
Article Category | Article |
Authors | Zou, Yi-Chao (Author), Chen, Zhi-Gang (Author), Aso, Kohei (Author), Zhang, Chenxi (Author), Kong, Fantai (Author), Hong, Min (Author), Matsumura, Syo (Author), Cho, Kyeongjae (Author) and Zou, Jin (Author) |
Journal Title | Small |
Journal Citation | 14 (22), pp. 1-6 |
Article Number | 1800780 |
Number of Pages | 6 |
Year | 2018 |
Publisher | John Wiley & Sons |
Place of Publication | Germany |
ISSN | 1613-6810 |
1613-6829 | |
Digital Object Identifier (DOI) | https://doi.org/10.1002/smll.201800780 |
Web Address (URL) | https://onlinelibrary.wiley.com/doi/full/10.1002/smll.201800780 |
Abstract | Phase engineering through chemical modification can significantly alter the properties of transition-metal dichalcogenides, and allow the design of many novel electronic, photonic, and optoelectronics devices. The atomic-scale mechanism underlying such phase engineering is still intensively investigated but elusive. Here, advanced electron microscopy, combined with density functional theory calculations, is used to understand the phase evolution (hexagonal 2H -> monoclinic T'-> orthorhombic T-d) in chemical vapor deposition grown Mo1-xWxTe2 nanostructures. Atomic-resolution imaging and electron diffraction indicate that Mo1-xWxTe2 nanostructures have two phases: the pure monoclinic phase in low W-concentrated (0 < x <= 10 at.%) samples, and the dual phase of the monoclinic and orthorhombic in high W-concentrated (10 < x < 90 at.%) samples. Such phase coexistence exists with coherent interfaces, mediated by a newly uncovered orthorhombic phase T-d'. T-d', preserves the centrosymmetry of T' and provides the possible phase transition path for T'-> Td with low energy state. This work enriches the atomic-scale understanding of phase evolution and coexistence in multinary compounds, and paves the way for device applications of new transition-metal dichalcogenides phases and heterostructures. |
Keywords | 2D materials; electron microscopy; metal dichinversion symmetry-breaking; 2-dimensional materials; monolayer mote2; heterostructures; charge alcogenides; |
ANZSRC Field of Research 2020 | 340210. Solid state chemistry |
401807. Nanomaterials | |
401605. Functional materials | |
510403. Condensed matter modelling and density functional theory | |
Byline Affiliations | University of Queensland |
Kyushu University, Japan | |
University of Texas at Dallas, United States | |
Centre for Future Materials | |
Institution of Origin | University of Southern Queensland |
https://research.usq.edu.au/item/q5057/atomic-insights-into-phase-evolution-in-ternary-transition-metal-dichalcogenides-nanostructures
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